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THALLIUM (III) CHLORIDE

CAS No.
13453-33-3
Chemical Name:
THALLIUM (III) CHLORIDE
Synonyms
THALLIC CHLORIDE;Thallium(Ⅲ)chloride;THALLIUM CHLORIDE (IC);THALLIUM (III) CHLORIDE;THALLIUMCHLORIDETETRAHYDRATE;THALLIUM CHLORIDE (IC), 99.9%;hallium(3+),trichloride,hydrate;thallium(3+),trichloride,hydrate;ThalliumchloridehydrateHOwhitextl;THALLIUM(III)TRICHLORIDETETRAHYDRATE
CBNumber:
CB0757481
Molecular Formula:
Cl3H2OTl
Molecular Weight:
328.75
MDL Number:
MFCD00049600
MOL File:
13453-33-3.mol
Last updated:2024-07-11 09:11:37

THALLIUM (III) CHLORIDE Properties

Melting point 37°C
form Crystalline Aggregates
Water Solubility It is soluble in water 862g/L
Exposure limits ACGIH: TWA 0.02 mg/m3 (Skin)
Dielectric constant 2.2(20℃)
CAS DataBase Reference 13453-33-3

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Hazard statements  H300-H330-H373-H411
Precautionary statements  P301+P310a-P304+P340-P320-P330-P405-P501a
Hazard Codes  T+,N
Risk Statements  26/28-33-51/53
Safety Statements  13-28-45-61
RIDADR  UN 1707 6.1/PG 2
WGK Germany  3
TSCA  Yes
HazardClass  6.1
PackingGroup  II
NFPA 704
0
4 0

THALLIUM (III) CHLORIDE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Alfa Aesar 041506 Thallium(III) chloride hydrate 13453-33-3 5g $109 2021-12-16 Buy
Alfa Aesar 041506 Thallium(III) chloride hydrate 13453-33-3 25g $490 2021-12-16 Buy
American Custom Chemicals Corporation ING0003112 THALLIUM(III) CHLORIDE TETRAHYDRATE 95.00% 13453-33-3 10G $1168.37 2021-12-16 Buy
Product number Packaging Price Buy
041506 5g $109 Buy
041506 25g $490 Buy
ING0003112 10G $1168.37 Buy

THALLIUM (III) CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

white crystal(s) [STR93]

Chemical Properties

Colorless crystals, deliquescing in moist air. M.p. about 43°C. A saturated aqueous solution (about 86% TlCl3 ? 4 H2O at 17°C) is strongly acidic due to hydrolysis, and precipitates brown Tl2O3 . xH2O when highly diluted. Readily soluble in alcohol and ether; 90-95% of the TlCl3 is extracted from a 6N HCl solution of TlCl3 by shaking with an equal volume of ether.

Synthesis

According to Meyer, TlCl ? 4H2O is prepared by passing Cl2 through a nearly boiling suspension of TlCl in a limited amount of water. After intermediate Tl(I)-T1(III) chloro compounds have dissolved, the solution is evaporated to a thin syrup with continuous addition of Cl2 . The water bath temperature should be 60-70°C. The syrup immediately solidifies to a slurry of fine, white needles of TlCl ? 4 H2O on cooling in an ice bath, larger crystals form on slower cooling. The crystals are rapidly filtered and dried 24 hours over H2SO4 andKOH(virtually no efflorescence). Cushman claims that TlC13 . 4 H2O crystals can only be dried between filter papers if loss of water is to be avoided. Hecht states that he found no definite tetrahydrates.
TlCl + Cl2 + 4H2O = TlCl3 ? 4H2O

THALLIUM (III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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THALLIUM (III) CHLORIDE THALLIUM CHLORIDE (IC) THALLIC CHLORIDE Thallium (III) chloride hydrate (8% H2O) Thallium(III) chloride hydrate (8% H2O) ThalliumchloridehydrateHOwhitextl Thallium(Ⅲ)chloride THALLIUM(III)TRICHLORIDETETRAHYDRATE THALLIUMCHLORIDETETRAHYDRATE THALLIUM CHLORIDE (IC), 99.9% thallium(3+),trichloride,hydrate hallium(3+),trichloride,hydrate 13453-33-3 Cl3Tl TlCl3 TlCl3稾H2O TlCl34H2O TlCl3xH2O Thallium Catalysis and Inorganic Chemistry metal halide Catalysis and Inorganic Chemistry Chemical Synthesis Thallium