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4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE

CAS No.
139-25-3
Chemical Name:
4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE
Synonyms
diisocyanatodimethyldiphenylmethane;5,5’-methylenebis(2-isocyanato-toluen;5,5’-methylenebis(2-isocyanatotoluene);BENZENE11METHYLENEBIS4ISOCYANATO3METHYL;BIS(4-ISOCYANATO-3-METHYLPHENYL)METHANE;isocyanicacid,esterwithdi-o-toluenemethane;4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE;3,3'-DIMETHYLDIPHENYLMETHANE-4,4'-DIISOCYANATE;1,1’-methylenebis[4-isocyanato-3-methyl-benzen;benzene,1,11-methylenebis(4-isocyanato-3-methyl-
CBNumber:
CB1408120
Molecular Formula:
C17H14N2O2
Molecular Weight:
278.31
MDL Number:
MFCD00019910
MOL File:
139-25-3.mol
Last updated:2023-05-04 15:14:07

4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE Properties

Boiling point 421.12°C (rough estimate)
Density 1.1222 (rough estimate)
refractive index 1.5500 (estimate)
CAS DataBase Reference 139-25-3
FDA UNII 3D7H11TIK1
EPA Substance Registry System 3,3'-Dimethyldiphenylmethane-4,4'-diisocyanate (139-25-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS08,GHS07,GHS09
Signal word  Danger
Hazard statements  H334-H319-H315-H410-H335-H332
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P261-P285-P304+P341-P342+P311-P501-P264-P280-P302+P352-P321-P332+P313-P362-P261-P271-P304+P340-P312-P273-P391-P501
RTECS  NQ8820000
Toxicity mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00946,

4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Biosynth Carbosynth FD62629 4,4'-Diisocyanato-3,3'-dimethyldiphenylmethane 139-25-3 10g $376 2021-12-16 Buy
American Custom Chemicals Corporation CHM0011252 4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE 95.00% 139-25-3 1G $694.85 2021-12-16 Buy
Biosynth Carbosynth FD62629 4,4'-Diisocyanato-3,3'-dimethyldiphenylmethane 139-25-3 25g $752 2021-12-16 Buy
American Custom Chemicals Corporation CHM0011252 4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE 95.00% 139-25-3 5G $1038.05 2021-12-16 Buy
Product number Packaging Price Buy
FD62629 10g $376 Buy
CHM0011252 1G $694.85 Buy
FD62629 25g $752 Buy
CHM0011252 5G $1038.05 Buy

4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE Chemical Properties,Uses,Production

Uses

4,?4''-?Diisocyanato-?3,?3''-?dimethyldiphenylmeth?ane is a reagent used in the synthesis of polyurethane materials.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.

Reactivity Profile

Isocyanates and thioisocyanates, such as 4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE, are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerization reactions in these materials. Some isocyanates react with water to form amines and liberate carbon dioxide. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence, [Wischmeyer(1969)].

Safety Profile

Poison by intravenous route. A sensitizer. When heated to decomposition it emits toxic fumes of NOx and CN-.

4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 16)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
9ding chemical ( Shanghai) Limited 4009209199 sales@9dingchem.com China 22519 55
Shandong Ono Chemical Co., Ltd. 0539-6362799 20) China 9998 58
Carbosynth -- sales@carbosynth.com United Kingdom 6018 58
1,1’-methylenebis[4-isocyanato-3-methyl-benzen 5,5’-methylenebis(2-isocyanato-toluen 5,5’-methylenebis(2-isocyanatotoluene) benzene,1,11-methylenebis(4-isocyanato-3-methyl- diisocyanatodimethyldiphenylmethane isocyanicacid,esterwithdi-o-toluenemethane BIS(4-ISOCYANATO-3-METHYLPHENYL)METHANE 3,3'-DIMETHYLDIPHENYLMETHANE-4,4'-DIISOCYANATE 4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE 4,4'-DIISOTHIOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE BENZENE11METHYLENEBIS4ISOCYANATO3METHYL 4,4''-DIISOCYANATO-3,3-DIMETHYLDIPHENYLMETHANE 98+% 1-isocyanato-4-(4-isocyanato-3-methyl-benzyl)-2-methyl-benzene 1-isocyanato-4-[(4-isocyanato-3-methyl-phenyl)methyl]-2-methyl-benzene 1-isocyanato-4-[(4-isocyanato-3-methylphenyl)methyl]-2-methylbenzene Bis(4-isocyanato-3-methylphenyl)methane 3,3'-Dimethyldiphenylmethane-4,4'-diisocyanate 139-25-3 Diphenylmethanes (for High-Performance Polymer Research) Reagent for High-Performance Polymer Research Diphenylmethanes (for High-Performance Polymer Research) Functional Materials Reagent for High-Performance Polymer Research