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PHENYLTHIOTRIMETHYLSILANE

CAS No.
4551-15-9
Chemical Name:
PHENYLTHIOTRIMETHYLSILANE
Synonyms
Trimethylsilylthiobenzene;PHENYLTHIOTRIMETHYLSILANE;TRIMETHYL(PHENYLTHIO)SILANE;S-(TRIMETHYLSILYL)THIOPHENOL;Phenylthiotrimethylsilane,95%;PHENYL TRIMETHYLSILYL SULFIDE;S-(TRIMETHYLSILYL)BENZENETHIOL;(Phenylthio)trimethylsilane>Trimethyl(phenylthio)silane 97%;Benzene, [(trimethylsilyl)thio]-
CBNumber:
CB8179771
Molecular Formula:
C9H14SSi
Molecular Weight:
182.36
MDL Number:
MFCD00008272
MOL File:
4551-15-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

PHENYLTHIOTRIMETHYLSILANE Properties

Boiling point 72 °C/8 mmHg (lit.)
Density 0.963 g/mL at 25 °C (lit.)
refractive index n20/D 1.532(lit.)
Flash point 87 °F
storage temp. Flammables area
solubility sol organic solvents; incompatible with strong acids and strong oxidizing agents.
form clear liquid
color Colorless to Light yellow
Specific Gravity 0.963
Water Solubility Hydrolyzes in water.
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Sensitive Moisture Sensitive
BRN 1905944
CAS DataBase Reference 4551-15-9(CAS DataBase Reference)
FDA UNII 4854JD2EEB
EPA Substance Registry System Silane, trimethyl(phenylthio)- (4551-15-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H332
Precautionary statements  P210-P302+P352-P304+P340+P312
Hazard Codes  Xn
Risk Statements  10-20-38
Safety Statements  23-28
RIDADR  UN 1993 3/PG 3
WGK Germany  3
3-10-13-21
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29310099
NFPA 704
3
1 0

PHENYLTHIOTRIMETHYLSILANE price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 226467 Trimethyl(phenylthio)silane 97% 4551-15-9 5g $112 2024-03-01 Buy
TCI Chemical P1378 (Phenylthio)trimethylsilane >95.0%(GC) 4551-15-9 5g $88 2024-03-01 Buy
TCI Chemical P1378 (Phenylthio)trimethylsilane >95.0%(GC) 4551-15-9 25g $347 2024-03-01 Buy
TRC P399523 Phenylthiotrimethylsilane 4551-15-9 50mg $45 2021-12-16 Buy
TRC P399523 Phenylthiotrimethylsilane 4551-15-9 500mg $75 2021-12-16 Buy
Product number Packaging Price Buy
226467 5g $112 Buy
P1378 5g $88 Buy
P1378 25g $347 Buy
P399523 50mg $45 Buy
P399523 500mg $75 Buy

PHENYLTHIOTRIMETHYLSILANE Chemical Properties,Uses,Production

Chemical Properties

clear colorless to light yellow liquid

Physical properties

bp 93–99 °C/12 mmHg; d 0.967 g cm?3.

Uses

(Phenylthio)trimethylsilane can be used in selective carbonyl protection; preparation of thioesters and cleavage of ethers.

Purification Methods

Phenylthio trimethylsilane (trimethyl phenylthio silane) [4551-15-9] M 182.4, b 95 -9 9o/12mm, d 4 0.97. Purification is as for phenyl trimethyl silylmethyl sulfide.

PHENYLTHIOTRIMETHYLSILANE Preparation Products And Raw materials

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S-(TRIMETHYLSILYL)BENZENETHIOL S-(TRIMETHYLSILYL)THIOPHENOL PHENYLTHIOTRIMETHYLSILANE PHENYL TRIMETHYLSILYL SULFIDE TRIMETHYL(PHENYLTHIO)SILANE Phenylthiotrimethylsilane(S-Trimethylsilylthiophenol) (Phenylthio)trimethylsilane, Phenyl trimethylsilyl sulfide, S-(Trimethylsilyl)thiophenol Trimethylsilylthiobenzene Phenylthiotrimethylsilane,95% Phenyl Trimethylsilyl Sulfide Trimethyl(phenylthio)silane S-(Trimethylsilyl)benzenethiol Trimethyl(phenylthio)silane 97% (Phenylthio)trimethylsilane> Benzene, [(trimethylsilyl)thio]- 4551-15-9 C6H5SSiCH33 C9H14SSi Building Blocks Sulfur Compounds Organic Building Blocks Protected Thiols/Mercaptans Protection & Derivatization Reagents (for Synthesis) Monoalkoxysilanes Si-O Compounds Si (Classes of Silicon Compounds) Monoalkoxysilanes Protection & Derivatization Reagents (for Synthesis) Si (Classes of Silicon Compounds) Si-O Compounds Synthetic Organic Chemistry