4-hydrazinylbenzonitrile
- CAS No.
- 17672-27-4
- Chemical Name:
- 4-hydrazinylbenzonitrile
- Synonyms
- 4-hydrazinylbenzonitrile
- CBNumber:
- CB61512342
- Molecular Formula:
- C7H7N3
- Molecular Weight:
- 133.15
- MDL Number:
- MFCD02663085
- MOL File:
- 17672-27-4.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-HYDRAZINO-BENZONITRILE 95.00% | CHM0146989 | 5MG | $505.91 |
| 4-Hydrazinylbenzonitrile | 17672274 | 1g | $795.6 |
| 4-Hydrazinylbenzonitrile 95+% | CD12132049 | 1g | $810 |
4-hydrazinylbenzonitrile price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| American Custom Chemicals Corporation | CHM0146989 | 4-HYDRAZINO-BENZONITRILE 95.00% | 17672-27-4 | 5MG | $505.91 | 2021-12-16 | Buy |
| Alichem | 17672274 | 4-Hydrazinylbenzonitrile | 17672-27-4 | 1g | $795.6 | 2021-12-16 | Buy |
| Crysdot | CD12132049 | 4-Hydrazinylbenzonitrile 95+% | 17672-27-4 | 1g | $810 | 2021-12-16 | Buy |
4-hydrazinylbenzonitrile Chemical Properties,Uses,Production
Synthesis
873-74-5
17672-27-4
The general procedure for the synthesis of 4-hydrazinylbenzonitrile from 4-aminobenzonitrile was as follows: aqueous hydrochloric acid solution was slowly added to a conical flask solution of 4-cyanobenzenamine (6.0 g, 0.050 mol) under cooling conditions. Subsequently, sodium nitrite solution (3.85 g, 0.055 mmol) was added dropwise at -15 °C. The reaction mixture was stirred at 0-10 °C for 15 min and then filtered to remove insoluble matter. The filtrate was slowly added to a pre-cooled hydrochloric acid solution of stannous chloride (24.0 g, 0.166 mmol). The reaction temperature was maintained at -15°C and stirring was continued for 30 minutes. Upon completion of the reaction, the solid product was collected by filtration to afford 5.2 g of the target compound 4-hydrazinylbenzonitrile. The structure of the product was confirmed by 1H NMR (300 MHz, DMSO-d6) with the following characteristic peaks: δ 7.04 (d, 2H), 7.70 (d, 2H), 9.17 (br s, 1H), 10.66 (br s, 2H).
References
[1] Organic Letters, 2015, vol. 17, # 24, p. 6258 - 6261
[2] Journal of the American Chemical Society, 1944, vol. 66, p. 1849
[3] Journal of Organic Chemistry, 2012, vol. 77, # 23, p. 10699 - 10706
[4] Patent: WO2013/186692, 2013, A1. Location in patent: Page/Page column 73
[5] Molecules, 2016, vol. 21, # 11,
4-hydrazinylbenzonitrile Preparation Products And Raw materials
4-hydrazinylbenzonitrile Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52705 | 58 |
| Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49734 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +86-571-86217390; +8618058761490 | info@gihichemicals.com | China | 49968 | 58 |
| Jilin Chinese Academy of Sciences-yanshen Technology | +undefined18143011203 | info@chemextension.com | China | 42056 | 58 |
| Guangzhou CATO Research Chemicals Inc. | +86-020-81960175-617 +8615602392859 | Intermediate@cato-chem.com | China | 3858 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| China Langchem Inc. | 0086-21-58956006 | China | 7811 | 57 |
