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92149-07-0

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92149-07-0 Structure

92149-07-0 Structure
IdentificationBack Directory
[Name]

4,7-DIMETHOXY-1,10-PHENANTHROLINE, 97%
[CAS]

92149-07-0
[Synonyms]

4,7-Dimethoxy-1,1-phenanthroline
4,7-diMethoxyl-1,10-phenanthroline
4,7-DiMethoxy-1,10-phenanthroline 97%
4,7-DIMETHOXY-1,10-PHENANTHROLINE, 97%
4,7-Dimethoxy-1,10-phenanthroline ,98%
[4,7-DIMETHOXY-1,10-PHENANTHROLINE, 97%]
[Molecular Formula]

C14H12N2O2
[MDL Number]

MFCD00233883
[MOL File]

92149-07-0.mol
[Molecular Weight]

240.257
Chemical PropertiesBack Directory
[Melting point ]

197-212 °C
[Boiling point ]

373.1±37.0 °C(Predicted)
[density ]

1.25
[storage temp. ]

Sealed in dry,2-8°C
[form ]

Crystalline Powder
[pka]

6.45±0.10(Predicted)
[color ]

White to brown
[Sensitive ]

air sensitive
[InChI]

InChI=1S/C14H12N2O2/c1-17-11-5-7-15-13-9(11)3-4-10-12(18-2)6-8-16-14(10)13/h3-8H,1-2H3
[InChIKey]

ZPGVCQYKXIQWTP-UHFFFAOYSA-N
[SMILES]

N1C2C(=CC=C3C=2N=CC=C3OC)C(OC)=CC=1
Hazard InformationBack Directory
[Chemical Properties]

White to brown Solid
[Uses]

Ligand for Cu-catalzyed N-arylation of imidazoles
[reaction suitability]

reagent type: ligand
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)Environment (GHS09)
GHS05,GHS07,GHS09
[Signal word ]

Danger
[Hazard statements ]

H302-H318-H400
[Precautionary statements ]

P264-P270-P273-P280-P301+P312-P305+P351+P338
[Hazard Codes ]

Xn,N
[Risk Statements ]

22-41-50
[Safety Statements ]

26-39-61
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

3
[TSCA ]

No
[HazardClass ]

9
[PackingGroup ]

Ⅲ
[HS Code ]

29339900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Acute 1
Eye Dam. 1
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Tetrahydrofuran-->Sodium-->Phosphorus oxitrichloride-->Acetone-->Sodium hydride-->Sodium Methoxide-->N,N-Dimethylaniline-->o-Phenylenediamine-->Diphenyl ether-->Trimethoxymethane-->2,2-Dimethyl-1,3-dioxane-4,6-dione
Questions And AnswerBack Directory
[Reaction]

  1. Palladium-catalyzed synthesis of benzofurans and coumarins from phenols and olefins.
  2. Copper-catalyzed intermolecular amidation and imidation of unactivted alkanes.
  3. Synthesis of amides via copper-catalyzed amidation of aryl halides using isocyanides.
  4. Copper-catalyzed benzylic C(sp3)-H alkoxylation of heterocyclic compounds.
  5. Iridium-catalyzed silylation of aryl C-H bonds.
  6. Palladium-catalyzed intramolecular cyclization of nitroalkenes: synthesis of thienopyrroles.
  7. A Copper-catalyzed N-alkynylation route to 2-substitued N-alkynyl pyrroles and their cyclization into pyrrolo[2,1-c]oxazin-1-ones
Reactions of 92149-07-0_1
Reactions of 92149-07-0_2
Reactions of 92149-07-0_3
Spectrum DetailBack Directory
[Spectrum Detail]

4,7-DIMETHOXY-1,10-PHENANTHROLINE, 97%(92149-07-0)1HNMR
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