- Hexamethylene diacrylate
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- $0.00 / 200KG
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2026-05-19
- CAS:13048-33-4
- Min. Order: 200KG
- Purity: 98%min
- Supply Ability: 30tons/month
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| | Hexamethylene diacrylate Chemical Properties |
| Melting point | 6°C | | Boiling point | 295°C | | density | 1.01 g/mL at 25 °C (lit.) | | vapor density | >1 (vs air) | | vapor pressure | <0.01 mm Hg ( 20 °C) | | refractive index | n20/D 1.456(lit.) | | Fp | >230 °F | | storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C | | solubility | Chlroform (Slightly), DMSO (Slightly) | | form | Liquid | | Specific Gravity | 1.01 | | color | Colourless | | Odor | Mild ester-like odor | | Water Solubility | Slightly miscible with water. | | FreezingPoint | 6 | | Sensitive | Hygroscopic | | Stability: | Light Sensitive | | InChI | 1S/C12H18O4/c1-3-11(13)15-9-7-5-6-8-10-16-12(14)4-2/h3-4H,1-2,5-10H2 | | InChIKey | FIHBHSQYSYVZQE-UHFFFAOYSA-N | | SMILES | C=CC(=O)OCCCCCCOC(=O)C=C | | LogP | 2.81 at 25℃ | | CAS DataBase Reference | 13048-33-4(CAS DataBase Reference) | | NIST Chemistry Reference | Hexamethylene diacrylate(13048-33-4) | | EPA Substance Registry System | 1,6-Hexanediol diacrylate (13048-33-4) |
| Hazard Codes | Xi | | Risk Statements | 36/38-43 | | Safety Statements | 39 | | RIDADR | UN 3082 9/PG 3 | | WGK Germany | 2 | | RTECS | AT1430000 | | TSCA | TSCA listed | | HazardClass | 9 | | PackingGroup | III | | HS Code | 29161290 | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Aquatic Acute 1
Aquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
Skin Sens. 1 | | Hazardous Substances Data | 13048-33-4(Hazardous Substances Data) |
| | Hexamethylene diacrylate Usage And Synthesis |
| Description | Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.
| | Sources |
- https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
- Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
- https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf
| | Description | Sensitizaion occurred after accidental occupational
exposure in an employee in the laboratory of a plastic
paint factory. | | Chemical Properties | Colorless transparent liquid | | Uses | 1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance. | | Uses | 1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.;
monomer in dental composite materials. | | General Description | Clear yellow liquid. | | Air & Water Reactions | Insoluble in water. | | Reactivity Profile | Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides. | | Fire Hazard | Hexamethylene diacrylate is probably combustible. | | Flammability and Explosibility | Non flammable | | Synthesis | 1,6-Hexanediol diacrylate was synthesized by esterification reaction using 1,6-hexanediol and acrylic acid as the raw materials, strongly acidic cationic resin D072 as the catalyst, cyclohexane as the water-carrying agent, and hydroquinone as the polymerization blocking agent. The experimental results showed that the optimum conditions for the esterification reaction were as follows: "(acrylic acid):"(1,6-hexanediol) 2.2, catalyst dosage (mass ratio of raw material) 2.5%, polymerization blocker dosage (mass ratio of acrylic acid) 0.6%, water-carrying agent dosage (mass ratio of raw material) 70O.4, reaction time 4h, reaction temperature 80-110 . 1,6-Hexanediol diacrylate was synthesized. The product yield reached 93.88%.
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| | Hexamethylene diacrylate Preparation Products And Raw materials |
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