ETHYL (DIPHENYLMETHYLSILYL)ACETATE

ETHYL (DIPHENYLMETHYLSILYL)ACETATE structure

CAS No.: 13950-57-7

Chemical Name:: ETHYL (DIPHENYLMETHYLSILYL)ACETATE

Synonyms: ethyl (methyldiphenylsilyl)acetate;ETHYL (DIPHENYLMETHYLSILYL)ACETATE;2-(Methyldiphenylsilyl)acetic acid ethyl ester

CBNumber:: CB5497193

Molecular Formula:: C17H20O2Si

Molecular Weight:: 284.425

MDL Number:: MFCD00042924

MOL File:: 13950-57-7.mol

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ETHYL (DIPHENYLMETHYLSILYL)ACETATE Chemical Properties,Uses,Production

Physical properties

clear to light yellow liquids.

Uses

vinyl 1,1-dication synthetic equivalent in reactions with Grignard reagents; reagent for Peterson synthesis of α,β-un saturated esters.

Preparation

whereas the direct silylation of the lithium enolate of an ester normally results in the formation of a mixture of the α-silyl ester and the corresponding silyl ketene acetal, the same reaction with methyldiphenylchlorosilane gives exclusively the α-methyldiphenylsilyl ester. This direct C-silylation is the best general route to α-silyl esters.

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

ketene

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Suppliers

Global( 2)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51471	80

Supplier	Advantage
Sigma-Aldrich	80

13950-57-7(ETHYL (DIPHENYLMETHYLSILYL)ACETATE)Related Search:

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ethyl (methyldiphenylsilyl)acetate 2-(Methyldiphenylsilyl)acetic acid ethyl ester ETHYL (DIPHENYLMETHYLSILYL)ACETATE 13950-57-7