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865-52-1

865-52-1 Structure

865-52-1 Structure
IdentificationMore
[Name]

TETRAMETHYLGERMANE
[CAS]

865-52-1
[Synonyms]

GERMANIUM TETRAMETHYL
TETRAMETHYLGERMANE
TETRAMETHYLGERMANIUM
(CH3)4Ge
tetramethyl-germaniu
tl81
Tetralmethylgermanium
TETRAMETHYLGERMANIUM SOLUTION, ~2.9 M IN THF
Tetramethylgermanium,98%
Tetramethylgermane,99%
Tetramethylgermanium solution
[EINECS(EC#)]

212-745-0
[Molecular Formula]

C4H12Ge
[MDL Number]

MFCD00014843
[Molecular Weight]

132.78
[MOL File]

865-52-1.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to slightly yellow liquid
[Melting point ]

-88 °C (dec.) (lit.)
[Boiling point ]

43-44 °C/740 mmHg (lit.)
[density ]

0.978 g/mL at 25 °C(lit.)
[vapor pressure ]

6.74 psi ( 20 °C)
[refractive index ]

n20/D 1.389(lit.)
[Fp ]

−35 °F
[storage temp. ]

Flammables area
[form ]

liquid
[color ]

colorless
[Specific Gravity]

0.978
[Water Solubility ]

Not miscible or difficult to mix in water.
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[Dielectric constant]

1.8200000000000001
[InChI]

InChI=1S/C4H12Ge/c1-5(2,3)4/h1-4H3
[InChIKey]

ZRLCXMPFXYVHGS-UHFFFAOYSA-N
[SMILES]

[Ge](C)(C)(C)C
[CAS DataBase Reference]

865-52-1(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

R11:Highly Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36:Irritating to the eyes.
R36/37:Irritating to eyes and respiratory system .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

3
[RTECS ]

LY5345000
[TSCA ]

No
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

2931900090
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to slightly yellow liquid
[Uses]

CVD precursor to germanium oxide thin films.
[Uses]

CVD precursor to germanium oxide thin films.1
[Uses]

Employed as a Chemical Vapor Deposition (CVD) precursor to germanium oxide thin films.
[reaction suitability]

core: germanium
[Synthesis]

Tetramethylgermane can be made by reacting tetrachlorogermane and methylmagnesium chloride.

It is also feasible to use dimethylzinc or dimethylcadmium instead of methylmagnesium chloride.

Spectrum DetailBack Directory
[Spectrum Detail]

Tetramethylgermane(865-52-1)MS
Tetramethylgermane(865-52-1)1HNMR
Tetramethylgermane(865-52-1)13CNMR
Tetramethylgermane(865-52-1)IR1
Tetramethylgermane(865-52-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Tetramethylgermanium, 98%(865-52-1)
[Sigma Aldrich]

865-52-1(sigmaaldrich)
[TCI AMERICA]

Tetramethylgermane,>98.0%(GC)(865-52-1)
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