| Identification | More | [Name]
Ethyl glyoxalate | [CAS]
924-44-7 | [Synonyms]
ETHYL GLYOXALATE
ETHYL GLYOXYLATE
ETHYL GLYOXYLATE POLYMER FORM
ETHYL OXOACETATE
ETHYL OXOACETATE POLYMER FORM
GLYOXALIC ACID ETHYL ESTER POLYMER FORM
GLYOXYLIC ACID ETHYL ESTER
GLYOXYLIC ACID ETHYL ESTER POLYMER FORM
ethylglyoxalatesolution
oxo-aceticaciethylester
Ethyl oxoacetate~Glyoxylic acid ethyl ester~Oxoacetic acid ethyl ester
ETHYL GLYOXALATE SOLUTION, ~50% IN TOLUE NE
Ethyl glycolate(probably 50% solution in toluene)
GLYOXYLIC ACID ETHYL ESTER, POLYMER FORM: 45-50% IN TOLUENE
Ethyl oxoacetate, tech
Ethyl glyoxylate, ca 50% soln. in toluene
Ethyl Glyoxylate Polymer form (47% in Toluene)
Ethyl 2-oxoacetate
2-Oxoacetic acid ethyl ester
Formylformic acid ethyl ester | [EINECS(EC#)]
213-105-3 | [Molecular Formula]
C4H6O3 | [MDL Number]
MFCD00044009 | [Molecular Weight]
102.09 | [MOL File]
924-44-7.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to slightly yellow solution | [Boiling point ]
110°C | [density ]
1.03 g/mL at 20 °C
| [refractive index ]
1.4750 | [Fp ]
7°C | [storage temp. ]
Refrigerator | [solubility ]
Chloroform, Ethyl Acetate | [form ]
Oil | [color ]
Clear Colorless | [Water Solubility ]
Immiscible with water. | [Sensitive ]
Air Sensitive | [BRN ]
1209486 | [CAS DataBase Reference]
924-44-7(CAS DataBase Reference) | [EPA Substance Registry System]
924-44-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xn | [Risk Statements ]
R11:Highly Flammable.
R38:Irritating to the skin.
R43:May cause sensitization by skin contact.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R63:Possible risk of harm to the unborn child.
R65:Harmful: May cause lung damage if swallowed.
R67:Vapors may cause drowsiness and dizziness. | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label . | [RIDADR ]
UN 1294 3/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29183000 |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to slightly yellow solution | [Uses]
Ethyl glyoxylate is widely used as an intermediate in the synthesis of pharmaceuticals (high reactivity of aldehyde function). It is used in the synthesis of a biodegradable polymer, poly(ethyl glyoxylate). It is actively involved in the Friedel-Crafts alkylation reactions with thiophenes to give the corresponding secondary alcohols. | [Definition]
ChEBI: The ethyl ester of glyoxylic acid. | [Synthesis Reference(s)]
Tetrahedron Letters, 24, p. 2223, 1983 DOI: 10.1016/S0040-4039(00)81889-4 |
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