| Identification | More | [Name]
Diphenyl phosphate | [CAS]
838-85-7 | [Synonyms]
DIPHENYL PHOSPHATE
PHOSPHORIC ACID DIPHENYL ESTER
PHOSPHORIC ACID DIPLHENYL ESTER
diphenylhydrogenphosphate
phenylphosphate((pho)2(ho)po)
Diphenyl phosphate, 98+%
DIPHENYLPHOSPHINE, 20% in heptane
Phosphoric acid diphenyl
Phosphoric acid hydrogen diphenyl ester
Biphenyl Ester | [EINECS(EC#)]
212-657-2 | [Molecular Formula]
C12H11O4P | [MDL Number]
MFCD00003033 | [Molecular Weight]
250.19 | [MOL File]
838-85-7.mol |
| Chemical Properties | Back Directory | [Appearance]
white crystalline powder | [Melting point ]
62-66 °C (lit.) | [Boiling point ]
280°C | [density ]
0,76 g/cm3 | [refractive index ]
1.6250 | [Fp ]
4°C | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Crystalline Powder | [pka]
1.12±0.50(Predicted) | [color ]
White | [Water Solubility ]
Soluble in benzene. Insoluble in water. | [BRN ]
1379164 | [InChI]
1S/C12H11O4P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H,(H,13,14) | [InChIKey]
ASMQGLCHMVWBQR-UHFFFAOYSA-N | [SMILES]
OP(=O)(Oc1ccccc1)Oc2ccccc2 | [CAS DataBase Reference]
838-85-7(CAS DataBase Reference) | [EPA Substance Registry System]
838-85-7(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P271-P280 | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [RTECS ]
TC5470000
| [TSCA ]
Yes | [HS Code ]
29190090 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
white crystalline powder | [Uses]
Diphenyl Phosphate is an organophosphate diester and metabolite of the flame retardant Triphenyl Phosphate (T808990) and also a metabolite of 2-Ethylhexyl diphenyl phosphate. | [Definition]
ChEBI: Diphenyl phosphate is an aryl phosphate. | [Purification Methods]
Crystallise it from CHCl3/pet ether. [Cherbuliez in Organo Phosphorus Compounds (Kosolapoff & Maier eds) Wiley Vol 6 pp 211-577 1973, Beilstein 6 IV 714.] | [Toxics Screening Level]
The initial threshold screening level (ITSL) for diphenyl phosphoric acid is 0.1 μg/m3 based on annual averaging time. | [References]
[1] XIAO YAN . Urinary metabolites of phosphate flame retardants in workers occupied with e-waste recycling and incineration[J]. Chemosphere, 2018, 200: Pages 569-575. DOI:10.1016/j.chemosphere.2018.02.148.
[2] MITSUO SAWAMOTO Toshinobu H Masami Kamigaito. Living cationic polymerization of isobutyl vinyl ether by the diphenyl phosphate/zinc iodide initiating system[J]. Polymer Bulletin, 1988, 20 5: 407-412. DOI:10.1007/BF01153430. |
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