セレサン 化学特性,用途語,生産方法
解説
酢酸フェニル水銀を主成分とする種子殺菌剤の商品名。塗抹用有機水銀剤で，イネ (いもち病，馬鹿苗病，ごま葉枯病など) ，ムギ (斑葉病，黒穂病など) ，アワ (黒穂病，白髪病) ，ダイズ (紫斑病など) ，アマ (立枯病，炭疽病) ，サツマイモ (黒斑病) などの種子や種芋の消毒に用いられた。
用途
また，消石灰と混合したセレサン石灰はいもち病防除剤として広く用いられたが，水銀の毒性のため 1973年に使用禁止になった。
化学的特性
silver crystals or white solid
使用
Applied at 2% strength (soln or mixed with solids) as a fungicide for treating seeds.
一般的な説明
Silver iridescent crystals or white fluffy solid . Sublimes easily. Sensitive to light. Highly toxic. Causes skin burns and is absorbed through the skin.
空気と水の反応
Insoluble in water.
反応プロフィール
ETHYLMERCURIC CHLORIDE is sensitive to prolonged exposure to light. Incompatible with strong oxidizers such as chlorine .
危険性
Strong irritant.
火災危険
Flash point data for ETHYLMERCURIC CHLORIDE are not available; however, ETHYLMERCURIC CHLORIDE is probably combustible.
安全性プロファイル
Poison by ingestion,
inhalation, skin contact, and intraperitoneal
routes. An experimental teratogen. Other
experimental reproductive effects. Human
mutation data reported. See also
MERCURY COMPOUNDS, ORGANIC.
When heated to decomposition it emits very
toxic fumes of Cland Hg.
職業ばく露
This chemical is used in manufacture of
coatings, resins, and lacquers. Widely known as “Plexiglass”
(in the polymer form), ethyl methacrylate is used to make
polymers, which in turn are used for building, automotive,
aerospace, and furniture industries. It is also used by dentists
as dental plates, artificial teeth, and orthopedic cement.
輸送方法
UN2277 Ethyl methacrylate, stabilized, Hazard
Class: 3; Labels: 3-Flammable liquid
純化方法
Mercuric chloride can be removed by suspending ethylmercuric chloride in hot distilled water, filtering with suction onto a sintered-glass crucible and drying it. Then crystallise it from ethanol and sublime it under reduced pressure. It can also be crystallised from water. [Marvel et al. J Am Chem Soc 47 3009 1925.]
不和合性
May form explosive mixture with air.
Incompatible with oxidizers (chlorates, nitrates, peroxides,
permanganates, perchlorates, chlorine, bromine, fluorine,etc.); contact may cause fires or explosions. Keep away
from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Corrodes some metals. Unless inhibited,
violent polymerization can occur from heat, sunlight, and
contact with strong oxidizers
廃棄物の処理
In accordance with 40CFR
165 recommendations for the disposal of pesticides and
pesticide containers. Must be disposed properly by following package label directions or by contacting your local or
federal environmental control agency, or by contacting
your regional EPA office.
セレサン 上流と下流の製品情報
原材料
準備製品