ChemicalBook--->CAS DataBase List--->89-40-7

89-40-7

89-40-7 Structure

89-40-7 Structure
IdentificationMore
[Name]

4-Nitrophthalimide
[CAS]

89-40-7
[Synonyms]

4-NITRO-1,2-BENZENE DICARBOXYLIC ACID, IMIDE
4-NITROPHTHALIMIDE
5-NITRO-1,3-DIHYDRO-2H-ISOINDOL-1,3-DIONE
5-NITRO-1H-ISOINDOLE-1,3(2H)-DIONE
5-NITROISOINDOLE-1,3-DIONE
5-NITROISOINDOLINE-1,3-DIONE
5-NITROPHTHALIMIDE
AKOS B028733
PHTHALIMIDE, 4-NITRO-
P-NITRO-PHTHALIMIDE
1H-Isoindole-1,3(2H)-dione, 5-nitro-
4-nitro-phthalimid
5-nitro-1h-isoindole-3(2h)-dione
4-Nitrophtalimide
4-Nirtophthalimide
5-Nitro-2H-isoindole-1,3-dione
[EINECS(EC#)]

201-905-5
[Molecular Formula]

C8H4N2O4
[MDL Number]

MFCD00005884
[Molecular Weight]

192.13
[MOL File]

89-40-7.mol
Chemical PropertiesBack Directory
[Appearance]

slight yellow powder
[Melting point ]

206 °C
[mp ]

206 °C
[Boiling point ]

328.09°C (rough estimate)
[density ]

1.5513 (rough estimate)
[refractive index ]

1.4900 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[pka]

7.79±0.20(Predicted)
[color ]

Yellow powder
[Stability:]

Stable. Combustible. Incompatible with moisture, water, strong oxidising agents, strong bases.
[Water Solubility ]

<0.01 g/100 mL at 18 ºC
[BRN ]

180224
[InChIKey]

ANYWGXDASKQYAD-UHFFFAOYSA-N
[CAS DataBase Reference]

89-40-7(CAS DataBase Reference)
[NIST Chemistry Reference]

4-Nitro-phthalimide(89-40-7)
[EPA Substance Registry System]

89-40-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

TI5625000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HS Code ]

29251900
[Toxicity]

mmo-sat 333 mg/plate EMMUEG 11(Suppl 12),1,88
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Nitric acid-->Phthalimide
[Preparation Products]

4-Nitrophthalic acid-->4-Nitrophthalic anhydride-->4-Nitroanthranilic acid-->4-Nitro-N-methylphthalimide-->4-NITROPHTHALOXIME-->4-Nitrophthalhydrazide-->1(3H)-ISOBENZOFURANONE, 5-FLUORO--->4-Aminophthalhydrazide-->4-AMINO-N-METHYLPHTHALIMIDE
Hazard InformationBack Directory
[General Description]

Yellow powder.
[Reactivity Profile]

A nitrated amine. Amines are combustible. The combustion of amines yields noxious NOx. REACTIVITY-Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Aromatic nitro compounds range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
[Air & Water Reactions]

This compound can be hydrolyzed. . Insoluble in water.
[Fire Hazard]

Flash point data for this chemical are not available, however 4-NITROPHTHALIMIDE is probably combustible.
[Chemical Properties]

slight yellow powder
[Uses]

4-Nitrophthalimide is a useful chemical in organic synthesis. Dyes and metabolites.
[Preparation]

4-Nitrophthalimide is synthesized from phthalimide by nitration. Cool the fuming nitric acid to below 5°C, slowly add concentrated sulfuric acid dropwise, and control the temperature to 10-13°C. Plus phthalimide. Leave at room temperature overnight. Then, it was poured into ice water with stirring, and the precipitate was precipitated below 20°C. Filter, wash with water, dry, and then recrystallize from ethanol to obtain 4-nitrophthalimide with a yield of 60%.
[Safety Profile]

Mutation data reported. Whenheated to decomposition it emits toxic vapors of NOx.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Nitrophthalimide(89-40-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

4-Nitrophthalimide(89-40-7)MS
4-Nitrophthalimide(89-40-7)13CNMR
4-Nitrophthalimide(89-40-7)IR1
4-Nitrophthalimide(89-40-7)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Nitrophthalimide, 98%(89-40-7)
[Alfa Aesar]

4-Nitrophthalimide, 98%(89-40-7)
[Sigma Aldrich]

89-40-7(sigmaaldrich)
[TCI AMERICA]

4-Nitrophthalimide,>98.0%(T)(89-40-7)
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