ChemicalBook--->CAS DataBase List--->7662-51-3

7662-51-3

7662-51-3 Structure

7662-51-3 Structure
IdentificationMore
[Name]

L-TYROSINE HYDRAZIDE
[CAS]

7662-51-3
[Synonyms]

H-TYR-NHNH2
L-TYROSINE HYDRAZIDE
L-tyrosinohydrazide
Tyrosinehydrazide
L-TYROSINE HYDRAZIDE 98%
[EINECS(EC#)]

231-631-1
[Molecular Formula]

C9H13N3O2
[MDL Number]

MFCD00007609
[Molecular Weight]

195.22
[MOL File]

7662-51-3.mol
Chemical PropertiesBack Directory
[Appearance]

white fine crystals
[Melting point ]

196-198 °C(lit.)
[Boiling point ]

331.89°C (rough estimate)
[density ]

1.1985 (rough estimate)
[refractive index ]

78 ° (C=5, 1mol/L HCl)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

almost transparency in 1mol/L HCl
[form ]

powder to crystal
[pka]

9.96±0.15(Predicted)
[color ]

White to Orange to Green
[Optical Rotation]

[α]20/D +76°, c = 4.2 in 1 M HCl
[BRN ]

2808635
[CAS DataBase Reference]

7662-51-3(CAS DataBase Reference)
[EPA Substance Registry System]

L-Tyrosine, hydrazide (7662-51-3)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36:Irritating to the eyes.
R43:May cause sensitization by skin contact.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

3
[TSCA ]

TSCA listed
[HS Code ]

29280000
Hazard InformationBack Directory
[Chemical Properties]

white fine crystals
[Uses]

Excellent reagent for the resolution of amino acids.
[Uses]

Resolving agent for various DL-amino acids
[reaction suitability]

reaction type: solution phase peptide synthesis
[Synthesis]

The synthesis of L-tyrosine hydrazide from L-tyrosine has been described. D-Tyrosine hydrazide has  been obtained by resolution of DL-tyrosine hydrazide with Cbz-L-proline.
[storage]

L-tyrosine hydrazide is stable in amber bottles, at room temperature, for indefinite periods of time. No special handling precautions have been described.
Spectrum DetailBack Directory
[Spectrum Detail]

L-TYROSINE HYDRAZIDE(7662-51-3)MS
L-TYROSINE HYDRAZIDE(7662-51-3)1HNMR
L-TYROSINE HYDRAZIDE(7662-51-3)13CNMR
L-TYROSINE HYDRAZIDE(7662-51-3)IR1
L-TYROSINE HYDRAZIDE(7662-51-3)IR2
L-TYROSINE HYDRAZIDE(7662-51-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

L-Tyrosine hydrazide, 98%(7662-51-3)
[Sigma Aldrich]

7662-51-3(sigmaaldrich)
[TCI AMERICA]

L-Tyrosine Hydrazide,>97.0%(T)(7662-51-3)
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