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ALPHA-SOLANINE

CAS No.
20562-02-1
Chemical Name:
ALPHA-SOLANINE
Synonyms
solanine;SOLATUNIN;α-Solanin;SOLATUNINE;a-Solanine;α-Solanine;ALPHA-SOLANIN;ALPHA-SOLANINE;α-Solanine ,99%;SOLANINE, ALPHA
CBNumber:
CB9696314
Molecular Formula:
C45H73NO15
Molecular Weight:
868.07
MDL Number:
MFCD00077873
MOL File:
20562-02-1.mol
Modify Date:
2022-08-11 17:36:43

ALPHA-SOLANINE Properties

Melting point 285℃ (dec.)
Boiling point 780.78°C (rough estimate)
Density 1.40±0.1 g/cm3 (20 ºC 760 Torr)
refractive index 1.5280 (estimate)
storage temp. −20°C
solubility Methanol (Slightly, Heated), Pyridine (Slightly, Sonicated), Water (Slightly, He
form Solid
pka 6.66(at 15℃)
color White to Off-White
Water Solubility 26.04mg/L(15 ºC)
Merck 13,8779
BRN 77607

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312+P330-P501
Hazard Codes  Xn
Risk Statements  22
Safety Statements  1-25-45-24/25
RIDADR  1544
WGK Germany  3
RTECS  WF0250000
10
HazardClass  6.1(b)
PackingGroup  III
HS Code  29399990

ALPHA-SOLANINE price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich S3757 α-Solanine from potato sprouts, ≥95% 20562-02-1 5mg $133 2022-05-15 Buy
Sigma-Aldrich S3757 α-Solanine from potato sprouts, ≥95% 20562-02-1 10mg $198 2022-05-15 Buy
Sigma-Aldrich S3757 α-Solanine from potato sprouts, ≥95% 20562-02-1 50mg $669 2022-05-15 Buy
Sigma-Aldrich PHL80074 α-Solanine phyproof Reference Substance 20562-02-1 10mg $313 2022-05-15 Buy
Usbiological 297738 a-Solanine 20562-02-1 5mg $335 2021-12-16 Buy
Product number Packaging Price Buy
S3757 5mg $133 Buy
S3757 10mg $198 Buy
S3757 50mg $669 Buy
PHL80074 10mg $313 Buy
297738 5mg $335 Buy

ALPHA-SOLANINE Chemical Properties,Uses,Production

Description

This steroidal alkaloid is present in several Solanum species including S. nigrum, S. Iycopersicum (tomato) and S. tuberosum (potato). The base crystallizes in slender needles and shrinks markedly at 235°C. It has [α]20D - 59.45° (pyridine) or - 42.16° (dilute HCl) and is readily soluble in hot EtOH, sparingly so in H20 and virtually insoluble in CHCl 3 or Et2 0. The salts are mostly amorphous although a crystalline hydrochloride has been prepared with m.p. 212°C (dec.). It is not affected by alkalies but mineral acids hydrolyze it to solanidine (q.v.) and one mole each of dextrose, galactose and rhamnose.
Pharmacologically, the alkaloid is a protoplasmic poison and a powerful haemolytic. Poisoning by potatoes sometimes occurs although the results are not usually fatal. The symptoms are nausea, headache, emesis and gastritis. With large doses parenchymatous nephritis and haemoglobinuria occurs with, at times, paralysis of the central nervous system and cardiac arrest. The alkaloid also possesses local irritant properties.

Chemical Properties

White solid

Uses

α-Solanine is produced as a by product in the synthesis of α-Chaconine. α-Chaconine is a glycoalkaloid displaying nerve toxin activity. Potential antifungal activity.

Definition

ChEBI: A glycoalkaloid poison found in species of the nightshade family (Solanaceae), such as the potato (Solanum tuberosum). It is a trisccharide derivative of solanidine [(22beta)-solanid-5-en-3beta-ol].

General Description

This substance is a primary reference substance with assigned absolute purity (considering chromatographic purity, water, residual solvents, inorganic impurities). The exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG

Hazard

A poison.

Purification Methods

Recrystallise -solanine from EtOH, 85% aqueous EtOH, MeOH or aqueous MeOH as dihydrate m 276-278o. It solubility in H2O is 25mg/L and 5% in pyridine, but it is very soluble in Et2O and CHCl3. The hydrochloride is gummy or amorphous but has been crystallised (m ~212o dec). It has insecticidal properties. [Kuhn et al. Chem Ber 88 1492 1955, Beilstein 21 III/IV 1402.]

References

Desfosses.,lahresb., 2, 114 (1820)
Firbas., Monatsh., 10, 541 (1889)
Cazeneuve, Breteau., Compt. rend., 128,887 (1899)
Davis., Pharm. I., 15, 160 (1902)
Wittman., Monatsh., 26,445 (1905)
Colombano., Gazzetta, 38, 19 (1908)
Zemplen, Gerecs., Ber., 61,2294 (1928)
Schopf, Herrmann., ibid, 66, 298 (1933)
Oddo, Caronna., ibid, 67,446 (1934)

ALPHA-SOLANINE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 73)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Zheyan Biotech Co., Ltd.
18017610038 zheyansh@163.com CHINA 3623 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 +86-19930503282 alice@crovellbio.com China 5920 58
BOC Sciences
631-4854226 inquiry@bocsci.com United States 19596 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-87569262 +8618192671955 1017@dideu.com China 3982 58
Zhengzhou Alfa Chemical Co.,Ltd
+86-18530059196 +86-18530059196 sale1@alfachem.cn China 11005 58
TargetMol Chemicals Inc.
+1-781-999-5354 +1-00000000000 marketing@targetmol.com United States 19231 58
Shaanxi Dideu Medichem Co. Ltd
29-89586680 +8618192503167 1005@dideu.com China 9938 58
Dideu Industries Group Limited
029-88380327 +8617691182729 Service@dideu.com China 30009 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
BOC Sciences 16314854226 info@bocsci.com United States 21113 65

View Lastest Price from ALPHA-SOLANINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2021-06-24 ALPHA-SOLANINE USP/EP/BP
20562-02-1
US $1.10 / g 1g 99.9% 100 Tons Min Dideu Industries Group Limited
2021-05-25 ALPHA-SOLANINE
20562-02-1
US $1.00 / PCS 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
2020-05-10 α-Solanine
20562-02-1
US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd
  • ALPHA-SOLANINE
    20562-02-1
  • US $1.00 / PCS
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
  • α-Solanine
    20562-02-1
  • US $1.00 / KG
  • 99%
  • Shaanxi Dideu Medichem Co. Ltd
SOLATUNIN SOLATUNINE beta-d-galactopyranoside,(3beta)-solanid-5-en-3-ylo-6-deoxy-alpha-l-mannopyra POTATOGLYCOALKALOIDS a-Solanine alpha-solanin from potato sprouts A-solanine from potato sprouts alpha-SOLANINE tlc A-SOLANINE WITH TLC [Solanid-5-en-3β-yl]2-O-(6-deoxy-α-L-mannopyranosyl)-3-O-(β-D-glucopyranosyl)-β-D-galactopyranoside 3β-[2-O-(6-Deoxy-α-L-mannopyranosyl)-3-O-(β-D-glucopyranosyl)-β-D-galactopyranosyloxy]solanid-5-ene Solanid-5-en-3β-yl 2-O-(6-deoxy-α-L-mannopyranosyl)-3-O-(β-D-glucopyranosyl)-β-D-galactopyranoside α-Solanin α-Solanidine,from Potao Sprouts α-Solanine ,99% alpha-Solanine froM potato sprouts, >=95% ALPHA-SOLANIN ALPHA-SOLANINE nosyl-(1-2)-o-(beta-d-glucopyranosyl-(1-3))- solanid-5-ene,3-beta-((o-6-deoxy-alpha-l-mannopyranosyl-(1-2)-o-(beta-d-glucop solanid-5-ene,3-beta-((o-6-deoxy-alpha-l-mannopyranosyl-o-(beta-d-glucopyranos solanine yl-beta-d-galactopyranosyl)oxy)- yranosyl-(1-3))-beta-d-galactopyranosyl)oxy)- SOLANINE, ALPHA β-D-Galactopyranoside, (3β)-solanid-5-en-3-yl O-6-deoxy-α-L-mannopyranosyl-(1→2)-O-[β-D-glucopyranosyl-(1→3)]- ALPHA-SOLANINE USP/EP/BP α-Solanine 20562-02-1 C45H73NO15 Complex Molecules Chiral Building Blocks Asymmetric Synthesis Asymmetric Synthesis Chiral Building Blocks Complex Molecules Alkaloids