Benzyltriphenylphosphonium chloride
- CAS No.
- 1100-88-5
- Chemical Name:
- Benzyltriphenylphosphonium chloride
- Synonyms
- BTPPC;BPP;BTPPCl;NSC 116712;AURORA KA-1173;Benzyltriphenylphosp;Benzyltriphenylchlorophosphine;Triphenylbenzylidenephosphorane;BENZYLIDENE(TRIPHENYL)PHOSPHORANE;benzyltriphenyl-phosphoniuchloride
- CBNumber:
- CB5738942
- Molecular Formula:
- C25H22ClP
- Molecular Weight:
- 388.87
- MDL Number:
- MFCD00011913
- MOL File:
- 1100-88-5.mol
- MSDS File:
- SDS
Melting point | ≥300 °C (lit.) |
---|---|
Density | 1.18 g/cm3 (20℃) |
vapor pressure | 0.1 hPa |
Flash point | 300°C |
storage temp. | Store at <= 20°C. |
form | Crystalline Powder |
color | White to almost white |
Water Solubility | SOLUBLE |
Sensitive | Hygroscopic |
BRN | 3599868 |
Stability | Stable. Incompatible with strong oxidizing agents. |
InChIKey | USFRYJRPHFMVBZ-UHFFFAOYSA-M |
LogP | -0.7 at 20℃ |
CAS DataBase Reference | 1100-88-5(CAS DataBase Reference) |
FDA UNII | WM5533HY8L |
EPA Substance Registry System | Phosphonium, triphenyl(phenylmethyl)-, chloride (1100-88-5) |
UNSPSC Code | 12352107 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() ![]() GHS05,GHS06,GHS08,GHS09 |
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Signal word | Danger | |||||||||
Hazard statements | H300+H330-H318-H335-H372-H410 | |||||||||
Precautionary statements | P260-P273-P280-P304+P340+P310-P305+P351+P338-P314 | |||||||||
Hazard Codes | T,Xi | |||||||||
Risk Statements | 25-36/37/38-24/25 | |||||||||
Safety Statements | 26-36/37/39-45-36 | |||||||||
RIDADR | UN 2811 6.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | TA2416500 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29310095 | |||||||||
Toxicity | LD50 orally in Rabbit: 43 mg/kg | |||||||||
NFPA 704 |
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Benzyltriphenylphosphonium chloride price More Price(25)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | B32807 | Benzyltriphenylphosphonium chloride 99% | 1100-88-5 | 25g | $32.52 | 2024-03-01 | Buy |
Sigma-Aldrich | B32807 | Benzyltriphenylphosphonium chloride 99% | 1100-88-5 | 100g | $95.4 | 2024-03-01 | Buy |
TCI Chemical | B0824 | Benzyltriphenylphosphonium Chloride >98.0%(HPLC)(T) | 1100-88-5 | 25g | $36 | 2024-03-01 | Buy |
TCI Chemical | B0824 | Benzyltriphenylphosphonium Chloride >98.0%(HPLC)(T) | 1100-88-5 | 500g | $391 | 2024-03-01 | Buy |
Alfa Aesar | A14034 | Benzyltriphenylphosphonium chloride, 99% | 1100-88-5 | 100g | $77 | 2024-03-01 | Buy |
Benzyltriphenylphosphonium chloride Chemical Properties,Uses,Production
Chemical Properties
Benzyltriphenylphosphonium Chloride is a white to off white powder, It is highly soluble in water and polarizable solvents. It is a quaternary phosphonium salt mainly used in organic synthesis as a wittig reagent and as a phase transfer catalyst in the production of fluoroelastomers and printing inks.
Uses
Benzyltriphenylphosphonium Chloride was used as a reagent in the organic synthesis of several compounds including that of stabilised phosphonium ylides containing saturated oxygen heterocycles. Also used in the synthesis of novel substituted cis-stilbene derivatives which display antimicrobial activity.
Application
Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:
Platinum chloro-tetrazole complexes via azidation.
Trans-stilbenes and cinnamates via Wittig olefination.
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.
Pentiptycenes for use as light-driven molecular brakes.
Archipelago structures for formation of petroleum asphaltenes.
It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.
Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites
Reactant for synthesis of:
Platinum chloro tetrazole complexes via azidation
Trans-stilbenes and cinnamates via Wittig olefination
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
Pentiptycenes for use as light-driven molecular brakes
Reactant for formation of archipelago structures for formation of petroleum asphaltenes
Flammability and Explosibility
Not classified
reaction suitability
reaction type: C-C Bond Formation
Purification Methods
Wash it with Et2O and crystallise it from EtOH (six-sided plates). It is hygroscopic and forms crystals with one molecule of H2O. [Michaelis & Soden Justus Liebigs Ann Chem 229 320 1885, Kr.hnke Chem Ber 83 291 1950, Beilstein 16 IV 994.]
Benzyltriphenylphosphonium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shandong Promise New Material Co.,Ltd. | +86-18678104048 +86-15305334460 | johnwang@promisechemical.com | China | 88 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8805 | 58 |
Hebei Mujin Biotechnology Co.,Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12830 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5888 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20262 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29793 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21632 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | FandaChem@Gmail.com | China | 8741 | 55 |
JingJiang Connect Chemical manufacturing Co., Ltd. | 0523-80501690 15252623102 | andy@katchemical.com | CHINA | 59 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2986 | 55 |
View Lastest Price from Benzyltriphenylphosphonium chloride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
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2025-02-12 | Benzyltriphenylphosphonium chloride
1100-88-5
|
US $0.00 / KG | 1KG | 99%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
![]() |
2025-02-12 | Benzyltriphenylphosphonium chloride
1100-88-5
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mujin Biotechnology Co.,Ltd | |
![]() |
2024-11-21 | Benzyltriphenylphosphonium chloride
1100-88-5
|
US $1.00 / KG | 1KG | 99% | 10 mt | Hebei Weibang Biotechnology Co., Ltd |
-
- Benzyltriphenylphosphonium chloride
1100-88-5
- US $0.00 / KG
- 99%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Benzyltriphenylphosphonium chloride
1100-88-5
- US $0.00 / KG
- 99%
- Hebei Mujin Biotechnology Co.,Ltd
-
- Benzyltriphenylphosphonium chloride
1100-88-5
- US $1.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
Benzyltriphenylphosphonium chloride Spectrum
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