ChemicalBook--->CAS DataBase List--->95-96-5

95-96-5

95-96-5 Structure

95-96-5 Structure
IdentificationBack Directory
[Name]

DL-Lactide
[CAS]

95-96-5
[Synonyms]

LACTIDE
purasorbl
dilactide
5-Dione,3
DL-LACTIDE
DL-DILACTIDE
LACTIDE(D,L-)
D,L-Lactide S
PURASORB(R) DL
DL-Lactide,97%
DL-LACTIDE 98+%
LACTIC ANHYDRIDE
TIMTEC-BB SBB007949
TIMTEC-BB SBB008348
DL-Lactide
lacticacid,bimol.cyclicester
3,6-dimethyl-p-dioxane-5-dione
5-dione,3,6-dimethyl-4-dioxane-2
3,6-dimethyl-p-dioxane-2,5-dione
p-Dioxane-2,5-dione, 3,6-dimethyl-
2,5-dimethyl-3,6-dioxo-1,4-dioxane
2,5-dioxo-3,6-dimethyl-1,4-dioxane
3,6-Dimethyl-2,5-dioxo-1,4-dioxane
2,5-Dimethyl-1,4-dioxane-3,6-dione
3,6-DIMETHYL-1,4-DIOXANE-2,5-DIONE
3,6-diketo-2,5-dimethyl-1,4-dioxane
1,4-Dioxane-2,5-dione, 3,6-dimethyl-
DL-3,6-Dimethyl-1,4-dioxane-2,5-dione
(n)-3,6-dimethyl-1,4-dioxane-2,5-dione
3,6-Dimethyl-1,4-dioxane-2,5-dione,99%
2-hydroxy-propanoicacibimol.cyclicester
CIS-(+/-)-3,6-DIMETHYL-1,4-DIOXANE-2,5-DIONE
3,6-DiMethyl-1,4-dioxane-2,5-dione, 99% 25GR
DL-Dilactide 3,6-Dimethyl-1,4-dioxane-2,5-dione
Propanoic acid, 2-hydroxy-, bimol. cyclic ester
rac-(2R*)-2α*,5α*-Dimethyl-1,4-dioxane-3,6-dione
rac-(3R*)-3β*,6β*-Dimethyl-1,4-dioxane-2,5-dione
[EINECS(EC#)]

202-468-3
[Molecular Formula]

C6H8O4
[MDL Number]

MFCD00011685
[MOL File]

95-96-5.mol
[Molecular Weight]

144.13
Chemical PropertiesBack Directory
[Appearance]

White crystalline powder
[Melting point ]

116-119 °C
[Boiling point ]

142 °C8 mm Hg(lit.)
[density ]

1.186±0.06 g/cm3(Predicted)
[vapor pressure ]

0.311Pa at 25℃
[Fp ]

180°C
[storage temp. ]

Refrigerator (+4°C)
[solubility ]

Soluble in chloroform and methanol. Slightly soluble in benzene.
[form ]

Crystalline Powder
[color ]

White
[Water Solubility ]

16.3g/L at 20℃
[Sensitive ]

Moisture Sensitive
[BRN ]

82121
[Cosmetics Ingredients Functions]

ABRASIVE
SKIN CONDITIONING
[InChI]

1S/C6H8O4/c1-3-5(7)10-4(2)6(8)9-3/h3-4H,1-2H3
[InChIKey]

JJTUDXZGHPGLLC-UHFFFAOYSA-N
[SMILES]

CC1OC(=O)C(C)OC1=O
[LogP]

0.4 at 25℃
[NIST Chemistry Reference]

1,4-Dioxane-2,5-dione, 3,6-dimethyl-(95-96-5)
[EPA Substance Registry System]

1,4-Dioxane-2,5- dione, 3,6-dimethyl-(95-96-5)
Hazard InformationBack Directory
[Chemical Properties]

White crystalline powder
[Uses]

Enzymatic alcoholysis of this racemic lactide catalyzed by commercial Novozym® 435 produces both alkyl (R)-lactates and alkyl (S,S)-lactyllactates in good yield and high enantiopurity.1
[Definition]

ChEBI: Lactide is a member of dioxanes.
[General Description]

3,6-Dimethyl-1,4-dioxane-2,5-dione (or rac-lactide), is the 50:50 racemic mixture of D- and L-Lactide. Rac-lactide is a lactone derived from lactic acid that has attracted great interest in academia and commercial applications, as it is derived from abundant renewable resources. Rac-lactide can be ready polymerized via ring-opening polymerization, using a variety of metal or organocatalysts, yielding poly(D,L-lactide). While the resulting polymer is generally amorphous, the use of stereospecific catalysts can lead to heterotactic PLA, which exhibits some degree of crystallinity.
[Flammability and Explosibility]

Nonflammable
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H319
[Precautionary statements ]

P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38-36
[Safety Statements ]

26-37/39
[WGK Germany ]

2
[RTECS ]

JH1100000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29322090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

polylactic acid and its copolymer-->Potassium lactate
Questions And AnswerBack Directory
[Uses]

DL-Lactide is used to produce 2-hydroxy-propionic acid 1-(1-phenyl-ethoxycarbonyl)-ethyl ester. It acts as an important raw material and an intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyes. It is involved in enzymatic alcoholysis to produce both alkyl (R)-lactates and alkyl (S,S)-lactyllactates.DL-Lactide is often used as a protective layer in wound coatings, or as anchors, screws or mesh in surgery, since it degrades in about six months to the innocuous lactic acid.
Spectrum DetailBack Directory
[Spectrum Detail]

DL-Lactide(95-96-5)MS
DL-Lactide(95-96-5)1HNMR
DL-Lactide(95-96-5)13CNMR
DL-Lactide(95-96-5)IR1
DL-Lactide(95-96-5)IR2
DL-Lactide(95-96-5)Raman
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