ChemicalBook--->CAS DataBase List--->7790-76-3

7790-76-3

7790-76-3 Structure

7790-76-3 Structure
IdentificationMore
[Name]

CALCIUM PYROPHOSPHATE
[CAS]

7790-76-3
[Synonyms]

CALCIUM DIPHOSPHATE
CALCIUM PHOSPHATE (PYRO)
CALCIUM PYROPHOSPHATE
CPP
DICALCIUM PYROPHOSPHATE
calciumphosphate(ca2p2o7)
calciumpyrophosphate(ca2p2o7)
Diphosphoricacid,calciumsalt
diphosphoricacid,calciumsalt(1:2)
pyrophosphoricacid,calciumsalt(1:2)
pyrophosphoric acid calcium salt
PYROPHOSPHATE DICALCIUM PRACTICAL*GRADE: ANHYDROUS
CALCIUM PYROPHOSPHATE, 99.9+%
CALCIUM PYROPHOSPHATE, 99.98%
Calciumpyrophosphate(99.95%-Ca)
DICALCIUMPYROPHOSPHATEANHYDROUS
DICALCIUMDIPHOSPHATE
CALCIUM PYROPHOSPHATE: (99.95% CA), (PHOSPHOR GRADE)
Calcium phosphate (pyro), 96% min
Calcium phosphate, amorphous
[EINECS(EC#)]

232-221-5
[Molecular Formula]

Ca2O7P2
[MDL Number]

MFCD00015983
[Molecular Weight]

254.1
[MOL File]

7790-76-3.mol
Chemical PropertiesBack Directory
[Appearance]

white powder
[Melting point ]

1230 °C
[density ]

3.09 g/mL at 25 °C(lit.)
[solubility ]

H2O: insoluble(lit.)
[form ]

Powder
[color ]

White
[Specific Gravity]

3.09
[Odor]

at 100.00?%. odorless
[Water Solubility ]

Soluble in hydrochloric acid and nitric acid. Insoluble in water.
[LogP]

-3.420 (est)
[Uses]

Calcium Pyrophosphate is a nutrient and dietary supplement that exists as a white odorless powder, insoluble in water. it is used in dental impression materials and as a buffer.
[CAS DataBase Reference]

7790-76-3(CAS DataBase Reference)
[EPA Substance Registry System]

Diphosphoric acid, calcium salt (1:2) (7790-76-3)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

28353100
[Hazardous Substances Data]

7790-76-3(Hazardous Substances Data)
Hazard InformationBack Directory
[Description]

Calcium pyrophosphate has the molecular formula of Ca2P2O7 and the molecular weight of 254.1378 g/mol. It has the CAS number of 7790-76-3. It may be prepared by the solid-state reaction of the dibasic orthophosphate, or alternately by the precipitation of a soluble Ca salt with aqueous pyrophosphoric acid:
2CaHPO4 + heat ? Ca2P2O7 +H2O
CaCl2 (aq) +H4P2O7 (aq) ? Ca2P2O7 (solid) + 2HCl (aq)
The solid-state reaction produces an amorphous crystal at 240–500°C. b-Ca2P2O7 forms >750°C and a-Ca2P2O7 forms in the temperature range of 1140 to 1350°C. The free energy of formation, △Gf=-3132 kcal/mol.
The product of the aqueous method is the dihydrate, Ca2P2O7·2H2O. It is a white powder and has the CAS number of 7790-76-3. It is insoluble in water but soluble in dilute acids. The anhydrate decomposes at 1353°C to form a metaphosphate:
Ca2P2O7 + heat ? Ca(PO3)2 + CaO
Calcium pyrophosphate is dimorphic. The phase transformation and sintering behaviors of Ca2P2O7 with different phase composition has been investigated by using X-ray powder diffraction (XRD), dilatometery and SEM techniques. It was found that although α-Ca2P2O7 (high-temperature form) could be maintained during its cooling process, it was metastable and retransformed into β-Ca2P2O7 (low-temperature form) at about 950 °C during its reheating process.
[Chemical Properties]

white powder
[Definition]

ChEBI: Calcium diphosphate is a calcium phosphate. It contains a diphosphate(4-).
[Flammability and Explosibility]

Nonflammable
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Calcium pyrophosphate, extra pure, 99.9+%(7790-76-3)
[Alfa Aesar]

Calcium phosphate (pyro), 96% min(7790-76-3)
[Sigma Aldrich]

7790-76-3(sigmaaldrich)
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