| Identification | More | [Name]
2-BROMO-5-NITROTOLUENE | [CAS]
7149-70-4 | [Synonyms]
2-BROMO-5-NITROTOLUENE
BROMO(5-)-2-NITROTOLUENE
TIMTEC-BB SBB006703
5-BROMO-2-NITROTOLUENE
2-bromo-5-nitromethylbenzene
3-METHYL-4-BROMONITROBENZENE
1-Methyl-2-bromo-5-nitrobenzene
1-Nitro-3-methyl-4-bromobenzene | [EINECS(EC#)]
230-481-4 | [Molecular Formula]
C7H6BrNO2 | [MDL Number]
MFCD00007281 | [Molecular Weight]
216.03 | [MOL File]
7149-70-4.mol |
| Chemical Properties | Back Directory | [Appearance]
LIGHT BROWN-ORANGE TO BROWN CRYST. POWDER | [Melting point ]
78-80 °C(lit.)
| [Boiling point ]
143 °C / 17mmHg | [density ]
1.6841 (rough estimate) | [refractive index ]
1.6120 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
powder to crystal | [color ]
Light yellow to Amber to Dark green | [BRN ]
1940342 | [InChI]
1S/C7H6BrNO2/c1-5-4-6(9(10)11)2-3-7(5)8/h2-4H,1H3 | [InChIKey]
HIMGPQVBNICCGL-UHFFFAOYSA-N | [SMILES]
Cc1cc(ccc1Br)[N+]([O-])=O | [CAS DataBase Reference]
7149-70-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S22:Do not breathe dust . | [WGK Germany ]
3
| [HazardClass ]
IRRITANT | [PackingGroup ]
II | [HS Code ]
29049090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral |
| Hazard Information | Back Directory | [Chemical Properties]
LIGHT BROWN-ORANGE TO BROWN CRYST. POWDER | [Uses]
2-Bromo-5-nitrotoluene has been used in the synthesis of :
- 4′-amino-4-hydroxy-2′-methylbiphenyl
- 3′:4-dinitro-2-methyldiphenyl ether via condensation with potassium m-nitrophenoxide
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 63, p. 8448, 1998 DOI: 10.1021/jo981557o | [Synthesis]
1 mol of o-bromotoluene, 20 g of dried acid saponin and isobutanol were added to a reactor equipped with a water separator, 1,2-dibromoethane was used as solvent, and concentrated nitric acid was added dropwise at 83 for 4 h at this temperature.
The reac |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956 |
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https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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