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Hexamethylene diacrylate

CAS No.
13048-33-4
Chemical Name:
Hexamethylene diacrylate
Synonyms
HDDA;1,6-HEXANEDIOL DIACRYLATE;Hexanediol acrylate;HDODA;Hexamethylendiacrylat;Hexane-1,6-diyl diacrylate;c716;sr238;nkesterahd;viscoat230
CBNumber:
CB1114704
Molecular Formula:
C12H18O4
Molecular Weight:
226.27
MDL Number:
MFCD00008631
MOL File:
13048-33-4.mol
MSDS File:
SDS
Last updated:2023-10-13 18:16:27

Hexamethylene diacrylate Properties

Melting point 6°C
Boiling point 295°C
Density 1.01 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.456(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility Chlroform (Slightly), DMSO (Slightly)
form Liquid
color Colourless
Specific Gravity 1.01
Water Solubility Slightly miscible with water.
Sensitive Hygroscopic
Stability Light Sensitive
InChIKey FIHBHSQYSYVZQE-UHFFFAOYSA-N
LogP 2.81 at 25℃
CAS DataBase Reference 13048-33-4(CAS DataBase Reference)
FDA UNII FY751V5MMY
NIST Chemistry Reference Hexamethylene diacrylate(13048-33-4)
EPA Substance Registry System 1,6-Hexanediol diacrylate (13048-33-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H317-H319
Precautionary statements  P261-P264-P272-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/38-43
Safety Statements  39
RIDADR  UN 3082 9/PG 3
WGK Germany  2
RTECS  AT1430000
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29161290
NFPA 704
0
2 1

Hexamethylene diacrylate price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 246816 1,6-Hexanediol diacrylate technical grade, 80% 13048-33-4 100g $51 2024-03-01 Buy
Sigma-Aldrich 246816 1,6-Hexanediol diacrylate technical grade, 80% 13048-33-4 500g $122 2024-03-01 Buy
TCI Chemical B2936 1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ) >85.0%(GC) 13048-33-4 25g $27 2024-03-01 Buy
TCI Chemical B2936 1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ) >85.0%(GC) 13048-33-4 500g $103 2024-03-01 Buy
Alfa Aesar 043203 1,6-Hexanediol diacrylate, 99% (reactive esters), stab. with 90ppm hydroquinone 13048-33-4 50g $44.5 2024-03-01 Buy
Product number Packaging Price Buy
246816 100g $51 Buy
246816 500g $122 Buy
B2936 25g $27 Buy
B2936 500g $103 Buy
043203 50g $44.5 Buy

Hexamethylene diacrylate Chemical Properties,Uses,Production

Description

Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.

Sources

  1. https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
  2. Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
  3. https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf

Description

Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.

Chemical Properties

Colorless transparent liquid

Uses

1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.

Uses

1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.

General Description

Clear yellow liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.

Fire Hazard

Hexamethylene diacrylate is probably combustible.

Flammability and Explosibility

Non flammable

629-11-8
292638-85-8
13048-33-4
Synthesis of Hexamethylene diacrylate from 1,6-Hexanediol and acrylic acid methyl ester

Hexamethylene diacrylate Preparation Products And Raw materials

Global( 340)Suppliers
Supplier Tel Email Country ProdList Advantage
SUZHOU SENFEIDA CHEMICAL CO.,LTD
+86-0512-83500002 +8615195660023 sales@senfeida.com China 5100 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58

View Lastest Price from Hexamethylene diacrylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Hexamethylene diacrylate pictures 2024-01-14 Hexamethylene diacrylate
13048-33-4
US $5.00-0.50 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Hexamethylene diacrylate pictures 2023-10-14 Hexamethylene diacrylate
13048-33-4
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Hexamethylene diacrylate pictures 2023-10-11 Hexamethylene diacrylate
13048-33-4
US $0.00-0.00 / kg 1kg 99% 50000kg Hebei Kingfiner Technology Development Co. , Ltd.
HEXAMETHYLENE GLYCOL DIACRYLATE Zinc02019846 1,6-BIS(ACRYLOYLOXY)HEXANE 1,6-HEXAMETHYLENE DIACRYLATE Bisacrylic acid 1,6-hexanediyl ester Bispropenoic acid 1,6-hexanediyl ester Diacrylic acid hexane-1,6-diyl ester 6-Hexanediol diacrylate 1,6-Hexanediol diacrylate, stabilized with 100 ppM HQ 1,6-Hexanediol diacrylate,HDODA Hexamethylene diacry 1,6-Bis(acryloyloxy)hexane  1,6-Hexanediol Diacrylate Hexamethylene Glycol Diacrylate HDDA 1,6-Hexanediol diacrylate Hexanediol diacrylat 2-Propenoic acid,1,1'-(1,6-hexanediyl) ester 1,6-Hexanediol diacrylate technical grade, 80% 1,6-Hexanediol diacrylate, technical, 99% reactive esters, stabilized Photomer 4017 TF HDDA (Hexanediol diacrylate) 1,6-Hexanediol diacrylate, Stabilized with 90ppm hydroquinone 1,6-hexanedioldi-2-propenoate 1,6-HEXANEDIOL DIACRYLATE, TECH., 80% 2-Propenoicacid,1,6-hexanediylester acrylicacid,hexamethyleneester c716 hexamethyleneacrylate hexamethylenediacrylate hexaneglycoldiarcylate kayaradhdda nkesterahd photomer4017 sartomer238 sartomersr238 setaluxuv2243 sr238 viscoat230 ACRYLICACID,DIESTERWITH1,6-HEXANEDIOL Hexane-1,6-diyl bisacrylate 1,6-HEXANEDIOL DIACRYLATE 98% 1,6-Hexanediol diacrylate, 99% (reactive esters), stab. with 90ppm hydroquinone 1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ) 6-Prop-2-enoyloxyhexyl prop-2-enoate Light Acrylate 1 1,6-Hexadiol diacrylate Bis(acrylic acid)1,6-hexanediyl ester hexamethylene diacrylate hexane-1,6-diol diacrylate 1,6-Hexanediol diacrylate, 99%, stab. with 90ppm hydroquinone 1,6-Hexanediol diacrylate, 88%, stabilized with 100 ppm HQ acrylicacid,hexam 1,6-Hexanediyl Ester hexane-1,1-diol HDDA (Hexanediol diacrylate) Photomer 4017 TF 1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ)> 1,6-Hexanediyl bisacrylate 1,6-Hexanediol diacrylate (stabilized with 100 ppm MEHQ) (4R,4aS,7aR,12bR)-4a-ethoxy-9-hydroxy-3,7a-dimethyl-1,2,4,5,6,13-hexahydro-4,12-methanobenzofuro[3,2-e]isoquinoline-7-one 1,6-Hexanediol Diacrylate,99%