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Dicyclopentadiene

Dicyclopentadiene
Dicyclopentadiene structure
CAS No.
77-73-6
Chemical Name:
Dicyclopentadiene
Synonyms
DCPD;C10H12;1,3-cpd;DCPD90%;3a,4,7,7a-Te;Dicyclopentadi;Dicyopentadiene;Dicyklopentadien;Dicyclpentadiene;Dicyclopentadien
CBNumber:
CB3854309
Molecular Formula:
C10H12
Formula Weight:
132.2
MOL File:
77-73-6.mol

Dicyclopentadiene Properties

Melting point:
33 °C(lit.)
Boiling point:
170 °C(lit.)
Density 
0.986 g/mL at 25 °C(lit.)
vapor pressure 
3 hPa (20 °C)
refractive index 
n20/D 1.511
Flash point:
114 °F
storage temp. 
Flammables area
form 
Liquid
color 
Clear
Odor
Camphor-like.
explosive limit
0.8-6.3%(V)
Water Solubility 
Immiscible with water.
FreezingPoint 
31.5℃
Merck 
14,2739
BRN 
1904092
Stability:
Stable at room temperature, but may form explosive peroxides if stored in contact with air. Incompatible with oxidizing agents. Decomposes on heating. Flammable. Mixtures of the vapour with air are explosive.
InChIKey
HECLRDQVFMWTQS-UHFFFAOYSA-N
CAS DataBase Reference
77-73-6(CAS DataBase Reference)
NIST Chemistry Reference
4,7-Methano-1H-indene, 3a,4,7,7a-tetrahydro-(77-73-6)
EPA Substance Registry System
4,7-Methano-1H-indene, 3a,4,7,7a-tetrahydro-(77-73-6)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F,Xn,N,T
Risk Statements  11-20/22-36/37/38-51/53-23-22-10
Safety Statements  36/37-61-45-26
RIDADR  UN 2048 3/PG 3
WGK Germany  3
RTECS  PC1050000
Autoignition Temperature 503 °C
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29021990
Hazardous Substances Data 77-73-6(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 353 mg/kg LD50 dermal Rabbit 4940 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
P210, P240,P241, P280, P370+P378
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P391 Collect spillage. Hazardous to the aquatic environment
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

Dicyclopentadiene price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 454338 Dicyclopentadiene contains BHT as stabilizer 77-73-6 1kg $65.4 2018-11-13 Buy
Sigma-Aldrich 454338 Dicyclopentadiene contains BHT as stabilizer 77-73-6 2.5kg $153 2018-11-13 Buy
TCI Chemical D0443 Dicyclopentadiene (stabilized with BHT)[precursor to Cyclopentadiene] >97.0%(GC) 77-73-6 25mL $16 2018-11-22 Buy
TCI Chemical D0443 Dicyclopentadiene (stabilized with BHT)[precursor to Cyclopentadiene] >97.0%(GC) 77-73-6 500mL $28 2018-11-22 Buy
Alfa Aesar 032546 Dicyclopentadiene, typically 95%, stab. 77-73-6 1kg $46 2018-11-16 Buy

Dicyclopentadiene Chemical Properties,Uses,Production

Chemical Properties

colourless crystals with a camphor-like odour

Chemical Properties

Cyclopentadiene is a crystalline solid or a liquid (above 32°C) with a disagreeable, camphor-like odor. The Odor Threshold is 0.011 (detectable); 0.020 ppm (recognizable).

General Description

A liquid with an acrid odor. Flash point 90°F. The vapors are irritating to the eyes and respiratory system. Subject to polymerization if subjected to heat for prolonged periods or if contaminated. If the polymerization takes place inside a container, the container may violently rupture. Insoluble in water. Density 8.2 lb / gal. Used in paints, varnishes, as an intermediate in insecticides, as a flame retardant in plastics.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Dicyclopentadiene may react vigorously with oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. Can undergo exothermic polymierization reactions In the presence of various catalysts (such as acids) or initiators, if subjected to heat for prolonged periods, or if contaminated. Many undergo autoxidation upon exposure to the air to form explosive peroxides.

Health Hazard

LIQUID OR SOLID: Irritating to skin and eyes.

Fire Hazard

FLAMMABLE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area.

Fire Hazard

Flash Point (°F): 90 ℃; Flammable Limits in Air (%): 0.8-6.3; Fire Extinguishing Agents: Foam, carbon dioxide, dry chemical, or water spray; Fire Extinguishing Agents Not To Be Used: Not pertinent; Special Hazards of Combustion Products: Not pertinent; Behavior in Fire: Not pertinent; Ignition Temperature (°F): 941; Electrical Hazard: Data not available; Burning Rate: Data not available.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: May occur in presence of acids, but not hazardous; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation. Mildly toxic by skin contact. A severe skin and moderate eye irritant. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam. When heated to decomposition it emits acrid smoke and fumes.

Potential Exposure

This compound is used in the manufacture of cyclopentadiene as a pesticide intermediate; in the production of ferrocene compounds; in paints, varnishes, and resin manufacture; in production of elastomers, resin systems, and polymers.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit

Shipping

UN2048 Dicyclopentadiene must carry a “FLAMMABLE LIQUID” label. It falls in Hazard Class 3

Incompatibilities

Forms explosive mixture with air above flash point. Depolymerizes at boiling point and forms two molecules of cyclopentadiene; unless inhibited and maintained under inert atmosphere to prevent polymerization. Violent reaction with strong oxidizers; strong acids; strong bases. Can accumulate static electrical charges, and may cause ignition of its vapors

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Dicyclopentadiene Preparation Products And Raw materials

Raw materials

Preparation Products


Dicyclopentadiene Suppliers

Global( 216)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Jinan Finer Chemical Co., Ltd
+86-531-88989536
+86-531-88989539 sales@finerchem.com CHINA 479 58
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22043 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20786 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1374 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Hangzhou FandaChem Co.,Ltd.
0086 158 5814 5714 (Mobile; WhatsApp; Telegram)
+86-571-56059825 fandachem@gmail.com CHINA 2444 55
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 24118 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20243 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 4525 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19997 58

View Lastest Price from Dicyclopentadiene manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-20 Dicyclopentadiene
77-73-6
US $1.00 / kg 1kg 98% 200kg career henan chemical co
2018-09-04 Dicyclopentadiene,DCPD, Cyclopentadiene Dime
77-73-6
US $1.00 / G 100G 99.9% 50000tons Hebei Ruishun Trade Co.,Ltd
2018-08-27 Dicyclopentadiene,DCPD, Cyclopentadiene Dime
77-73-6
US $1.00 / G 100G 99% 50000tons Hebei Ruishun Trade Co.,Ltd

Dicyclopentadiene Spectrum


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