ChemicalBook--->CAS DataBase List--->91000-69-0

91000-69-0

91000-69-0 Structure

91000-69-0 Structure
IdentificationMore
[Name]

FMOC-L-Arginine
[CAS]

91000-69-0
[Synonyms]

9-FLUORENYLMETHOXYCARBONYL-L-ARGININE
FMOC-ARGININE
FMOC-ARG-OH
FMOC-L-ARGININE
FMOC-L-ARG-OH
N-(9-FLUORENYLMETHOXYCARBONYL)-L-ARGININE
N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-L-ARGININE
N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-L-ARGININE
N-ALPHA-[(FLUOREN-9-YLMETHOXY)CARBONYL]-L-ARGININE
N-ALPHA-FMOC-L-ARGININE
Nα-(9-Fluorenylmethoxycarbonyl)-L-arginine
Nα-Fmoc-L-arginine
9-(Fluorenylmethoxy carbonyl-Homo-Arginine
FMOC-L-ARGININE-OH
FMOC-ARG
Fmoc-Arg-OH (Fmoc-L-Arginine)
Fmoc-Arq-OH
N(ALPHA)-[9H-FLUOREN-9-YLMETHOXY)CARBONYL]-L-ARGININE
Fmoc-L-Arg-OH*H2O
N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-arginine hydrate
[Molecular Formula]

C21H24N4O4
[MDL Number]

MFCD00051770
[Molecular Weight]

396.44
[MOL File]

91000-69-0.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

145-150 °C(lit.)
[alpha ]

9 º (c=1 DMF 24 ºC)
[Boiling point ]

520.14°C (rough estimate)
[density ]

1.2722 (rough estimate)
[refractive index ]

1.6620 (estimate)
[storage temp. ]

2-8°C
[solubility ]

Aqueous Acid (Slightly), Chloroform (Slightly), Dimethylformamide (Slightly)
[form ]

Powder
[pka]

3.81±0.21(Predicted)
[color ]

Off-white
[Optical Rotation]

[α]/D +9.0±2.0°, c = 1% in DMF
[Sensitive ]

Moisture Sensitive
[BRN ]

4828015
[Major Application]

peptide synthesis
[InChIKey]

DVBUCBXGDWWXNY-SFHVURJKSA-N
[SMILES]

C(O)(=O)[C@H](CCCNC(N)=N)NC(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O
[CAS DataBase Reference]

91000-69-0(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H319-H335-H315
[Precautionary statements ]

P264-P270-P301+P312-P330-P501-P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

21
[HS Code ]

29252900
[Storage Class]

11 - Combustible Solids
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

FMOC-Arg-OH(91000-69-0).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

Nα-Fmoc-L-arginine is an N-Fmoc-protected form of L-Arginine (A769505). L-Arginine is an conditionally essential amino acid for humans and adult mammals as it’s requirements exceed production during certain developmental stages in life (such as pregnancy). L-Arginine also prevents blood toxicity from intravenous amino acid administration in humans.
[storage]

Store at -20°C
[References]

[1] Yi Yang*, Lena Hansen and Per Ryberg. “Side-Chain Unprotected Fmoc-Arg/His/Tyr-OH Couplings and Their Application in Solid-Phase Peptide Synthesis through a Minimal-Protection/Green Chemistry Strategy.” Organic Process Research & Development 26 5 (2022): 1520–1530.
Spectrum DetailBack Directory
[Spectrum Detail]

FMOC-L-Arginine(91000-69-0)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Nalpha-FMOC-L-Arginine, 99+%(91000-69-0)
[Sigma Aldrich]

91000-69-0(sigmaaldrich)
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