| Identification | More | [Name]
Diethyl acetylenedicarboxylate | [CAS]
762-21-0 | [Synonyms]
2-butynedioic acid diethyl ester
ACETYLENEDICARBOXYLIC ACID DIETHYL ESTER
DIETHYL ACETYLENEDICARBOXYLATE
DIETHYL BUTYNEDIOATE
Bis-(Ethoxycarbonyl)acetylene
Diethyl 2-butynedioate
butynedioic acid diethyl ester
but-2-ynedioic acid diethyl ester
YL2-BUTYNEDIOATE
Diethyl but-2-yne-1,4-dioate
Bis(carboethoxy)acetylene
Diethyl acetylenedicarboxylic acid | [EINECS(EC#)]
212-095-8 | [Molecular Formula]
C8H10O4 | [MDL Number]
MFCD00009186 | [Molecular Weight]
170.16 | [MOL File]
762-21-0.mol |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [F ]
8-10 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29171990 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR LIGHT YELLOW LIQUID | [Uses]
Diethyl acetylenedicarboxylate is used as a protein cross-linker. It is also used in the synthesis of 3,4,5-trisubstituted 2(5H)-furanone derivatives, highly functionalized thiazolidinone derivatives, novel cyclic peroxide glucosides and 4,11-dimesitylbisanthene, soluble bisanthene derivative, via Diels-Alder reaction. | [General Description]
Diethyl acetylenedicarboxylate is a protein cross-linker. | [Purification Methods]
Dissolve the ester in *C6H6, wash it with NaHCO3, H2O, dry over Na2SO4, filter, evaporate and distil it in a vacuum [IR: Walton & Hughes J Am Chem Soc 79 3985 1957, Truce & Kruse J Am Chem Soc 81 5372 1959]. [Beilstein 2 H 803.] |
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