| Identification | More | [Name]
(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER | [CAS]
88568-95-0 | [Synonyms]
(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
(+/-)-CBZ-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
DL-Z-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
(+/-)-METHYL 2-BENZYLOXYCARBONYLAMINO-2-(DIMETHOXYPHOSPHINYL)ACETATE
N-(BENZYLOXYCARBONYL)-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
N-BENZYLOXYCARBONYLPHOSPHONOGLYCINE TRIMETHYL ESTER
N-BENZYLOXYCARBONYL TRIMETHYLPHOSPHONOGLYCINE
N-CBZ-2-METHYL (DIMETHYLPHOSPHONO) GLYCINATE
N-Z-PHOSPHONOGLYCINE TRIMETHYL ESTER
(+/-)-TRIMETHYL Z-ALPHA-PHOSPHONOGLYCINATE
(+/-)-Z-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
Z-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
(±)-Trimethyl Z-α-phosphonoglycinate
(±)-Z-α-Phosphonoglycine trimethyl ester
(+-)-N-cbz-A-phosphonoglycine trimethyl ester
N-(BENZYLOXYCARBONYL)-ALPHA-PHOSPHONO-GL
DL-alpha-Phosphonoglycinetrimethylester
CBZ-ALPHA-PHOSPHONO-DL-GLYCINE TRIMETHYL ESTER
(n)-benzyloxycarbonyl-à-phosphonoglycine trimethyl ester
(n)-cbz-à-phosphonoglycine trimethyl ester | [EINECS(EC#)]
629-458-5 | [Molecular Formula]
C13H18NO7P | [MDL Number]
MFCD00043304 | [Molecular Weight]
331.26 | [MOL File]
88568-95-0.mol |
| Chemical Properties | Back Directory | [Appearance]
White crystalline powder | [Melting point ]
77-80 °C(lit.)
| [Boiling point ]
480.5±45.0 °C(Predicted) | [density ]
1.284±0.06 g/cm3(Predicted) | [storage temp. ]
2-8°C | [solubility ]
Soluble in methanol. | [form ]
Crystalline Powder | [pka]
9.42±0.46(Predicted) | [color ]
White | [BRN ]
5764460 | [Major Application]
peptide synthesis | [InChI]
InChI=1S/C13H18NO7P/c1-18-12(15)11(22(17,19-2)20-3)14-13(16)21-9-10-7-5-4-6-8-10/h4-8,11H,9H2,1-3H3,(H,14,16) | [InChIKey]
GSYSFVSGPABNNL-UHFFFAOYSA-N | [SMILES]
C(OC)(=O)C(P(OC)(OC)=O)NC(OCC1=CC=CC=C1)=O | [CAS DataBase Reference]
88568-95-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29242990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral |
| Hazard Information | Back Directory | [Description]
(+/-)-Benzyloxycarbonyl-alpha-phosphonoglycine trimethyl ester is an important organic compound with the appearance of white to off-white powder to crystals, melting point of 78.0~ 82.0 °C, soluble in methanol, irritating to the eyes and skin, store in a cool, dry place in a closed Keep away from strong oxidising agents. Keep away from strong oxidising agents. It is mainly used in chemical industry and experimental research. | [Chemical Properties]
White crystalline powder | [Uses]
Starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes; the dehydroamino acids can be stereoselectively reduced to amino acids | [reaction suitability]
reaction type: solution phase peptide synthesis |
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