ChemicalBook--->CAS DataBase List--->7783-48-4

7783-48-4

7783-48-4 Structure

7783-48-4 Structure
IdentificationMore
[Name]

Strontium fluoride
[CAS]

7783-48-4
[Synonyms]

STRONTIUM FLUORIDE
STRONTIUM (II) FLUORIDE
SrF2
Strontium fluoride (SrF2)
strontiumfluoride(srf2)
Strontiumfluoridemetalsbasiswhitepowder
Strontiumfluoridereagentwhitepowder
STRONTIUM FLUORIDE FOR GLASS INDUSTRY
STRONTIUM FLUORIDE, ANHYDROUS, POWDER, 9 9.99%
STRONTIUM FLUORIDE, PRECIPITATED, 99.99&
STRONTIUM FLUORIDE 99.99%
STRONTIUM FLUORIDE PURE
Strontiumfluoride,99%min
Strontiumfluoride,Puratronic?,99.99%(metalsbasis)
Strontiumfluoride,99%
Strontiumfluoride(99.99%-Sr)PURATREM
Strontiumfluoride,reagent,99%
strontium fluoride, puratronic
Strontium fluoride 99%
STRONTIUM FLUORIDE, REAGENT
[EINECS(EC#)]

232-000-3
[Molecular Formula]

F2Sr
[MDL Number]

MFCD00011251
[Molecular Weight]

125.62
[MOL File]

7783-48-4.mol
Chemical PropertiesBack Directory
[Appearance]

White powder
[Melting point ]

>1400 °C (lit.)
[Boiling point ]

2489 °C (lit.)
[density ]

4.24 g/mL at 25 °C(lit.)
[refractive index ]

1.442
[solubility ]

soluble in dilute acid solutions
[form ]

powder
[color ]

White
[Specific Gravity]

4.24
[Odor]

odorless
[Water Solubility ]

11.7 mg/100 mL (18 ºC)
[Specific Heat Capacity]

Cp(crystal):0.557236J/(g·K),at 25℃
[Crystal Structure]

CaF2 type
[Merck ]

14,8842
[Solubility Product Constant (Ksp)]

pKsp: 8.36
[Space group]

Fm3m
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.580.580.589090900.1947
[Dielectric constant]

6.4699999999999998
[Exposure limits]

ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
[Stability:]

hygroscopic
[InChI]

1S/2FH.Sr/h2*1H;/q;;+2/p-2
[InChIKey]

FVRNDBHWWSPNOM-UHFFFAOYSA-L
[SMILES]

F[Sr]F
[Uses]

Substitute for other fluorides, electronic and optical applications, single crystals for lasers, hightemperature dry-film lubricants.
[CAS DataBase Reference]

7783-48-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Strontium fluoride(7783-48-4)
[EPA Substance Registry System]

7783-48-4(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN3288
[WGK Germany ]

2
[RTECS ]

WK8925000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

2826199090
[Storage Class]

11 - Combustible Solids
[Safety Profile]

Moderately toxic by intravenous route. Mildly toxic by ingestion. When heated to decomposition it emits toxic fumes of F-. See also FLUORIDES and STRONTIUM COMPOUNDS.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrogen fluoride-->Strontium carbonate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Strontium fluoride(7783-48-4).msds
Questions And AnswerBack Directory
[Crystal System]

The space lattice of SrF2 belongs to the cubic system, and its calcium fluoride structure has a lattice constant of a=0.5781 nm and Sr–F=0.2504 nm. The cleavage plane is (111)—that is, octahedron is formed by the cleavage.
Hazard InformationBack Directory
[Chemical Properties]

Strontium fluoride, also called strontium difluoride and strontium(II) fluoride, is a fluoride of strontium. It is a stable brittle white crystalline solid. It forms face-centered cubic crystals, with structure of calcium fluoride. It is almost insoluble in water. Strontium fluoride is prepared by reaction of strontium chloride with fluorine gas, by action of hydrofluoric acid on strontium carbonate, or by addition of potassium chloride to strontium chloride solution. It irritates eyes and skin, and is harmful when inhaled or ingested.
[Chemical Properties]

White powder. Soluble in hydrochloric acid and hydrogen fluoride; insoluble in water.
[Physical properties]

Strontium fluoride, SrF2, also called "strontium difluoride" and "strontium (II) fluoride", is a stable, brittle, white crystalline solid with a melting point of 1477°C and a boiling point of 2460°C. Its molecular weight is 125.62 g/mol. Its density is 4.24 g/cm3. Its melting point has also been given as 1463°C and a boiling point of 2489°C. It is virtually insoluble since its solubility in water is 0.00012 g/100 ml of water at 18°C.
SrF2 is almost insoluble in water (its KSP value is approximately 4.33×109 at 25°C. It irritates eyes and skin, and is harmful when inhaled or ingested.
[Preparation]

Strontium fluoride can be prepared by the reaction of strontium chloride with fluorine gas, or by action of hydrofluoric acid on strontium carbonate:
SrCl2 (aq)+ F2 (gas)→SrF2 (solid)+ Cl2 (gas)
SrCO3+ 2HF→SrF2+ CO2+H2O
Note that the first reaction depends upon the insolubility of SrF2 in water. Strontium fluoride is a water-insoluble source for use in oxygen-sensitive applications, such as metal production since it in nonhygroscopic.
[Hazard]

Toxic material.
[Flammability and Explosibility]

Notclassified
Spectrum DetailBack Directory
[Spectrum Detail]

Strontium fluoride(7783-48-4)IR1
Strontium fluoride(7783-48-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Strontium fluoride, Puratronic, 99.99% (metals basis)(7783-48-4)
[Sigma Aldrich]

7783-48-4(sigmaaldrich)
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