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ChemicalBook > Product Catalog >Organic Chemistry >Organometalate >(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Suppliers list
Company Name: CONIER CHEM AND PHARMA LIMITED
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Products Intro: Product Name:(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride
CAS:164931-83-3
Purity:0.99 Package:1kg
Company Name: Zhengzhou Alfa Chemical Co.,Ltd
Tel: +8618530059196
Email: sale04@alfachem.cn
Products Intro: CAS:164931-83-3
Purity:97%+ Package:5g;25g;100g;500g;1kg;25kg
Company Name: Alfa Chemistry
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Products Intro: Product Name:(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride
CAS:164931-83-3
Remarks:https://www.alfachemic.com/catalysts/1r-2r-1-2-cyclohexanediamino-n-n-bis-3-5-cas-164931-83-3-item-79340.htm
Company Name: VladaChem GmbH
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Products Intro: Product Name:(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)chromium(III) chloride
CAS:164931-83-3
Remarks:VL320131
Company Name: GIHI CHEMICALS CO.,LIMITED
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Products Intro: Product Name:(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
CAS:164931-83-3
Purity:99 Package:5KG;1KG,25kg
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Basic information
Reactions
Product Name:(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
Synonyms:(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE;（1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride;(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan;Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-;(R,R)Jacbosen;RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride
CAS:164931-83-3
MF:C36H52ClCrN2O2
MW:632.27
EINECS:605-379-1
Product Categories:Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;CycloadditionChiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;SALENs
Mol File:164931-83-3.mol
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Structure
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Chemical Properties
Melting point >350 °C(lit.)
form Powder
color brown
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 26-36
WGK Germany 3
MSDS Information
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Usage And Synthesis
Reactions
  1. Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
  2. Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
  3. Catalyst for copolymerization of CO2 and epoxides.
  4. Catalyst for enantioselective alkylation of tributyltin enolates.
  5. Enantioselective addition of Me2Zn to aldehydes.
  6. Enantioselective intramolecular addition of tertiary enamides to ketones.
  7. Asymmetric iodocyclization.
  8. Catalytic intermolecular linear allylic C-H animation.
Reactions of 164931-83-3_1
Reactions of 164931-83-3_2
UsesCatalyst used for:
  • Asymmetric anti-Mannich reactions
  • Coupling reactions
  • Ring-opening and Diels-Alder reactions
  • Allylic C-H oxidation of terminal alkenes
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Preparation Products And Raw materials
Tag:(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE(164931-83-3) Related Product Information
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE CHROMIUM(II) CHLORIDE Chromium(III) chloride Chromium (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE N-benzylidenecyclohexylamine N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE