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84127-04-8

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84127-04-8 Structure

84127-04-8 Structure
IdentificationBack Directory
[Name]

Bis(4-methoxyphenyl)phosphine
[CAS]

84127-04-8
[Synonyms]

Bis(4-methoxyphenyl)phosphine
Phosphine, bis(4-methoxyphenyl)-
[Molecular Formula]

C14H15O2P
[MDL Number]

MFCD15143653
[MOL File]

84127-04-8.mol
[Molecular Weight]

246.24
Chemical PropertiesBack Directory
[Melting point ]

36-40°C
[Boiling point ]

352.4±42.0 °C(Predicted)
[Fp ]

>110℃
[form ]

solid
[InChI]

1S/C14H15O2P/c1-15-11-3-7-13(8-4-11)17-14-9-5-12(16-2)6-10-14/h3-10,17H,1-2H3
[InChIKey]

FWKICRREDMVWRF-UHFFFAOYSA-N
[SMILES]

COc1ccc(Pc2ccc(OC)cc2)cc1
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Warning
[Hazard statements ]

H228-H315-H319-H335
[Precautionary statements ]

P210-P261-P305+P351+P338
[Hazard Codes ]

F
[Risk Statements ]

11-36/37/38
[Safety Statements ]

26-36
[RIDADR ]

1325
[WGK Germany ]

3
[HazardClass ]

4.1
[PackingGroup ]

Ⅱ
[Storage Class]

4.1B - Flammable solid hazardous materials
[Hazard Classifications]

Eye Irrit. 2
Flam. Sol. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Reactant for:
  • Enantioselective Ir-catalyzed hydrogenation
  • Palladium-catalyzed asymmetric additions
  • Alkali-metal-catalyzed addition reactions
  • Preparation of different DIOP-type ligands for uses in Rh-catalyzed asymmetric hydrogenation
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reagent type: ligand
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