| Identification | Back Directory | [Name]
(2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& | [CAS]
854045-93-5 | [Synonyms]
JohnPhos AuCl Au(JohnPhos)Cl (2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& Chloro[2-(di-t-butylphosphino)biphenyl]gold(I),99% Chloro[2-(di-t-butylphosphino)biphenyl]gold(I),98% Chloro(di-tert-butyl(2-phenylphenyl)phosphine)gold Chloro[2-(di-t-butylphosphino)biphenyl]gold(I), 99% (2-Biphenyl)di-tert-butylphosphine gold(I) chloride 2-(Di-tert-butylphosphino)biphenyl gold(I) chloride 1,1''-BIPHENYL]-2-YLBIS(T-BUTYLPHOSPHINE]CHLOROGOLD Chloro[(1,1μ-biphenyl-2-yl)di-tert-butylphosphine]gold(I) Chloro[2-(di-t-butylphosphino))-1,1'-biphenyl]gold(I), 99% Gold,[[1,1'-biphenyl]-2-ylbis(1,1-diMethylethyl)phosphine]chloro- (2-Biphenyl)di-tert-butylphosphine gold(I) chloride, 2-(Di-tert-butylphosphino)biphenyl gold(I) chloride, [[1,1μ-Biphenyl]-2-ylbis(t-butylphosphine]chlorogold | [Molecular Formula]
C20H27P.AuCl | [MDL Number]
MFCD09265131 | [MOL File]
854045-93-5.mol | [Molecular Weight]
530.83 |
| Chemical Properties | Back Directory | [Melting point ]
237-240 °C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
white | [InChI]
1S/C20H27P.Au.ClH/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;;/h7-15H,1-6H3;;1H/q;+1;/p-1 | [InChIKey]
MZMOUYZCJIFYAH-UHFFFAOYSA-M | [SMILES]
Cl[Au].CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C |
| Questions And Answer | Back Directory | [Reaction]
- Highly active gold catalyst for the intramolecular exohydrofunctionalization of allenes.
- Catalyst used for the hydroarylation of allenes.
- Catalyst used for the intramolecular cyclization of monopropargyl triols.
- Synthesis of pyrroles via a gold-catalyzed cascade reaction.
- Gold-catalyzed carboalkoxylations of 2-ethynylbenzyl ethers.
- Gold-catalyzed annulations of allenes with N-hydroxy anilines.

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