ChemicalBook--->CAS DataBase List--->83076-07-7

83076-07-7

83076-07-7 Structure

83076-07-7 Structure
IdentificationBack Directory
[Name]

Chloro[tri(o-tolyl)phosphine]gold(I)
[CAS]

83076-07-7
[Synonyms]

Chloro(tri-o-tolylphosphine)gold
Chloro(tris(2-tolyl)phosphine)gold
Chloro[tris(o-tolyl)phosphine]gold
(Tri-o-tolylphosphine)gold chloride
Chloro[tri(o-tolyl)phosphine]gold(I)
chloro-tris(2-methylphenyl)phosphanium
Chloro[tri(o-tolyl)phosphine]gold(I),95%
Chloro(tri(2-methylphenyl)phosphine)gold
Chloro[tris(2-methylphenyl)phosphine]gold
Chloro[tris(o-methylphenyl)phosphine]gold
Tris(2-methylphenyl)phosphinegold chloride
[Molecular Formula]

C21H20AuClP+
[MDL Number]

MFCD14155882
[MOL File]

83076-07-7.mol
[Molecular Weight]

535.777
Chemical PropertiesBack Directory
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

solid
[Appearance]

White to off-white Solid
[InChI]

1S/C21H21P.Au.ClH/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;/h4-15H,1-3H3;;1H/q;+1;/p-1
[InChIKey]

VECXLHSTZNCQLD-UHFFFAOYSA-M
[SMILES]

Cl[Au].Cc1ccccc1P(c2ccccc2C)c3ccccc3C
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Gold Catalysts — 21st Century ′Gold Rush′
Catalyst for:
  • Alkylation of silyl enol ethers with orthoalkynylbenzoic acid esters
  • Cycloisomerization
  • Cyclization of 1,6-enynes
  • Tandem [3,3]-sigmatropic rearrangement-cycloisomerization cascade
  • Cycloaddition of enyne derivatives with aryl alkynes or alkenes
[reaction suitability]

core: gold
reagent type: catalyst
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