| Identification | More | [Name]
DIETHYL(3-PYRIDYL)BORANE | [CAS]
89878-14-8 | [Synonyms]
3-(DIETHYLBORYL)PYRIDINE
DIETHYL(3-PYRIDYL)BORANE
3-Diethylboranyl Pyridine | [EINECS(EC#)]
278-928-2 | [Molecular Formula]
C9H14BN | [MDL Number]
MFCD00012348 | [Molecular Weight]
147.03 | [MOL File]
89878-14-8.mol |
| Chemical Properties | Back Directory | [Melting point ]
172-175 °C(lit.)
| [Boiling point ]
205.9±22.0 °C(Predicted) | [density ]
0.86±0.1 g/cm3(Predicted) | [storage temp. ]
Refrigerator | [form ]
Solid | [pka]
4.40±0.12(Predicted) | [color ]
White to Almost white | [Water Solubility ]
Slightly soluble in water. | [InChI]
InChI=1S/C9H14BN/c1-3-10(4-2)9-6-5-7-11-8-9/h5-8H,3-4H2,1-2H3 | [InChIKey]
OJKBCQOJVMAHDX-UHFFFAOYSA-N | [SMILES]
C1=NC=CC=C1B(CC)CC | [CAS DataBase Reference]
89878-14-8(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
White to yellow solid | [Uses]
Reactant for: preparation of inhibitors of ataxia telangiectasia mutated and Rad3 related (ATR) protein kinase as potential anticancer agents, N-Methylation reactions of the pyridyl group, Palladium catalyzed amination reactions, intramolecular Heck reactions, Coupling reactions and Synthesis of trisubstituted pyrimidines from polyhalopyrimidines via Suzuki coupling. | [Uses]
suzuki reaction | [reaction suitability]
reagent type: reductant | [Synthesis]
Reaction temperature 0 ~ 5 ℃, reaction time 6h, diethylmethoxyborane drop time 30 min, material ratio n (3-bromopyridine): n (diethylmethoxyborane) for 0.9:1.0, material ratio n (isopropylmagnesium chloride): n (diethylmethoxyborane) for 1.0:1.0. In th |
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