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920-39-8

920-39-8 Structure

920-39-8 Structure
IdentificationBack Directory
[Name]

ISOPROPYLMAGNESIUM BROMIDE
[CAS]

920-39-8
[Synonyms]

Isopropylbromomagnesium
BroMoisopropylMagnesiuM
2-Propylmagnesium bromide
ISOPROPYLMAGNESIUM BROMIDE
Brom(1-methylethyl)magnesium
bromo(1-methylethyl)magnesium
IsopropylMagnesiuM broMide solution
iso-Propylmagnesiumbromide(15%inTHF)
Isopropylmagnesium bromide, 1.0 M in THF
IsopropylMagnesiuM broMide, 3M in 2-MeTHF
i-Propylmagnesium bromide 1M solution in THF
i-Propylmagnesium bromide 2M solution in DEE
Isopropylmagnesium bromide [1M solution in THF]
Isopropylmagnesium bromide solution 1.0 M in THF
Isopropylmagnesium Bromide 2.0 M In Diethyl Ether
ISOPROPYLMAGNESIUM BROMIDE: 15% IN TETRAHYDROFURAN
Isopropylmagnesium Bromide 1.0 M In Tetrahydrofuran
i-Propylmagnesium bromide 2.75M solution in 2-MeTHF
ISOPROPYLMAGNESIUM BROMIDE, 0.8 M in TETRAHYDROFURAN
Isopropyl magnesium bromide 3M 2- methyltetrahydrofuran
IsopropylMagnesiuM broMide, 1.0 M solution in THF, J&KSeal
IsopropylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal
IsopropylMagnesiuM broMide, 3M solution in 2-MeTHF, AcroSeal
Isopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L)
IsopropylMagnesiuM broMide, 2.0 M solution in 2-Me THF, J&KSeal
IsopropylMagnesiuM broMide, 3.0 M solution in 2-Me THF, J&KSeal
Isopropylmagnesium bromide,3M solution in 2-Methyltetrahydrofuran
Isopropylmagnesium bromide solution 2.9 M in 2-methyltetrahydrofuran
IsopropylMagnesiuM broMide, 3.0 M in 2-Methyltetrahydrofuran, SpcSeal
i-Propylmagnesium bromide, 2.9M (35wt% ±1wt%) in 2-methyltetrahydrofuran
Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, AcroSeal
Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, AcroSeal§3
[EINECS(EC#)]

213-056-8
[Molecular Formula]

C3H7BrMg
[MDL Number]

MFCD00672110
[MOL File]

920-39-8.mol
[Molecular Weight]

147.3
Chemical PropertiesBack Directory
[Appearance]

Clear dark brown or dark gray solution
[Melting point ]

114-116℃
[Boiling point ]

148-154℃
[density ]

0.982 g/mL at 25 °C
[Fp ]

-17°C
[storage temp. ]

2-8°C
[solubility ]

Miscible with tetrahydorfuran and diethyl ether. Immiscible with hydrocarbons.
[form ]

Solution
[color ]

Clear dark brown or dark gray
[Sensitive ]

Air & Moisture Sensitive
[InChI]

InChI=1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1
[InChIKey]

UCJIVFREPMUZDC-UHFFFAOYSA-M
[SMILES]

C(C)(C)[Mg]Br
[EPA Substance Registry System]

Magnesium, bromo(1-methylethyl)- (920-39-8)
Hazard InformationBack Directory
[Chemical Properties]

Clear dark brown or dark gray solution
[Uses]

Isopropylmagnesium bromide is a Grignard reagent used in organic synthesis, especially for the introduction of iso-propyl group to carbonyl compounds. It is also used as a strong base in aprotic solvent.
[General Description]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 2.9 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.
[reaction suitability]

reaction type: Grignard Reaction
[Synthesis]

Nitrogen was replaced 3 times in a 500L reactor, 25.25kg of magnesium balls (0.8cm) were added, 100L of 2-methyltetrahydro was added and the initiator (2-bromopropane Grignard reagent) was 2kg. furan and initiator (2-bromopropane Grignard reagent) 2kg, h
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)
GHS02,GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H225-H261-H302-H314
[Precautionary statements ]

P210-P231+P232-P280-P301+P312-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

F,C
[Risk Statements ]

11-19-34-14/15-40-37-17-14
[Safety Statements ]

16-26-27-36/37/39-45-43-39-37-36
[RIDADR ]

3399
[WGK Germany ]

2
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

4.3
[PackingGroup ]

I
[HS Code ]

29319090
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
Water-react 2
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