Benzoic acid, 3-amino-5-ethoxy-, methyl ester (9CI)
- CAS No.
- 706792-04-3
- Chemical Name:
- Benzoic acid, 3-amino-5-ethoxy-, methyl ester (9CI)
- Synonyms
- Methyl 3-amino-5-ethoxybenzoate;3-Amino-5-ethoxybenzoic acid methyl ester;Bnzoic acid, 3-amino-5-ethoxy-, methyl ester;Benzoic acid, 3-amino-5-ethoxy-, methyl ester;Benzoic acid, 3-amino-5-ethoxy-, methyl ester (9CI)
- CBNumber:
- CB61070826
- Molecular Formula:
- C10H13NO3
- Molecular Weight:
- 195.22
- MDL Number:
- MFCD20696913
- MOL File:
- 706792-04-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Methyl3-amino-5-ethoxybenzoate | 7338DF | 10g | $154 |
| Methyl3-amino-5-ethoxybenzoate 98% | A116460 | 25g | $161 |
| Methyl3-amino-5-ethoxybenzoate 95-98% | 61-11633 | 1g | $180 |
| methyl3-amino-5-ethoxybenzoate 95+% | CM153636 | 5g | $184 |
| methyl3-amino-5-ethoxybenzoate 95+% | CM153636 | 10g | $281 |
| More product size | |||
Benzoic acid, 3-amino-5-ethoxy-, methyl ester (9CI) price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| AK Scientific | 7338DF | Methyl3-amino-5-ethoxybenzoate | 706792-04-3 | 10g | $154 | 2021-12-16 | Buy |
| Ambeed | A116460 | Methyl3-amino-5-ethoxybenzoate 98% | 706792-04-3 | 25g | $161 | 2021-12-16 | Buy |
| Abosyn | 61-11633 | Methyl3-amino-5-ethoxybenzoate 95-98% | 706792-04-3 | 1g | $180 | 2021-12-16 | Buy |
| Chemenu | CM153636 | methyl3-amino-5-ethoxybenzoate 95+% | 706792-04-3 | 5g | $184 | 2021-12-16 | Buy |
| Chemenu | CM153636 | methyl3-amino-5-ethoxybenzoate 95+% | 706792-04-3 | 10g | $281 | 2021-12-16 | Buy |
Benzoic acid, 3-amino-5-ethoxy-, methyl ester (9CI) Chemical Properties,Uses,Production
Synthesis
1375150-03-0
706792-04-3
General procedure for the synthesis of methyl 3-amino-5-ethoxybenzoate from methyl 3-ethoxy-5-nitrobenzoate: to methyl 3-ethoxy-5-nitrobenzoate (6.1 kg, 27.1 mol) prepared in step 2, methanol (54 L) and purified water (54 L) were added, followed by 10% palladium/carbon catalyst (6.1 kg, 10% wt/wt) . The reaction was carried out at room temperature with stirring in a hydrogen atmosphere at 4 atmospheres for 2.5 hours. Upon completion of the reaction, acetone (54 L) was added to dilute the reaction mixture, followed by removal of the 10% palladium/carbon catalyst by filtration. Methanol and acetone were removed by distillation under reduced pressure. The resulting solid was filtered and washed with pure water to give the final methyl 3-amino-5-ethoxybenzoate (4.88 kg, 92.2% yield, yellow solid). The product was characterized by 1H-NMR (400 MHz, CDCl3) with the following chemical shifts: δ 6.95 (s, 2H), 6.39 (s, 1H), 4.01 (q, J=6.8Hz, 2H), 3.87 (s, 3H), 3.76 (s, 2H), 1.38 (t, J=6.8Hz, 3H).
References
[1] Patent: US2014/350007, 2014, A1. Location in patent: Paragraph 0082; 0083; 0084
[2] Patent: WO2003/106405, 2003, A1. Location in patent: Page 204-208
Benzoic acid, 3-amino-5-ethoxy-, methyl ester (9CI) Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| Fluoropharm Co., Ltd. | +86-0571-85586753 +86-13336034509 | sales@fluoropharm.com | China | 1445 | 60 |
| Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4327 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| Protheragen-ING | +16313385890 | info@protheragen-ing.com | United States | 3868 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 43339 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Chemwill Asia Co.,Ltd. | 86-21-51086038 | chemwill_asia@126.com | CHINA | 23912 | 58 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42934 | 64 |
| Changzhou Anxuan Chemical, Co., Ltd. | 13912302692 13912302692; | sales@anxuanchem.com | China | 4828 | 58 |
