ChemicalBook >> CAS DataBase List >>(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE structure

CAS No.: 164931-83-3

Chemical Name:: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

Synonyms: (R,R)Jacbosen;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan;RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride;（1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE;(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride;(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent;(R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent;Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-

CBNumber:: CB5761982

Molecular Formula:: C36H52ClCrN2O2

Molecular Weight:: 632.27

MDL Number:: MFCD02684555

MOL File:: 164931-83-3.mol

Last updated:2023-04-23 13:52:06

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Properties

Melting point	>350 °C(lit.)
form	Powder
color	brown

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302+H312+H332
Precautionary statements	P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	26-36
WGK Germany	3

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE price More Price(12)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	531944	(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride	164931-83-3	1g	$85.3	2024-03-01	Buy
Sigma-Aldrich	531944	(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride	164931-83-3	5g	$144.6	2024-03-01	Buy
Strem Chemicals	24-0850	(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride	164931-83-3	1g	$64	2024-03-01	Buy
Strem Chemicals	24-0850	(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride	164931-83-3	5g	$239	2024-03-01	Buy
American Custom Chemicals Corporation	OGM0000040	(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE 95.00%	164931-83-3	1G	$294	2021-12-16	Buy

Product number	Packaging	Price	Buy
531944	1g	$85.3	Buy
531944	5g	$144.6	Buy
24-0850	1g	$64	Buy
24-0850	5g	$239	Buy
OGM0000040	1G	$294	Buy

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Chemical Properties,Uses,Production

Reactions

Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
Catalyst for copolymerization of CO2 and epoxides.
Catalyst for enantioselective alkylation of tributyltin enolates.
Enantioselective addition of Me2Zn to aldehydes.
Enantioselective intramolecular addition of tertiary enamides to ketones.
Asymmetric iodocyclization.
Catalytic intermolecular linear allylic C-H animation.

Uses

Catalyst used for:

Asymmetric anti-Mannich reactions
Coupling reactions
Ring-opening and Diels-Alder reactions
Allylic C-H oxidation of terminal alkenes

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Suppliers

Global( 51)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47465	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12468	58
Alfa Chemistry	+1-5166625404	Info@alfa-chemistry.com	United States	21317	58
VladaChem GmbH	+49-7246-3082843	info@vladachem.de	Germany	1860	58
GIHI CHEMICALS CO.,LIMITED	+8618058761490	info@gihichemicals.com	China	49999	58
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6116	58
LEAPCHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	43348	58
Shanghai Acmec Biochemical Technology Co., Ltd.	+undefined18621343501	product@acmec-e.com	China	33349	58
Chemwill Asia Co.,Ltd.	86-21-51086038	chemwill_asia@126.com	CHINA	23931	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76

Supplier	Advantage
CONIER CHEM AND PHARMA LIMITED	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Alfa Chemistry	58
VladaChem GmbH	58
GIHI CHEMICALS CO.,LIMITED	58
Shaoxin Catsyn Co., Ltd.	58
LEAPCHEM CO., LTD.	58
Shanghai Acmec Biochemical Technology Co., Ltd.	58
Chemwill Asia Co.,Ltd.	58
J & K SCIENTIFIC LTD.	76

164931-83-3((1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE)Related Search:

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE CHROMIUM(II) CHLORIDE Chromium(III) chloride Chromium (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE

(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE N-benzylidenecyclohexylamine

N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE （1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (R,R)Jacbosen RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride (R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent (R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent 164931-83-3 Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Cycloaddition Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents CycloadditionChiral Catalysts, Ligands, and Reagents Privileged Ligands and Complexes SALENs