ChemicalBook >> CAS DataBase List >>Benzyltriphenylphosphonium chloride

Benzyltriphenylphosphonium chloride

CAS No.
1100-88-5
Chemical Name:
Benzyltriphenylphosphonium chloride
Synonyms
BTPPC;BPP;BTPPCl;NSC 116712;AURORA KA-1173;Benzyltriphenylphosp;Benzyltriphenylchlorophosphine;Triphenylbenzylidenephosphorane;BENZYLIDENE(TRIPHENYL)PHOSPHORANE;benzyltriphenyl-phosphoniuchloride
CBNumber:
CB5738942
Molecular Formula:
C25H22ClP
Molecular Weight:
388.87
MDL Number:
MFCD00011913
MOL File:
1100-88-5.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02

Benzyltriphenylphosphonium chloride Properties

Melting point ≥300 °C (lit.)
Density 1.18 g/cm3 (20℃)
vapor pressure 0.1 hPa
Flash point 300°C
storage temp. Store at <= 20°C.
form Crystalline Powder
color White to almost white
Water Solubility SOLUBLE
Sensitive Hygroscopic
BRN 3599868
Stability Stable. Incompatible with strong oxidizing agents.
InChIKey USFRYJRPHFMVBZ-UHFFFAOYSA-M
LogP -0.7 at 20℃
CAS DataBase Reference 1100-88-5(CAS DataBase Reference)
FDA UNII WM5533HY8L
EPA Substance Registry System Phosphonium, triphenyl(phenylmethyl)-, chloride (1100-88-5)
UNSPSC Code 12352107
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H300+H330-H318-H335-H372-H410
Precautionary statements  P260-P273-P280-P304+P340+P310-P305+P351+P338-P314
Hazard Codes  T,Xi
Risk Statements  25-36/37/38-24/25
Safety Statements  26-36/37/39-45-36
RIDADR  UN 2811 6.1/PG 2
WGK Germany  3
RTECS  TA2416500
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29310095
Toxicity LD50 orally in Rabbit: 43 mg/kg
NFPA 704
1
4 1

Benzyltriphenylphosphonium chloride price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B32807 Benzyltriphenylphosphonium chloride 99% 1100-88-5 25g $32.52 2024-03-01 Buy
Sigma-Aldrich B32807 Benzyltriphenylphosphonium chloride 99% 1100-88-5 100g $95.4 2024-03-01 Buy
TCI Chemical B0824 Benzyltriphenylphosphonium Chloride >98.0%(HPLC)(T) 1100-88-5 25g $36 2024-03-01 Buy
TCI Chemical B0824 Benzyltriphenylphosphonium Chloride >98.0%(HPLC)(T) 1100-88-5 500g $391 2024-03-01 Buy
Alfa Aesar A14034 Benzyltriphenylphosphonium chloride, 99% 1100-88-5 100g $77 2024-03-01 Buy
Product number Packaging Price Buy
B32807 25g $32.52 Buy
B32807 100g $95.4 Buy
B0824 25g $36 Buy
B0824 500g $391 Buy
A14034 100g $77 Buy

Benzyltriphenylphosphonium chloride Chemical Properties,Uses,Production

Chemical Properties

Benzyltriphenylphosphonium Chloride is a white to off white powder, It is highly soluble in water and polarizable solvents. It is a quaternary phosphonium salt mainly used in organic synthesis as a wittig reagent and as a phase transfer catalyst in the production of fluoroelastomers and printing inks.

Uses

Benzyltriphenylphosphonium Chloride was used as a reagent in the organic synthesis of several compounds including that of stabilised phosphonium ylides containing saturated oxygen heterocycles. Also used in the synthesis of novel substituted cis-stilbene derivatives which display antimicrobial activity.

Application

Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:
Platinum chloro-tetrazole complexes via azidation.
Trans-stilbenes and cinnamates via Wittig olefination.
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.
Pentiptycenes for use as light-driven molecular brakes.
Archipelago structures for formation of petroleum asphaltenes.
It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.
Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites

Reactant for synthesis of:
Platinum chloro tetrazole complexes via azidation
Trans-stilbenes and cinnamates via Wittig olefination
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
Pentiptycenes for use as light-driven molecular brakes
Reactant for formation of archipelago structures for formation of petroleum asphaltenes

Flammability and Explosibility

Not classified

reaction suitability

reaction type: C-C Bond Formation

Purification Methods

Wash it with Et2O and crystallise it from EtOH (six-sided plates). It is hygroscopic and forms crystals with one molecule of H2O. [Michaelis & Soden Justus Liebigs Ann Chem 229 320 1885, Kr.hnke Chem Ber 83 291 1950, Beilstein 16 IV 994.]

Benzyltriphenylphosphonium chloride Preparation Products And Raw materials

Global( 470)Suppliers
Supplier Tel Email Country ProdList Advantage
Shandong Promise New Material Co.,Ltd.
+86-18678104048 +86-15305334460 johnwang@promisechemical.com China 88 58
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8805 58
Hebei Mujin Biotechnology Co.,Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12830 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325 sales1@chuanghaibio.com China 5888 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20262 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29793 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21632 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 FandaChem@Gmail.com China 8741 55
JingJiang Connect Chemical manufacturing Co., Ltd.
0523-80501690 15252623102 andy@katchemical.com CHINA 59 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +8618949832763 info@tnjchem.com China 2986 55

View Lastest Price from Benzyltriphenylphosphonium chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzyltriphenylphosphonium chloride pictures 2025-02-12 Benzyltriphenylphosphonium chloride
1100-88-5
US $0.00 / KG 1KG 99%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Benzyltriphenylphosphonium chloride pictures 2025-02-12 Benzyltriphenylphosphonium chloride
1100-88-5
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mujin Biotechnology Co.,Ltd
Benzyltriphenylphosphonium chloride pictures 2024-11-21 Benzyltriphenylphosphonium chloride
1100-88-5
US $1.00 / KG 1KG 99% 10 mt Hebei Weibang Biotechnology Co., Ltd
(phenylmethyl)triphenyl-phosphoniuchloride (phenylmethyl)triphenylphosphoniumchloride Benzyltriphenylchlorophosphine benzyltriphenylphosphonidechloride benzyltriphenyl-phosphoniuchloride Phosphonium,triphenyl(phenylmethyl)-,chloride triphenyl(phenylmethyl)-phosphoniuchloride triphenyl(phenylmethyl)phosphoniumchloride Triphenyl(phenylmethyl)-phosphoniumchloride BENZYLIDENE(TRIPHENYL)PHOSPHORANE AURORA KA-1173 Benzyltriphenylphosphoniumchloride,99% BTPPCl: Benzyltriphenylphosphonium Chloride Benzyltriphenylphosphonium chloride BENZYL TRIPHENYL PHOSPHONIUM CHLORIDE(BTTPC) Phosphonium, benzyltriphenyl, chloride Triphenylbenzylidenephosphorane benzyltriphenilphosphonium chloride Benzyltriphenylphosp Benzyl triphenyl phosphorus chloride BenzyltriphenylphosphoniuM chloride (BPP) Three phenylphosphine dichloridebenzyl NSC 116712 Benzyltriphenylphosphonium chloride 99% BTPPCl Phosphonium, triphenyl(phenylmethyl)-, chloride (1:1) Benzyltriphenylphosphonium Chloride > BENZYLTRIPHENYLPHOSPHONIUM CHLORIDE FOR Benzyl triphenyl phosphonium Chloride Solid BTPPC BPP Triphenyl(phenylmethyl)phosphonium Chloride(BTPPC) 1100-88-5 C6H5CH2PClC6H53 C6H5CH2PC6H53Cl C25H21P C25H22ClP C-C Bond Formation Olefination Synthetic Reagents Wittig Reagents organophosphorus compound C-C Bond Formation Olefination Wittig Reagents Pharmaceutical Intermediates Miscellaneous Compounds Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction