ChemicalBook--->CAS DataBase List--->597-63-7

597-63-7

597-63-7 Structure

597-63-7 Structure
IdentificationMore
[Name]

TETRAETHYLGERMANE
[CAS]

597-63-7
[Synonyms]

GERMANIUM TETRAETHYL
TETRAETHYLGERMANE
TETRAETHYLGERMANIUM
(C2H5)4Ge
tetraethyl-german
tetraethyl-germaniu
Tetraethylgermane,99%
TETRAETHYLGERMANIUM LIQ
[EINECS(EC#)]

209-905-7
[Molecular Formula]

C8H20Ge
[MDL Number]

MFCD00015096
[Molecular Weight]

188.88
[MOL File]

597-63-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Melting point ]

-90 °C
[Boiling point ]

163-164 °C(lit.)
[density ]

0.998 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.442(lit.)
[Fp ]

95 °F
[storage temp. ]

Flammables area
[form ]

liquid
[color ]

colorless
[Specific Gravity]

1.1989
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[Dielectric constant]

1.97
[InChI]

InChI=1S/C8H20Ge/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H3
[InChIKey]

QQXSEZVCKAEYQJ-UHFFFAOYSA-N
[SMILES]

[Ge](CC)(CC)(CC)CC
[CAS DataBase Reference]

597-63-7(CAS DataBase Reference)
[EPA Substance Registry System]

Germane, tetraethyl- (597-63-7)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Warning
[Hazard statements ]

H226-H302-H315-H319-H335
[Precautionary statements ]

P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
[Hazard Codes ]

Xn
[Risk Statements ]

R10:Flammable.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[RTECS ]

LY5290000
[TSCA ]

Yes
[HS Code ]

2931.90.9051
[HazardClass ]

3
[PackingGroup ]

III
Questions And AnswerBack Directory
[Description]

Tetraethylgermanium is a kind of organic germanium compounds. Germanium shares the group 14 with silicon, tin and lead in the periodic table. Though having limited synthetic value due to the cost of organic germanium compounds, germanium is considered as a non-toxic alternative of many toxic organotin reagents. Compounds such as d tetraethylgermanium are used as precursors for germanium dioxide chemical vapor deposition in the microelectronics industry, being useful in the manufacturing of semiconductor films.
[Sources]

www.newworldencyclopedia.org/entry/Germanium
https://en.wikipedia.org/wiki/Tetraethylgermane
https://www.google.com/patents/US3211583
Hazard InformationBack Directory
[Chemical Properties]

clear colorless liquid
[Uses]

Tetraethylgermane is used in the microsomal metabolic studies of the organometallic derivatives of the group-??IV elements.
[Synthesis]

Produced by reacting germanium tetrabromide with ethylmagnesium bromide or ethyl lithium in ether, or by heating germanium halide with triethylaluminum and sodium chloride to 80-130°C.

Spectrum DetailBack Directory
[Spectrum Detail]

TETRAETHYLGERMANE(597-63-7)MS
TETRAETHYLGERMANE(597-63-7)1HNMR
TETRAETHYLGERMANE(597-63-7)13CNMR
TETRAETHYLGERMANE(597-63-7)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Tetraethylgermanium, 99%(597-63-7)
[Sigma Aldrich]

597-63-7(sigmaaldrich)
[TCI AMERICA]

Tetraethylgermane,>98.0%(GC)(597-63-7)
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