| Identification | More | [Name]
1-Iodonaphthalene | [CAS]
90-14-2 | [Synonyms]
1-IODONAPHTHALENE
1-NAPHTHYL IODIDE
1-iodo-naphthalen
alpha-Iodonaphthalene
Iodonaphthalene
Naphthalene, 1-iodo-
naphthalene,1-iodo-
1-Iodonaphthalene,98%
1-Iodonaphthalene, 97.50%
a-Jodnnphthalin
1-Iodonaphthalene, 97.5%
(1-Naphtyl) iodide
1-Naphtyl iodide | [EINECS(EC#)]
201-968-9 | [Molecular Formula]
C10H7I | [MDL Number]
MFCD00003876 | [Molecular Weight]
254.07 | [MOL File]
90-14-2.mol |
| Chemical Properties | Back Directory | [Appearance]
clear yellow to brown liquid | [Melting point ]
4°C | [Boiling point ]
163-165 °C/15 mmHg (lit.) | [density ]
1.74 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.701(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
0.007g/l | [form ]
liquid (clear)
| [color ]
clear very deep brown-yellow
| [Specific Gravity]
1.74 | [Water Solubility ]
Slightly soluble in water. | [Sensitive ]
Light Sensitive | [BRN ]
1906415 | [Dielectric constant]
4.5599999999999996 | [InChI]
1S/C10H7I/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H | [InChIKey]
NHPPIJMARIVBGU-UHFFFAOYSA-N | [SMILES]
Ic1cccc2ccccc12 | [CAS DataBase Reference]
90-14-2(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Iodonaphthalene(90-14-2) | [EPA Substance Registry System]
90-14-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
8 | [TSCA ]
Yes | [HS Code ]
29036990 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Hydrochloric acid-->Diethyl ether-->Acetic acid-->Hexane-->Potassium iodide-->Sodium thiosulfate-->Naphthalene-->Potassium bromate-->1-Iodo-8-methylnaphthalene-->1,8-Diiodonaphthalene-->1,8-Dimethylnaphthalene | [Preparation Products]
1-Naphthalenemethanol-->7H-Benz[de]anthracen-7-one, 11-nitro--->1-(4-Bromophenyl)-naphthlene-->4,4'-Dinitrodiphenic acid-->2-(1-Naphthylene)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane-->1,1'-Binaphthyl |
| Hazard Information | Back Directory | [Chemical Properties]
clear yellow to brown liquid | [Uses]
1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine. | [General Description]
Ultrafast relaxation of 1-iodonaphthalene has been studied by time-resolved femtosecond pump-probe mass spectrometry. 1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine. | [References]
[1] Tetrahedron Letters, 2011, vol. 52, # 16, p. 1993 - 1995
[2] Synlett, 2014, vol. 25, # 7, p. 995 - 1000
[3] Journal of Fluorine Chemistry, 2016, vol. 189, p. 59 - 67
[4] Chemistry - A European Journal, 2011, vol. 17, # 20, p. 5652 - 5660
[5] Catalysis Communications, 2013, vol. 32, p. 15 - 17 |
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