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16836-95-6

16836-95-6 Structure

16836-95-6 Structure
IdentificationMore
[Name]

SILVER P-TOLUENESULFONATE
[CAS]

16836-95-6
[Synonyms]

4-TOLUENESULFONIC ACID SILVER SALT
P-TOLUENESULFONIC ACID SILVER SALT
SILVER 4-TOLUENESULFONATE
SILVER(I) P-TOLUENESULFONATE
SILVER(I) P-TOLUENESULPHONATE
SILVER P-TOLUENESULFONATE
SILVER TOLUENE-4-SULFONATE
SILVER TOSYLATE
TOLUENE-4-SULFONIC ACID SILVER SALT
4-methyl-benzenesulfonicacisilver(1++)salt
Silver(I) tosylate~p-Toluenesulphonic acid silver(I) salt
silver p-toluenesulphonate
SILVER P-TOLUENESULFONATE, 99+%
Benzenesulfonic acid, 4-methyl-, silver(1+) salt
p-toluenesulfonic acid silver(i) salt
silver(i) tosylate
Silver toluene-4-sulphonate
Silver(I) p-toluenesulfonate, 98+%
p-Toluenesulfonic acid silver salt, Silver tosylate
4-Methylbenzenesulfonic acid silver(I) salt
[EINECS(EC#)]

240-859-0
[Molecular Formula]

C7H7AgO3S
[MDL Number]

MFCD00007511
[Molecular Weight]

279.06
[MOL File]

16836-95-6.mol
Chemical PropertiesBack Directory
[Appearance]

WHITE TO LIGHT GREY CRYSTALLINE POWDER
[Melting point ]

264-266℃ (decomposition)
[storage temp. ]

below 5° C
[solubility ]

sol acetonitrile, diethyl ether, water
[form ]

powder
[Water Solubility ]

Soluble in water.
[Sensitive ]

Light Sensitive
[BRN ]

3598937
[InChIKey]

JUDUFOKGIZUSFP-UHFFFAOYSA-M
[CAS DataBase Reference]

16836-95-6(CAS DataBase Reference)
[EPA Substance Registry System]

Benzenesulfonic acid, 4-methyl-, silver(1+) salt (16836-95-6)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[F ]

8
[TSCA ]

No
[HazardClass ]

9
[HS Code ]

2843290000
Hazard InformationBack Directory
[Chemical Properties]

WHITE TO LIGHT GREY CRYSTALLINE POWDER
[Uses]

Silver p-toluenesulfonate is used to converts alkyl halides to tosylates, and benzyl selenyl chlorides into their corresponding selenyl tosylates. It used in promotion of the leaving ability of halogens. For use in the conversion of alkyl halides to alkyl tosylates.
[Preparation]

Silver p-toluenesulfonate can be prepared by mixing aqueous solutions of Silver(I) Nitrate and sodium tosylate and filtering off the precipitate.
[reaction suitability]

reagent type: catalyst
core: silver
[storage]

Silver p-toluenesulfonate should be protected from light.
[Purification Methods]

The anhydrous salt is obtained by recrystallisation from H2O. Store it in the dark. [Claesson & Wallin Chem Ber 12 1851 1879, Beilstein 11 H 97, 99.]
Spectrum DetailBack Directory
[Spectrum Detail]

SILVER P-TOLUENESULFONATE(16836-95-6)1HNMR
SILVER P-TOLUENESULFONATE(16836-95-6)FT-IR
SILVER P-TOLUENESULFONATE(16836-95-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Silver p-toluenesulfonate, 98+%(16836-95-6)
[Sigma Aldrich]

16836-95-6(sigmaaldrich)
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