ChemicalBook--->CAS DataBase List--->79-92-5

79-92-5

79-92-5 Structure

79-92-5 Structure
IdentificationMore
[Name]

Camphene
[CAS]

79-92-5
[Synonyms]

2,2-DIMETHYL-3-METHYLENE-BICYCLO[2.2.1]HEPTANE
2,2-DIMETHYL-3-METHYLENENORBORNANE
3,3-DIMETHYL-2-METHYLENENORCAMPHANE
AKOS NCG1-0107
(+/-)-CAMPHENE
CAMPHENE
CAMPHENE 46
CAMPHENE 90
D,L-CAMPHENE
FEMA 2229
2,2-dimethyl-3-methylene-bicyclo(2.2.1)heptan
2,2-dimethyl-3-methylene-bicyclo[2.2.1]heptan
3,3-Dimethyl-2-methylenenorbornane
3,3-dimethyl-2-methylenenorcamphene
Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-
camphene(2,2-dimethyl-3-methylene-norbornane)
NA 9011
CAMPHENE P&F FCC
CAMPHENE, 1000MG, NEAT
Camphene,~80%
[EINECS(EC#)]

201-234-8
[Molecular Formula]

C10H16
[MDL Number]

MFCD00066603
[Molecular Weight]

136.23
[MOL File]

79-92-5.mol
Chemical PropertiesBack Directory
[Appearance]

Camphene is a colorless to white crystalline solid, Camphor, or turpentine odor. It may be shipped as a liquid. Freezing/Melting point 5 50C.
[Melting point ]

48-52 °C (lit.)
[Boiling point ]

159-160 °C (lit.)
[density ]

0.85 g/mL at 25 °C(lit.)
[vapor pressure ]

3.99 hPa (20 °C)
[FEMA ]

2229
[refractive index ]

1.4551
[Fp ]

94 °F
[storage temp. ]

Flammables area
[solubility ]

0.0042g/l
[form ]

Crystalline Low Melting Solid
[color ]

White
[Specific Gravity]

0.85
[Odor]

at 10.00 % in dipropylene glycol. woody herbal fir needle camphor terpenic
[PH]

5.5 (H2O, 22℃)(saturated aqueous solution)
[Odor Threshold]

0.88ppm
[Odor Type]

woody
[Water Solubility ]

practically insoluble
[JECFA Number]

1323
[Merck ]

1730
[Dielectric constant]

2.7(20℃)
[InChIKey]

CRPUJAZIXJMDBK-DTWKUNHWSA-N
[LogP]

4.22 at 20℃
[Uses]

Manufacture of synthetic camphor, camphor substitute.
[CAS DataBase Reference]

79-92-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Camphene(79-92-5)
[EPA Substance Registry System]

79-92-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F
[Risk Statements ]

R11:Highly Flammable.
R10:Flammable.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S33:Take precautionary measures against static discharges .
[RIDADR ]

UN 1325 4.1/PG 2
[WGK Germany ]

2
[RTECS ]

EX1055000
[Autoignition Temperature]

265 °C
[HazardClass ]

4.1
[PackingGroup ]

III
[HS Code ]

29021990
[Safety Profile]

Mutation data reported. Combustible; yields flammable vapors when heated and can react with oxidizing materials. To fight fire, use water spray, foam, fog, CO2. When heated to decomposition it emits acrid smoke and irritating fumes.
[Hazardous Substances Data]

79-92-5(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Turpentine oil-->Metatitanic acid-->Rutile-->ALPHA-PINENE-->alpha-Pinene-->GAMMA-TERPINENE-->DL-Limonene-->Acetic acid
[Preparation Products]

Terpinyl cyclohexanol mixture-->2-Bornene-->Terpinolene
Hazard InformationBack Directory
[General Description]

A colorless to white crystalline solid with an insipid camphor-like odor. Dust and crystals are irritants to the eyes, nose and throat. Emits flammable vapors when heated. Emits acrid smoke and irritating fumes at high temperature. Used for the manufacture of synthetic camphor.
[Reactivity Profile]

CAMPHENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.
[Hazard]

Toxic by ingestion.
[Health Hazard]

Inhalation causes irritation of nose and throat. Contact with eyes or skin causes irritation.
[Potential Exposure]

Camphene is used to manufacture synthetic camphor; for making moth-proofing and in the cosmetics, perfume, and food flavoring industries.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit
[Shipping]

UN1325 Flammable solids, organic, n.o.s., Hazard Class: 4.1; Labels: 4.1-Flammable solid. UN2319 Terpene hydrocarbons, n.o.s., Hazard Class: 3; Labels: 3- Flammable liquid
[Incompatibilities]

Forms explosive mixture with air. Emulsions in xylene may violently decompose on contact with iron or aluminum above 70C. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with reducing agents may cause exothermic reaction, releasing flammable hydrogen gas
[Description]

Camphene is a colorless to white crystallinesolid with camphor-like odor. It may be shipped as a liquid.Freezing/Melting point=50℃. Molecular weight=136.24;Boiling point=159℃; Melting point=37℃; Flashpoint=42℃ (oc); 33℃ (cc). Hazard Identification (basedon NFPA-704 M Rating System): Health 2, Flammability 3,Reactivity 0. Insoluble in water.
[Chemical Properties]

Camphene has a terpene, camphoraceous taste.
[Chemical Properties]

Camphene is a colorless to white crystalline solid, Camphor, or turpentine odor. It may be shipped as a liquid. Freezing/Melting point 5 50C.
[Chemical Properties]

WHITE CRYSTALLINE LOW MELTING SOLID
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
[Occurrence]

Reported found in carrot, dill, fennel, marjoram, nutmeg, parsley, pepper, tarragon and thyme.
[Definition]

ChEBI: A monoterpene with a bicyclic skeleton that is bicyclo[2.2.1]heptane substituted by geminal methyl groups at position 2 and a methylidene group at position 3. It is a widespread natural product found in many essential oils.
[Preparation]

From pinene by catalytic isomerization or from bornyl chloride by heating with alkali in the presence of abietenesulfonic acid.
[Aroma threshold values]

Detection at 10%: camphoraceous, cooling, piney woody with terphy nuances. It has citrus and green minty and green spicy notes.
[Taste threshold values]

Taste characteristics at 50–100 ppm: camphoraceous, cooling, minty, with citrus and green spicy nuances.
[Flammability and Explosibility]

Flammable
[Pharmacology]

Oral administration of camphene (260 mmols/kg) to rats increased bile flow by 50% 4 hr after administration (M?rsdorf, 1966). Development of atheromatosis of the aorta in rabbits fed 1 g cholesterol/day for 3 months was considerably inhibited by simultaneous administration of a mixture of terpenes including camphene, injected sc in a dose of 1 ml every other day for 6 wk and then given orally in doses of 2 ml/day (Benk?, Macher, Szarvas & Tiboldi, 1961). The effect of 1 g cholesterol/day for 8 wk in the diet of rabbits in increasing the number and volume of mast cells in the aortic adventitia and increasing the total lipid content of the aortic wall was slightly enhanced by the simultaneous addition of 11 g camphene/day (Lesznyak, Benko, Szabo & Muller, 1972). This camphene treatment also decreased the lipid accumulation in the liver, but had no effect on the cholesterol-induced atheromatosis of the aorta (Benko, Szabo, Muller & Lesznyak, 1972).
[Anticancer Research]

This was tested against melanoma cells in a syngeneic model, and there was promisingantitumor activity (Ma et al. 2016).
[storage]

Color Code—Red: Flammability Hazard: Storein a flammable liquid storage area or approved cabinetaway from ignition sources and corrosive and reactivematerials. Prior to working with camphene you shouldbe trained on its proper handling and storage. Camphenemust be stored to avoid contact with strong oxidizers(such as chlorine, bromine, and fluorine) since violentreactions occur. Store in tightly closed containers in acool, well-ventilated area. Sources of ignition, such assmoking and open flames, are prohibited where Campheneis used, handled, or stored in a manner that could create apotential fire or explosion hazard. Use only nonsparkingtools and equipment, especially when opening and closingcontainers of camphene.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

camphene(79-92-5).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Camphene(79-92-5)MS
Camphene(79-92-5)1HNMR
Camphene(79-92-5)13CNMR
Camphene(79-92-5)IR1
Camphene(79-92-5)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Camphene, remainder mainly alpha-fenchene, 75%(79-92-5)
[Sigma Aldrich]

79-92-5(sigmaaldrich)
[TCI AMERICA]

(+/-)-Camphene  (contains ca. 20% Tricyclene),>78.0%(GC)(79-92-5)
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