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77214-82-5

77214-82-5 Structure

77214-82-5 Structure
IdentificationMore
[Name]

Iron(III) p-toluenesulfonate
[CAS]

77214-82-5
[Synonyms]

Iron(III)p-toluenesulfonate
Benzenesulfonic acid, 4-methyl-, iron(3+) salt
IRON(III)-PARA-TOLUENESULPHONATE
4-Methyl-benzolsulfonsure, Eisen Salz
p-Toluenesulfonic acid, ferric salt
Iron (III) tris(4-methylbenzenesulfonate)
Iron(Ⅲ)p-toluenesulfonate
[EINECS(EC#)]

420-960-8
[Molecular Formula]

C21H21FeO9S3
[MDL Number]

MFCD01766290
[Molecular Weight]

569.43
[MOL File]

77214-82-5.mol
Chemical PropertiesBack Directory
[density ]

1.52 at 20℃
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Pellets
[Appearance]

Yellow to orange Solid
[InChI]

InChI=1S/C7H8O3S.Fe/c1-6-2-4-7(5-3-6)11(8,9)10;/h2-5H,1H3,(H,8,9,10);
[InChIKey]

LWLURCPMVVCCCR-UHFFFAOYSA-N
[SMILES]

S(C1C=CC(C)=CC=1)(O)(=O)=O.[Fe]
[Surface tension]

71.52mN/m at 1g/L and 20℃
[CAS DataBase Reference]

77214-82-5(CAS DataBase Reference)
[EPA Substance Registry System]

77214-82-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H318
[Precautionary statements ]

P280-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R41:Risk of serious damage to eyes.
[Safety Statements ]

S24:Avoid contact with skin .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HS Code ]

2904100090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

p-Toluenesulfonic acid-->Iron hydroxide
Hazard InformationBack Directory
[Chemical Properties]

Iron (III) p-toluenesulfonate, also known as Iron p-toluenesulfonate, is a red or orange solid powder. It is an oxidising agent for solid-state capacitors, readily soluble in water, ethanol and n-butanol, and is polymerised with EDOT in specific proportions to manufacture solid-state capacitors.
Iron(III) p-toluenesulfonate
[Uses]

Iron(III) p-toluenesulfonate is a conductive compound used as a dopant or a conductive coating in vapor phase polymerized conductive polymers.
[Application]

Iron(III) p-toluenesulfonate, Fe(OTs)3·6H2O, is an inexpensive, versatile and commercially available catalyst for the allylation of acetals using allyltrimethylsilane to yield homoallyl ethers in moderate to good yields[1].
[Preparation]

Iron(III) p-toluenesulfonate is prepared by reacting p-toluenesulphonic acid (PTS) with iron(III) hydroxide (Fe(OH)₃) under specific conditions.
[References]

[1] Spafford, M. J., Anderson, E. D., Lacey, J. R., Palma, A. C., Mohan, R. S. (2007). Iron(III) p-toluenesulfonate catalyzed synthesis of homoallyl ethers from acetals and aldehydes. Tetrahedron Letters, 48 49, Pages 8665-8667. https://doi.org/10.1016/j.tetlet.2007.10.026
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