ChemicalBook > Product Catalog >Organic Chemistry >Organometalate >(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

Request For Quotation
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Suppliers list
Company Name: CONIER CHEM AND PHARMA LIMITED
Tel: +8618523575427
Email: sales@conier.com
Products Intro: Product Name:(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride
CAS:164931-83-3
Purity:0.99 Package:1kg
Company Name: Zhengzhou Alfa Chemical Co.,Ltd
Tel: +8618530059196
Email: sale04@alfachem.cn
Products Intro: CAS:164931-83-3
Purity:97%+ Package:100g;500g;1kg;50kg;100kg
Company Name: VladaChem GmbH
Tel: +49-7246-3082843
Email: info@vladachem.de
Products Intro: Product Name:(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)chromium(III) chloride
CAS:164931-83-3
Remarks:VL320131
Company Name: GIHI CHEMICALS CO.,LIMITED
Tel: +86-571-86217390; +8618058761490
Email: info@gihichemicals.com
Products Intro: Product Name:(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
CAS:164931-83-3
Purity:99 Package:5KG;1KG,25kg
Company Name: HANGZHOU LEAP CHEM CO., LTD.
Tel: +86-571-87711850
Email: market18@leapchem.com
Products Intro: CAS:164931-83-3
Purity:0 Package:1g; 5g; 25g; 1kg; 5kg; 25kg Remarks:0
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Basic information
Reactions
Product Name:(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
Synonyms:(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE;（1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride;(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan;Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-;(R,R)Jacbosen;RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride
CAS:164931-83-3
MF:C36H52ClCrN2O2
MW:632.27
EINECS:605-379-1
Product Categories:Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;CycloadditionChiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;SALENs
Mol File:164931-83-3.mol
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Structure
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Chemical Properties
Melting point >350 °C(lit.)
storage temp. 2-8°C, protect from light, stored under nitrogen
form Powder
color brown
InChIKeyZWANLSXDTHQDNO-OHRASPNLSA-K
SMILESCC(C)(C)c1cc2\C=N\[C@@H]3CCCC[C@H]3\N=C\c4cc(cc(c4O[Cr](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 26-36
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
MSDS Information
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Usage And Synthesis
Reactions
  1. Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
  2. Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
  3. Catalyst for copolymerization of CO2 and epoxides.
  4. Catalyst for enantioselective alkylation of tributyltin enolates.
  5. Enantioselective addition of Me2Zn to aldehydes.
  6. Enantioselective intramolecular addition of tertiary enamides to ketones.
  7. Asymmetric iodocyclization.
  8. Catalytic intermolecular linear allylic C-H animation.
Reactions of 164931-83-3_1
Reactions of 164931-83-3_2
UsesCatalyst used for:
  • Asymmetric anti-Mannich reactions
  • Coupling reactions
  • Ring-opening and Diels-Alder reactions
  • Allylic C-H oxidation of terminal alkenes
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Preparation Products And Raw materials
Tag:(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE(164931-83-3) Related Product Information
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE CHROMIUM(II) CHLORIDE Chromium(III) chloride Chromium (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE N-benzylidenecyclohexylamine N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE