ChemicalBook >> CAS DataBase List >>Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
- CAS No.
- 63995-70-0
- Chemical Name:
- Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
- Synonyms
- TPPTS;Sodium 3,3',3''-phosphanetriyltribenzenesulfonate;TRIS(3-SULFONATOPHENYL)PHOSPHINE HYDRATE SODIUM SALT;TRIS(3;TPPTS-Na;10% oxide);Triphenylphosphine-3,3;TRISODIUM TRIPHENYLPHOSPHINE-3 3' 3''-T&;TRI(M-SULFOPHENYL)PHOSPHINE, SODIUM SALT;TRIS(3-SULFONATOPHENYL) PHOSPHINE HYDRATE
- CBNumber:
- CB5171996
- Molecular Formula:
- C18H16NaO9PS3
- Molecular Weight:
- 526.46
- MDL Number:
- MFCD00221694
- MOL File:
- 63995-70-0.mol
- MSDS File:
- SDS
Last updated:2024-08-21 22:41:43
| Melting point | >300°C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | DMSO (Slightly), Water (Slightly) |
| form | Powder |
| color | white to off-white |
| Water Solubility | Soluble in water. |
| BRN | 3584807 |
| Stability | Hygroscopic |
| FDA UNII | WUE9W42Q27 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26 | |||||||||
| WGK Germany | 1 | |||||||||
| F | 10 | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 744034 | Triphenylphosphine-3,3′,3′′-trisulfonic acid trisodium salt ≥95.0% | 63995-70-0 | 1g | $211 | 2024-03-01 | Buy |
| Sigma-Aldrich | 744034 | Triphenylphosphine-3,3′,3′′-trisulfonic acid trisodium salt ≥95.0% | 63995-70-0 | 5g | $1010 | 2024-03-01 | Buy |
| TCI Chemical | T2187 | Triphenylphosphine-3,3',3''-trisulfonic Acid Trisodium Salt >97.0%(HPLC)(T) | 63995-70-0 | 1g | $95 | 2024-03-01 | Buy |
| TCI Chemical | T2187 | Triphenylphosphine-3,3',3''-trisulfonic Acid Trisodium Salt >97.0%(HPLC)(T) | 63995-70-0 | 5g | $248 | 2024-03-01 | Buy |
| Alfa Aesar | 039538 | Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt hydrate tech. 85% | 63995-70-0 | 0.25g | $120 | 2021-12-16 | Buy |
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Chemical Properties,Uses,Production
Chemical Properties
White to off-white solid
Uses
Tris(3-sulfophenyl)phosphine Trisodium Salt (Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt) is a reagent used in organic synthesis such as benzothiazole-based cycloplatinated chromophores.
Preparation
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt (TPPTS) is synthesized by sulfonation of triphenylphosphine with oleum (i.e., concentrated H2SO4 and SO3). Various parameters (triphenylphosphine/oleum ratio,wt % of SO3, time, temperature, and agitation speed) have been studied and modified to suppress the formation of by-products such as phosphines with a low degree of sulfonation and phosphine oxides. One particularly attractive method employs orthoboric acid B(OH)3, concentrated H2SO4, and a controlled SO3 concentration and cleanly affords either disulfonated ligand (TPPDS) or TPPTS with negligible oxidation and no by-products.
Application
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt (TPPTS) can be used as a capping agent in the synthesis of TPPTS stabilized palladium nanoparticles (PdNPs) using K2PdCl4 as the palladium source and HCOONa as the reductant. The TPPTS stabilized PdNPs are applicable as an efficient catalyst in the aqueous phase Suzuki-Miyaura coupling reaction at room temperature. TPPTS is also a ligand in the metal-catalyzed hydroformylation of functionalized olefins and direct arylation polymerization reactions.
storage
Solid Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt (TPPTS) is substantially stable to air, but bottles of TPPTS should be flushed with N2 or Ar and kept tightly closed for prolonged storage. TPPTS is slowly oxidized to the phosphine oxide in the solution. Therefore, oxygen-free solvents are preferred.
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Preparation Products And Raw materials
Global( 202)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7193 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5882 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 19536 | 58 |
View Lastest Price from Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-09-19 | Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
63995-70-0
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | |
 |
2024-09-12 | Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
63995-70-0
|
US $10.00-171.00 / g | 1g | 0.90 | 25kg | Shanghai UCHEM Inc. | |
 |
2020-03-16 | Triphenylphosphine-3,3',3''-trisulfonic Acid Trisodium Salt
63995-70-0
|
US $1.00-0.00 / KG | 1KG | 99% | 20 tons | Shaanxi Dideu Medichem Co. Ltd |
-
- Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
63995-70-0
- US $5.00-2.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
-
- Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
63995-70-0
- US $10.00-171.00 / g
- 0.90
- Shanghai UCHEM Inc.
-
- Triphenylphosphine-3,3',3''-trisulfonic Acid Trisodium Salt
63995-70-0
- US $1.00-0.00 / KG
- 99%
- Shaanxi Dideu Medichem Co. Ltd
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Triphenylphosphine-3,3'',3''''-trisulfonic acid trisodium salt