ChemicalBook--->CAS DataBase List--->694-87-1

694-87-1

694-87-1 Structure

694-87-1 Structure
IdentificationMore
[Name]

Bicyclo[4.2.0]octa-1,3,5-triene
[CAS]

694-87-1
[Synonyms]

BENZOCYCLOBUTENE
BICYCLO[4.2.0]OCTA-1,3,5-TRIENE
1,2-Dihydrobenzocyclobutene
Benzocyclobutane
Benzocyclobutene, 1,2-dihydro-
Cardene
BICYCLO[4.2.0]OCTA-1,3,5-TRIEN
Bicyclo[4.2.0]octa-1(6),2,4-triene
Bicyclo[4.2.0]octa-2,4,6(1)-triene
1,2-Ethenobenzene
1,2-Vinylenebenzene
2,3-Vinylenebenzene
Benzocyclobutadiene
[Molecular Formula]

C8H8
[MDL Number]

MFCD01321219
[Molecular Weight]

104.15
[MOL File]

694-87-1.mol
Questions And AnswerBack Directory
[Preparation]

4-Bromobenzocyclobutene, a catalyst, magnesium or zinc metal, and a solvent are mixed and stirred at 20–50°C for 0.2–2 h under an inert gas atmosphere. After the reaction is completed, the reaction solution is separated to obtain benzocyclobutene. The catalyst is nickel chloride, titanium chloride, Fe(acac)3, or benzoyl acetophenone iron.
Chemical PropertiesBack Directory
[Boiling point ]

150 °C/748 mmHg (lit.)
[density ]

0.957 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.541(lit.)
[Fp ]

97 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[InChI]

InChI=1S/C8H8/c1-2-4-8-6-5-7(8)3-1/h1-4H,5-6H2
[InChIKey]

UMIVXZPTRXBADB-UHFFFAOYSA-N
[SMILES]

C12C(CC1)=CC=CC=2
[Uses]

Benzocyclobutene (BCB) is composed of a benzene ring fused to a cyclobutane ring (chemical formula C8H8). It is frequently used to create photosensitive polymers. BCB-based polymer dielectrics may be spun on various substrates, with good step coverage properties that make them useful to planarize uneven topographies. Applications include wafer bonding, optical interconnects, semihermetic package sealing, passivation, and low-k dielectrics. BCB has been also reported as a material with good biocompatibility, being used in intracortical neural implants and other biomedical applications.
[CAS DataBase Reference]

694-87-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Bicyclo[4.2.0]octa-1,3,5-triene(694-87-1)
[EPA Substance Registry System]

694-87-1(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)Flame (GHS02)
GHS08,GHS02
[Signal word ]

Warning
[Hazard statements ]

H226-H304
[Precautionary statements ]

P210-P233-P240-P241+P242+P243-P280-P301+P310+P331-P303+P361+P353-P370+P378-P403+P235-P405-P501
[Risk Statements ]

R10:Flammable.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 3295 3/PG 3
[WGK Germany ]

3
[HazardClass ]

3
[PackingGroup ]

[HS Code ]

29029090
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Flam. Liq. 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

CYCLOBUTANE-->Benzene
[Preparation Products]

4-Aminobenzocyclobutene-->1-Bromobenzocyclobutene-->2,3-Benzodioxin (8CI,9CI)-->Bicyclo[4.2.0]octa-1,3,5-triene-3-carboxamide (7CI,8CI)-->3-(Bromomethyl)bicyclo[4.2.0]octa-1,3,5-triene-->5-nitro-1,2-dihydrocyclobutabenzene-->4-Bromobenzocyclobutene
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Definition]

ChEBI: A carbobicyclic compound that is benzene fused to a cyclobutane ring.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 97, p. 5600, 1975 DOI: 10.1021/ja00852a057
The Journal of Organic Chemistry, 38, p. 3412, 1973 DOI: 10.1021/jo00959a039
Tetrahedron Letters, 16, p. 1893, 1975
[Toxics Screening Level]

The Initial Threshold Screening Level (ITSL) for benzocyclobutene is 220 μg/m3 with an annual averaging time.
Spectrum DetailBack Directory
[Spectrum Detail]

Benzocyclobutene(694-87-1)1HNMR
Benzocyclobutene(694-87-1)13CNMR
Benzocyclobutene(694-87-1)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

694-87-1(sigmaaldrich)
694-87-1 suppliers list
Company Name: Tianjin Chuangwei New Materials Co., Ltd.  Gold
Telephone: 13752736608 13752736608
Website: www.cwmat.cn/
Company Name:   Gold
Telephone: 18809439555 13262587081
Website: www.benzolyte.com/
Company Name: Henan Yinuokai New Materials Co., Ltd  Gold
Telephone: 15565215982 15565215982
Website: www.chemicalbook.com/supplier/131630565/
Company Name: Tongchuang Pharma(Suzhou). Co., Ltd.  Gold
Telephone: 0512-63263366 18912765016
Website: https://www.chemicalbook.com/ShowSupplierProductsList15406/0_EN.htm
Company Name: Mianyang Chemget Chemical Co., Ltd.  Gold
Telephone: 816-816-2551723 18681628050
Website: http://www.chemget.com.cn/
Company Name: Henan yingchuang  Gold
Telephone: 16650708709
Website: www.hnyingchuang.com/
Company Name: LinkChem Technology Co., Ltd.  Gold
Telephone: 021-58950110 13124863828
Website: www.linkchem.cn
Company Name: Zhuo Ruining (Shanghai) Technology Co., Ltd  Gold
Telephone: 18163338995 18163338995
Website: www.chemicalbook.com/supplier/25453348/
Company Name: Shaanxi Gulliver Biotechnology Research Co., Ltd  Gold
Telephone: 13892423764
Website:
Company Name: Yurui (Shanghai) Chemical Co., Ltd.  Gold
Telephone: 02150456736 18602143071
Website: http://www.uivchem.com
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: TCI (Shanghai) Development Co., Ltd.  
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Shijiazhuang Sdyano Fine Chemical Co., Ltd.  
Telephone: 0311-89250318 13582355795
Website: www.sdynchem.com
Company Name: Capot Chemical Co., Ltd  
Telephone: +86 (0) 571 85 58 67 18
Website: www.capotchem.com
Company Name: Accela ChemBio Co.,Ltd.  
Telephone: 021-50795510 4000665055
Website: http://www.shao-yuan.com/
Company Name: Shanghai Longsheng chemical Co.,Ltd.  
Telephone: 58099637 13585536065
Website: www.shlshg.com
Tags:694-87-1 Related Product Information
3469-06-5 195730-31-5 1073-39-8 694-87-1 35202-54-1 148849-67-6