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3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole structure

CAS No.: 365564-11-0

Chemical Name:: 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole

Synonyms: 1-(Triisopropylsilyl)-1H-...;N-TIPS pyrrole-3-boronic acid pinacol ester;1-(Triisopropylsilyl)pyrrole-3-boronic Acid Pinacol Ester;1-(Triisopropylsilyl)-1H-pyrrole-3-boronic acid pinacol ester;1-(triisopropylsilyl)-1H-pyrrol-3-ylboronic acid pinacol ester;3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(tripropan...;1-(Triisopropylsilyl)-1H-pyrrole-3-boronic acid pinacol ester - [T7679];3-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(propan-2-yl)silyl]-1H-pyrrole;3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole;tri(propan-2-yl)-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrrol-1-yl]silane

CBNumber:: CB42520180

Molecular Formula:: C19H36BNO2Si

Molecular Weight:: 349.39

MDL Number:: MFCD08063117

MOL File:: 365564-11-0.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-04-24 14:58:19

Product description	Number	Pack Size	Price
3-(Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(propan-2-yl)silyl]-1H-pyrrole	T302793	50mg	$45
3-(Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(propan-2-yl)silyl]-1H-pyrrole	T302793	500mg	$90
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(1-methylethyl)silyl]-1H-pyrrole 95+%	096383	1g	$152
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(1-methylethyl)silyl]-1H-pyrrole	CS-0051659	1g	$75
1-(Triisopropylsilyl)-1H-pyrrole-3-boronic acid, pinacol ester	8H87-1-06	1g	$88
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3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole Properties

Melting point	59 °C
Boiling point	383.6±15.0 °C(Predicted)
Density	0.94±0.1 g/cm3(Predicted)
storage temp.	Storage temp. 2-8°C
pka	-2.53±0.70(Predicted)
form	Powder or Solid
color	White to yellow
InChI	InChI=1S/C19H36BNO2Si/c1-14(2)24(15(3)4,16(5)6)21-12-11-17(13-21)20-22-18(7,8)19(9,10)23-20/h11-16H,1-10H3
InChIKey	GWFIZBYDIHGZRJ-UHFFFAOYSA-N
SMILES	N1([Si](C(C)C)(C(C)C)C(C)C)C=CC(B2OC(C)(C)C(C)(C)O2)=C1

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302
Precautionary statements	P280-P305+P351+P338
HS Code	2933998090

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole price More Price(26)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TRC	T302793	3-(Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(propan-2-yl)silyl]-1H-pyrrole	365564-11-0	50mg	$45	2021-12-16	Buy
TRC	T302793	3-(Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(propan-2-yl)silyl]-1H-pyrrole	365564-11-0	500mg	$90	2021-12-16	Buy
Matrix Scientific	096383	3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(1-methylethyl)silyl]-1H-pyrrole 95+%	365564-11-0	1g	$152	2021-12-16	Buy
ChemScene	CS-0051659	3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(1-methylethyl)silyl]-1H-pyrrole	365564-11-0	1g	$75	2021-12-16	Buy
SynQuest Laboratories	8H87-1-06	1-(Triisopropylsilyl)-1H-pyrrole-3-boronic acid, pinacol ester	365564-11-0	1g	$88	2021-12-16	Buy

Product number	Packaging	Price	Buy
T302793	50mg	$45	Buy
T302793	500mg	$90	Buy
096383	1g	$152	Buy
CS-0051659	1g	$75	Buy
8H87-1-06	1g	$88	Buy

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole Chemical Properties,Uses,Production

Synthesis

87630-36-2

25015-63-8

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole

365564-11-0

To a stirred solution of 3-bromo-1-(triisopropylmethylsilyl)pyrrole (6.50 g, 21.50 mmol) and pinacolborane (4.13 g, 32.25 mmol) in toluene (120 mL) was sequentially added PdCl2(ACN)2 (0.45 g, 1.72 mmol), dicyclohexyl (2',6'-dimethoxybiphenyl-2-yl)phosphine (2.65 g, 6.45 mmol) and triethylamine (6.53 g, 64.50 mmol). The reaction mixture was degassed twice with nitrogen and subsequently heated to 90 °C and kept for 16 hours. The progress of the reaction was monitored by thin layer chromatography (TLC) and after confirming complete consumption of the raw materials the reaction was stopped and cooled to room temperature. The reaction mixture was diluted with ethyl acetate (200 mL), filtered through a pad of diatomaceous earth and the filtrate was concentrated under reduced pressure. The residue was purified by column chromatography (eluent ratio: ethyl acetate/hexane from 1/200 to 1/50) to afford the target product 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(1-methylethyl)methanesilyl]-1H-pyrrole (3.50 g, 46% yield) as a white solid.

References

[1] Angewandte Chemie - International Edition, 2006, vol. 45, # 21, p. 3484 - 3488
[2] Journal of the American Chemical Society, 2007, vol. 129, # 11, p. 3358 - 3366
[3] Journal of Organic Chemistry, 2008, vol. 73, # 14, p. 5589 - 5591
[4] Organic Letters, 2010, vol. 12, # 19, p. 4224 - 4227

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole Preparation Products And Raw materials

Raw materials

Pinacol 3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE Bis(pinacolato)diboron Pinacolborane 1-(TRIISOPROPYLSILYL)PYRROLE

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHOXY-1,1'-BIPHENYL Toluene Triethylamine Bis(acetonitrile)dichloropalladium(II)

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Preparation Products

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole Suppliers

Global( 74)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	+86-13017695106 +86-13676922317	jiuyitime@fdachem.com	China	16513	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21142	58
Alfa Chemistry	+1-5166625404;	Info@alfa-chemistry.com	United States	20405	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418684 +8618949823763	sales@tnjchem.com	China	25356	58
Shanghai Acmec Biochemical Technology Co., Ltd.	+86-18621343501; +undefined18621343501	product@acmec-e.com	China	33324	58
Aladdin Scientific		tp@aladdinsci.com	United States	52923	58
Suzhou ARTK Medchem Co., Ltd.	+8618118463618	sales1@artkmedchem.com	China	39021	58

Supplier	Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	58
Capot Chemical Co.,Ltd.	60
Accela ChemBio Inc.	58
Alchem Pharmtech,Inc.	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
Alfa Chemistry	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Shanghai Acmec Biochemical Technology Co., Ltd.	58
Aladdin Scientific	58
Suzhou ARTK Medchem Co., Ltd.	58

View Lastest Price from 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2026-04-17	3-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(propan-2-yl)silyl]-1H-pyrrole 365564-11-0	US $3.00-9.00 / KG	0.1KG	99%	g-kg-tons, free sample is available	ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

3-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(propan-2-yl)silyl]-1H-pyrrole
365564-11-0
US $3.00-9.00 / KG
99%
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole Spectrum

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole(365564-11-0)¹HNMR

365564-11-0(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole)Related Search:

3-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-5-(piperidin-4-yl)pyridine 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole-2,4,5-d3 3-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)-5-(trifluoroMethyl)benzonitrile dimethylsilanediol 2-Methylbenzo[d]oxazol-6-ylboronic acid pinacol ester

4-METHYLPYRIDINE-2-BORONIC ACID PINACOL ESTER 2-(2,5-Dihydrofuran-3-yl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane 2-(TRIFLUOROMETHYL)PYRIDINE-4-BORONIC ACID PINACOL ESTER 1-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole 6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzo[d]thiazole

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1-(Triisopropylsilyl)-1H-... 1-(Triisopropylsilyl)-1H-pyrrole-3-boronic acid pinacol ester 1H-Pyrrole, 3-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(1-Methylethyl)silyl]- 3-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(1-Methylethyl)silyl]-1H-pyrrole N-TIPS pyrrole-3-boronic acid pinacol ester 1-(triisopropylsilyl)-1H-pyrrol-3-ylboronic acid pinacol ester 3-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1-[tris(propan-2-yl)silyl]-1H-pyrrole 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)-1H-pyrrole 1-(Triisopropylsilyl)pyrrole-3-boronic Acid Pinacol Ester tri(propan-2-yl)-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrrol-1-yl]silane 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(tripropan... 1-(Triisopropylsilyl)-1H-pyrrole-3-boronic acid pinacol ester - [T7679] 365564-11-0