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85-85-8

85-85-8 Structure

85-85-8 Structure
IdentificationMore
[Name]

1-(2-Pyridylazo)-2-naphthol
[CAS]

85-85-8
[Synonyms]

1-(2-PYRIDYLAZO)-2-NAPHTHOL
A-(2-PYRIDINEAZO)-B-NAPHTHOL
PAN
PAN-2
PAN INDICATOR
TIMTEC-BB SBB009111
1-(2-pyridinylazo)-2-Naohthalenol
1-(2-pyridinylazo)-2-naphthaleno
1-(2-Pyridylazo)-2-Hydroxynaphthalene
1-[(E)-2-Pyridinyldiazenyl]-2-naphthol
2-Hydroxy-1-(2-pyridylazo)naphthalene
2-Naphthol, 1-(2-pyridylazo)-
1-(2-Pyridylazo)-2-naphtol
1-(2-PYRIDYLAZO)-2-NAPHTHOL, A.C.S. REAG ENT
1-(2-PYRIDYLAZO)-2-NAPHTHOL, INDICATOR G RADE
1-(2-PYRIDYLAZO)-2-NAPHTHOL INDICATOR FO R METAL TITRATION
1-(2-Pyridylazo)-2-NaphtholA.R.(Pan)
PanIndicatorGr-(1-(2-Pyridylazo)-2-Naphthol)
PanIndicatorGr
(2-PyridylAzo)-2-Naphthol
[EINECS(EC#)]

201-637-9
[Molecular Formula]

C15H11N3O
[MDL Number]

MFCD00004071
[Molecular Weight]

249.27
[MOL File]

85-85-8.mol
Chemical PropertiesBack Directory
[Appearance]

orange crystals
[Melting point ]

138-141 °C (lit.)
[Boiling point ]

392.37°C (rough estimate)
[bulk density]

190kg/m3
[density ]

1.1469 (rough estimate)
[refractive index ]

1.5700 (estimate)
[storage temp. ]

Store at +5°C to +30°C.
[form ]

Powder/Solid
[pka]

8.86±0.50(Predicted)
[color ]

green to red, upon chelation with metal
[Stability:]

Stable. Incompatible with strong oxidizing agents, strong bases.
[Water Solubility ]

Insoluble
[ε(extinction coefficient)]

≥15000 at 462-468nm in methanol at 0.01g/L
>35,000 at 222-228nm in methanol at 0.01g/L
>9,000 at 300-306nm in methanol at 0.01g/L
[λmax]

461-465 nm in ethanol
[BRN ]

206390
[CAS DataBase Reference]

85-85-8(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Naphthalenol, 1-(2-pyridinylazo)-(85-85-8)
[EPA Substance Registry System]

85-85-8(EPA Substance)
Questions And AnswerBack Directory
[Uses]

1-(2-Pyridylazo)-2-naphthol is an indicator of transition metals. 1-(2-Pyridylazo)-2-naphthol is an indicator in complexometry and a reagent for the extraction and spectrophotometric determination of many transition metals. Dyes and metabolites.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

29333999
[Hazardous Substances Data]

85-85-8(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Carbon dioxide-->Sodium cyanide-->Cyclohexane-->2-Aminopyridine-->Ethyl nitrite-->3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride
[Preparation Products]

CARAMEL-->polyaniline composite film
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-(2-Pyridylazo)-2-naphthol(85-85-8).msds
Hazard InformationBack Directory
[Chemical Properties]

orange crystals
[Definition]

ChEBI:1-(2-pyridin-2-yldiazenyl)-2-naphthol is a member of naphthols.
[General Description]

1-(2-Pyridylazo)-2-naphthol (PAN), an orange colored dye, is commonly used as an acid-base indicator. It can form chelates with metal ions, which makes it a valuable indicator in complexometric titrations. PAN is also a spectrophotometric reagent, which can extract metal chelates into an organic solvent.
[Agricultural Uses]

1-(2-Pyridylazo)-2-naphthol is a hard stratum of strongly compacted soil caused by continual plowing to the same depth of hardened soil which has high clay content. The precipitated iron and silicates cement the soil particles and form pans. 1-(2-Pyridylazo)-2-naphthol often impede drainage and root growth. It can be broken up using a subsoiler .
[Purification Methods]

Purify PAN by repeated crystallisation from EtOH or MeOH. It can also be purified by sublimation under vacuum. Purity can be checked by TLC using a mixed solvent (pet ether/Et2O/EtOH; 10:10:1) on a silica gel plate. It has pK1 1.9 and pK2 12.2 in 20% aqueous ethoxyethanol. It chelates with copper [Pease & Williams Anal Chem 31 1046 1959]. [Beilstein 22 I 694, 22 III/IV 7073, 22/4 V 618.]
Spectrum DetailBack Directory
[Spectrum Detail]

1-(2-Pyridylazo)-2-naphthol(85-85-8)MS
1-(2-Pyridylazo)-2-naphthol(85-85-8)1HNMR
1-(2-Pyridylazo)-2-naphthol(85-85-8)13CNMR
1-(2-Pyridylazo)-2-naphthol(85-85-8)IR1
1-(2-Pyridylazo)-2-naphthol(85-85-8)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-(2-Pyridylazo)-2-naphthol, indicator grade, pure, 98%(85-85-8)
[Alfa Aesar]

1-(2-Pyridylazo)-2-naphthol, 99%(85-85-8)
[Sigma Aldrich]

85-85-8(sigmaaldrich)
[TCI AMERICA]

PAN  [=1-(2-Pyridylazo)-2-naphthol] [Metal indicator and spectrophotometric reagent for transition metals],>98.0%(T)(85-85-8)
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