Oxamidsure

Oxamic acid Struktur
471-47-6
CAS-Nr.
471-47-6
Bezeichnung:
Oxamidsure
Englisch Name:
Oxamic acid
Synonyma:
Oxamate;2-aMino-2-oxoacetic acid;Oxalamic acid;Oxamic acid Oxalic acid monoamide;OXAMIC ACID;OXAMIDIC ACID;OxamicAcid>Oxamicacid,98%;Glycine, 2-oxo-;Oxamic acid 98%
CBNumber:
CB5667743
Summenformel:
C2H3NO3
Molgewicht:
89.05
MOL-Datei:
471-47-6.mol

Oxamidsure Eigenschaften

Schmelzpunkt:
207-210 °C (dec.) (lit.)
Siedepunkt:
165.08°C (rough estimate)
Dichte
1.6193 (rough estimate)
Brechungsindex
1.4264 (estimate)
storage temp. 
2-8°C(protect from light)
Löslichkeit
DMSO (Slightly), Methanol (Slightly), Water (Slightly)
Aggregatzustand
Crystalline Powder
pka
1.60±0.20(Predicted)
Farbe
White
Wasserlöslichkeit
Soluble in water 108 mg/mL.
Merck 
14,6917
BRN 
1743294
InChI
InChI=1S/C2H3NO3/c3-1(4)2(5)6/h(H2,3,4)(H,5,6)
InChIKey
SOWBFZRMHSNYGE-UHFFFAOYSA-N
SMILES
C(O)(=O)C(N)=O
CAS Datenbank
471-47-6(CAS DataBase Reference)
EPA chemische Informationen
Oxamic acid (471-47-6)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38
S-Sätze: 26-36
WGK Germany  3
TSCA  Yes
HS Code  29241990
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P304+P340 BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P405 Unter Verschluss aufbewahren.

Oxamidsure Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.

Beschreibung

Oxamic acids also known to as oxalic acid monoamides have emerged as potent precursors for the generation of the carbamoyl radical. Oxamic acids can easily undergo decarboxylation through a single electron oxidation resulting in the generation of the reactive carbamoyl radical, which can then engage in diverse radical reactions or undergo a second single electron oxidation as originally unveiled by Minisci. Oxamic acids are thus versatile intermediates for the synthesis of nitrogen-containing organic molecules[1]. The oxidative decarboxylation of oxamic acids can be mediated through thermal, photochemical, electrochemical or photoelectrochemical means, generating carbamoyl radicals, which may further add to unsaturated systems to provide a broad range of important amides. Oxidative decarboxylation of oxamic acids also offers a straightforward entry for the preparation of urethanes, ureas, and thioureas.

Chemische Eigenschaften

Oxamic acid is a white, water-soluble solid. It is the monoamide ofoxalic acid. It can react with metal carbonates to form oxamate. Oxamic acid inhibits lactate dehydrogenase A.

Verwenden

Oxamic acid is an ozone oxidation product and is used in the synthesis of hydroxybenzimidazoles preparation as potential anti tumor agents targeting human lactate dehydrogenase A.This compound is suitable for lactate dehydrogenase (LDH) related research.

Definition

ChEBI: Oxamic acid is a dicarboxylic acid monoamide resulting from the formal condensation of one of the carboxy groups of oxalic acid with ammonia. It has a role as an Escherichia coli metabolite. It is a conjugate acid of an oxamate.

Application

Oxamic acid (OA) has applications in polymer chemistry. It increases the water solubility of certain polymers, including polyester,epoxide, and acrylic upon binding with them. Oxamic acid can be used as a reactant to prepare 6-phenanthridinecarboxamide by direct C-H carbamoylation reaction using ammonium persulfate in DMSO. It can also be used as an organic ligand to prepare functionalized metal oxide nanoparticles for various biological applications. OA along with p-aminobenzoic acid is used to functionalize Au nanoparticles for the development of a sensor to detect Fe3+ ions by the calorimetric method.

Oxamidsure Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Oxamidsure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 121)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Sense Chemicals (Shanghai) Co., Ltd.
+86-21-52751036; +8613818977689
david.dai@sensechemicals.com China 224 58
Hongxiong
+undefined18915499068
Suzhouhongxiong@163.com China 120 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32480 60
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22968 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49390 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196
sale04@alfachem.cn China 12468 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
sales@tnjchem.com China 34572 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250
1026@dideu.com China 29220 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739
info@dycnchem.com CHINA 52867 58
Shaanxi Didu New Materials Co. Ltd
+86-89586680 +86-13289823923
1026@dideu.com China 9116 58

471-47-6(Oxamidsure)Verwandte Suche:


  • AMINOOXOACETIC ACID
  • Oxamicacid,98%
  • Aminooxoacetic acid, Oxalic acid monoamide
  • OxaMic acid, 98% 10GR
  • OxaMic acid, 98% 25GR
  • Acetic acid, aminooxo-
  • aminooxo-aceticaci
  • Formic acid, (aminocarbonyl)-
  • Formic acid, carbamoyl-
  • Glycine, 2-oxo-
  • Glyoxylic acid, amino-
  • Oxamate, (aminocarbonyl)-
  • OXALIC ACID MONOAMIDE
  • OXAMIC ACID
  • OXAMIDIC ACID
  • Oxamic acid 98%
  • OxamicAcid>
  • Acetic acid, 2-amino-2-oxo-
  • OXAMIC ACID USP/EP/BP
  • Oxamic acid Oxalic acid monoamide
  • 2-aMino-2-oxoacetic acid
  • Oxalamic acid
  • Oxamate
  • (S)-2-(Cyclohexylmethyl)succinicacid-5-methyl ester
  • 2-Propenoicacid,2-cyano-3-phenyl-,methylester,(6E)-
  • Oxamic acid (6CI, 7CI, 8CI)
  • Oxamic Acid, ≥ 97.0%
  • 471-47-6
  • H2NCOCOOH
  • NH2COCO2H
  • H2NCOCO2H
  • C2H3NO3
  • C2H2NO3
  • AMINE
  • Building Blocks
  • C1 to C5
  • Carboxylic Acids
  • Carbonyl Compounds
  • Organic Building Blocks
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