METHYL JASMONATE
- CAS No.
- 1211-29-6
- Chemical Name:
- METHYL JASMONATE
- Synonyms
- Methyl cis-jasmonate;JASMONIC ACID METHYL ESTER;(1R)-3-Oxo-2α-[(Z)-2-pentenyl]-1α-cyclopentaneacetic acid methyl ester;Cmc_7389;Cmc_13964;FEMA 3410;JASMONEIGE;,2beta(z)]]-;METHYL JASMONATE;(-)-methyljasmonate
- CBNumber:
- CB4100148
- Molecular Formula:
- C13H20O3
- Molecular Weight:
- 224.3
- MDL Number:
- MFCD00151382
- MOL File:
- 1211-29-6.mol
- MSDS File:
- SDS
| alpha | D -76.5° (c = 3.4 in CH3OH) |
|---|---|
| Boiling point | 110 °C0.2 mm Hg(lit.) |
| Density | 1.03 g/mL at 25 °C(lit.) |
| FEMA | 3410 | METHYL JASMONATE |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| Odor | at 100.00 %. floral fresh petal magnolia oily waxy |
| Odor Type | floral |
| JECFA Number | 1400 |
| LogP | 2.12 |
| CAS DataBase Reference | 1211-29-6(CAS DataBase Reference) |
| Substances Added to Food (formerly EAFUS) | METHYL JASMONATE |
| FDA UNII | 900N171A0F |
| EPA Substance Registry System | Cyclopentaneacetic acid, 3-oxo-2-(2Z)-2-pentenyl-, methyl ester, (1R,2R)- (1211-29-6) |
METHYL JASMONATE price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | J210535 | (-)-JasmonicAcidMethylEster | 1211-29-6 | 5mg | $880 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | API0013577 | 3-OXO-2-(2-PENTENYL)CYCLOPENTANEACETIC ACID METHYL ESTER 95.00% | 1211-29-6 | 5G | $1163.09 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | API0013577 | 3-OXO-2-(2-PENTENYL)CYCLOPENTANEACETIC ACID METHYL ESTER 95.00% | 1211-29-6 | 1G | $224.7 | 2021-12-16 | Buy |
| Chemenu | CM202237 | Methyl2-((1R,2R)-3-oxo-2-((Z)-pent-2-en-1-yl)cyclopentyl)acetate 95% | 1211-29-6 | 100g | $317 | 2021-12-16 | Buy |
| Crysdot | CD13025718 | Methyl2-((1R,2R)-3-oxo-2-((Z)-pent-2-en-1-yl)cyclopentyl)acetate 95+% | 1211-29-6 | 100g | $339 | 2021-12-16 | Buy |
METHYL JASMONATE Chemical Properties,Uses,Production
Description
Methyl jasmonate has a powerful, floral-herbaceous, sweet, persistent odor. Can be isolated from jasmine oil; or it may be prepared synthetically (probably in the trans-form) from muconic acid via the methyl-3-oxo-cyclopenthyl acetate.
Chemical Properties
METHYL JASMONATE is a volatile component of jasmine flower absolute. It is
a colorless to pale yellow liquid, bp0.125 kPa 116–118 °C, d20
20 1.022–1.028, n20
D
1.473–1.477, possessing an odor reminiscent of the floral heart of jasmine.
Synthesis of the title compound is accomplished by reaction of (2Z)-2-buten-1-yl
bromide with Li in the presence of copper-(I) iodide, and the product is treated
with a mixture of 2-methylene- and 4-methylene-3-oxocyclopentylacetic acid
methyl ester. The aforementioned ester mixture is obtained by reaction of methyl
3-oxocyclopentylacetate with formaldehyde.
An alternative route uses a palladium-catalyzed decarboxylation of the readily
available substituted allyl 2-oxocyclopentanecarboxylates, which leads to the
corresponding cyclopentenones. Addition of dimethylmalonate, with subsequent
saponification/decarboxylation and, if necessary, (Z)-selective hydrogenation,
yields methyl jasmonate:
Methyl jasmonate exists in an equilibrium mixture in which the trans-isomer
dominates. But of all possible four enantiomeric isomers, chiefly the minor (+)-cis-isomer is responsible for the typical sensory properties of methyl jasmonate.
Therefore, several approaches to obtain this material selectively have been developed
either by directed syntheses or by enrichment using
special isomerization distillation techniques.
Methyl jasmonate is used in fine fragrances where it provides rich, soft effects in jasmine and muguet compositions.
Chemical Properties
Methyl jasmonate has a powerful, floral–herbaceous, sweet, persistent odor.
Occurrence
Reportedly identified in jasmine oil (Jasminum grandiflorum L.) and in Tunisian rosemary. Also found in lemon peel oil, peppermint oil and green and fermented tea
Uses
(-)-Jasmonic Acid Methyl Ester can be used in biological study where it can exert concn.-dependent effect on SE1 and upregulated SE1 expression in both young and mature leaves of Gynostemma pentaphyllum, with greater upregulation in young leaves than in mature leaves.
Uses
Methyl ester in perfumes.
Definition
ChEBI: A jasmonate ester that is the methyl ester of jasmonic acid.
Aroma threshold values
Detection: 5.7 ppm
Taste threshold values
Taste characteristics at 15 ppm: floral, fruity, green, waxy, seedy and melon-like
Trade name
Jasmoneige® (Nippon Zeon), Splendione® (Firmenich)
Synthesis
Can be isolated from jasmine oil; synthetically it can be prepared (probably in the trans-form) from muconic acid via the methyl-3-oxo-cyclopentyl acetate
METHYL JASMONATE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Henan Tengmao Chemical Technology Co. LTD | +8615238638457 | salesvip2@hntmhg.com | China | 415 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8822 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
View Lastest Price from METHYL JASMONATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-15 | Methyl (2-pent-2-enyl-3-oxo-1-cyclopentyl)acetate
1211-29-6
|
US $1.00 / g | 10g | 99 | 100ton | ANHUI SHENGZHIKAI BIOTECHNOLOGY CO.,LTD | |
 |
2023-12-13 | Methyl jasmonate
1211-29-6
|
US $110.00-90.00 / kilogram | 1kilogram | 99% | 10 tons/per week | Henan Tengmao Chemical Technology Co. LTD | |
 |
2023-09-27 | Methyl Jasmonate
1211-29-6
|
US $20.00-1.00 / kg | 1kg | 0.99 | 20 ton | Hebei Yanxi Chemical Co., Ltd. |
-
- Methyl (2-pent-2-enyl-3-oxo-1-cyclopentyl)acetate
1211-29-6
- US $1.00 / g
- 99
- ANHUI SHENGZHIKAI BIOTECHNOLOGY CO.,LTD
-
- Methyl jasmonate
1211-29-6
- US $110.00-90.00 / kilogram
- 99%
- Henan Tengmao Chemical Technology Co. LTD
-
- Methyl Jasmonate
1211-29-6
- US $20.00-1.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
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