Carboxin

Carboxin Struktur
5234-68-4
CAS-Nr.
5234-68-4
Bezeichnung:
Carboxin
Englisch Name:
Carboxin
Synonyma:
v4x;d735;Dmoc;f735;DCMO;d-735;f 735;d 735;Kisvax;OXATIN
CBNumber:
CB9267538
Summenformel:
C12H13NO2S
Molgewicht:
235.3
MOL-Datei:
5234-68-4.mol

Carboxin Eigenschaften

Schmelzpunkt:
91.1-91.7°C
Siedepunkt:
420.6±45.0 °C(Predicted)
Dichte
1.45
Dampfdruck
2.5 x 10-5 Pa (25 °C)
Brechungsindex
1.6000 (estimate)
Flammpunkt:
100 °C
storage temp. 
Sealed in dry,2-8°C
Löslichkeit
Chloroform (Slightly), Methanol (Slightly)
pka
14.31±0.70(Predicted)
Aggregatzustand
Crystals
Farbe
White
Wasserlöslichkeit
10.095 g/100 mL
Merck 
13,1837
BRN 
983249
LogP
2.140
NIST chemische Informationen
Carboxin(5234-68-4)
EPA chemische Informationen
Carboxin (5234-68-4)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi,Xn
R-Sätze: 21/22-36/37/38-20/21/22
S-Sätze: 36-26
RIDADR  UN2588 (Pesticide, solid, poisonous, n.o.s.); UN2902 (Pesticide, liquid, poisonous, n.o.s.)
WGK Germany  3
RTECS-Nr. RP4550000
HS Code  29349990
Giftige Stoffe Daten 5234-68-4(Hazardous Substances Data)
Toxizität LD50 in rats, mice (mg/kg): 430, 3200 orally (Dyadicheva)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitsschädlich bei Verschlucken. Akute Toxizität oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H317 Kann allergische Hautreaktionen verursachen. Sensibilisierung der Haut Kategorie 1A Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H373 Kann die Organe schädigen bei längerer oder wiederholter Exposition. Spezifische Zielorgan-Toxizität (wiederholte Exposition) Kategorie 2 Warnung P260, P314, P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gewässergefährdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P260 Dampf/Aerosol/Nebel nicht einatmen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P301+P312 BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P314 Bei Unwohlsein ärztlichen Rat einholen / ärztliche Hilfe hinzuziehen.

Carboxin Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R21/22:Gesundheitsschädlich bei Berührung mit der Haut und beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.

S-Sätze Betriebsanweisung:

S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Chemische Eigenschaften

Carboxin is a white crystalline solid

Verwenden

Carboxine is an fungicide used for the control of fruit rot of custard apple.

Definition

ChEBI: An anilide obtained by formal condensation of the amino group of aniline with the carboxy group of 2-methyl-5,6-dihydro-1,4-oxathiine-3-carboxylic acid. A fungicide for control of bunts and smuts normally that is normally used as a seed treatment.

Allgemeine Beschreibung

Off-white crystals. Systemic fungicide and seed protectant.

Landwirtschaftliche Anwendung

Fungicide: Carboxin is a General Use Pesticide (GUP) and is used as a seed protectant. It is often used in combination with other fungicides such as thiram or captan. Carboxin is a systemic anilide fungicide. It is used as a seed treatment for control of smut, rot, and blight on barley, oats, rice, cotton, vegetables, corn and wheat. It is also used to control fairy rings on turf grass. Carboxin may be used to prevent the formation of these diseases or may be used to cure existing plant diseases. Also used as a wood preservative.

Handelsname

CADAN®; CARBOXIN OXATHION PESTICIDE®; CASWELL No. 165 A®; D-735®; F-735®; FLO PRO V SEED PROTECTANT®[C]; KEMIKAR®; OXALIN®; PADAN®; SANVEX®; THIOBEL®; VEGETOX®; VITAFLO®; VITAVAX® 200FF; V 4X®

Sicherheitsprofil

Poison by ingestion. Moderately toxic by skin contact and possibly other routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and SOx.

mögliche Exposition

A potential danger to those involved in the production, Formulation and application of this systemic fungicide, seed protectant and wood preservative

Environmental Fate

Biological. The sulfoxidation of carboxin to carboxin sulfoxide by the fungus Ustilago maydis was reported by Bollag and Liu (1990).
Soil. Carboxin oxidized in soil forming carboxin sulfoxide. The half-life in soil was reported to be 24 hours (Worthing and Hance, 1991).
Plant. In plants (barley, cotton and wheat) and water, carboxin oxidizes to the corresponding sulfoxide (Worthing and Hance, 1991).

Stoffwechselwegen

Carboxin is a systemic fungicide which is very stable to hydrolysis but is readily oxidised at sulfur to a sulfoxide and a sulfone. The latter, oxycarboxin, is itself a commercial fungicide. Metabolism is mainly by oxidation at sulfur in soil, plants and animals but hydroxylation of the phenyl ring is also important in animals. Hydrolysis has been convincingly demonstrated only in plants (peanut).

Versand/Shipping

UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Inkompatibilitäten

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Avoid heat and humidity. Thermal decomposition products may include cyanide gas and cyanide salts.

Waste disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Carboxin Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Carboxin Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 255)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Nanjing Liskon Biological Technology Co., Ltd
025-52110956 +8613814852963
sales@liskonchem.com China 7 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714
fandachem@gmail.com China 9346 55
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873
sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63711 58
SIMAGCHEM CORP
+86-13806087780
sale@simagchem.com China 17367 58
Longyan Tianhua Biological Technology Co., Ltd
0086 18039857276 18039857276
CHINA 2783 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
sales@tnjchem.com China 34572 58

5234-68-4(Carboxin)Verwandte Suche:


  • 1,4-Oxathiin, 2,3-dihydro-5-carboxanilido-6-methyl-
  • 1,4-Oxathiin-3-carboxamide, 5,6-dihydro-2-methyl-N-phenyl-
  • 1,4-oxathiin-3-carboxamide,5,6-dihydro-2-methyl-n-phenyl
  • 1,4-Oxathiin-3-carboxanilide, 5,6-dihydro-2-methyl-
  • 1,4-oxathiin-3-carboxanilide,5,6-dihydro-2-methyl-
  • 2,3-Dihydro-5-carboxanilido-6-methyl-1,4-oxathiin
  • d735
  • d-735
  • Dmoc
  • dualmurganicrpb
  • enhance
  • enhanceplus
  • f 735
  • f735
  • Flo pro v seed protectant
  • floprovseedprotectant
  • germateplus
  • Kisvax
  • mist-o-maticmurganic
  • murganic
  • pro-gro
  • rtvvitavax
  • v4x
  • Vitaflo 250
  • vitaflo250
  • vitaflow
  • Vitavax 100
  • Vitavax 735d
  • Vitavax 75w
  • vitavax100
  • vitavax-200
  • vitavax-300
  • vitavax30-c.
  • VITAVAX(R)
  • Vitavax(Uniroyal)
  • CARBOXIN PESTANAL (5,6-DIHYDRO- 2-METHYL
  • CARBOXIN, 1GM, NEAT
  • CARBOXIN (5,6-DIHYDRO-2-METHYL-N-PHENYL-1,4-OXATHIIN-3-CARBOXAMIDE)
  • 5,6-Dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-caboxamide
  • carbathiine
  • carboxin (bsi,iso,ansi)
  • 5,6-dihydro-2-methyl-1,4-oxathiin- 3-carbonic acid, anilide
  • 2,3-DIHYDRO-5-CARBOXANILINO-6-METHYL-1,4-OXATHIIN
  • VITAVAXEC200
  • 1,4-OXANTHIIN-3-CARBOXAMIDE,5,6-DIHYDRO-2-METHYL-N-PHENYL-
  • Fenoxan
  • Carboxin Standard
  • 6-methyl-N-phenyl-2,3-dihydro-1,4-oxathiine-5-carboxamide
  • Carboxin 1g [5234-68-4]
  • Carboxine Standard
  • 2,3-dihydro-5-carboxanilido-6-methyl-4-oxathiin
  • 2,3-Dihydro-6-methyl-1,4-oxathiin-5-carboxanilide
  • 2,3-dihydro-6-methyl-1,4-oxathiine-5-carboxylicacidanilide
  • 2,3-dihydro-6-methyl-5-phenylcarbamoyl-1,4-oxathiin
  • 2-Methyl-N-phenyl-5,6-dihydro-1,4-oxathiine-3-carboxamide
  • 5,6-Dihydro-2-methyl-3-carboxanilido-1,4-oxathiin
  • 5,6-dihydro-2-methyl-4-oxathiin-3-carboxanilide
  • 5,6-dihydro-2-methyl-n-phenyl-4-oxathiin-3-carboxamide
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