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ブプロフェジン

ブプロフェジン 化学構造式
69327-76-0
CAS番号.
69327-76-0
化学名:
ブプロフェジン
别名:
アプラウド;2-ターシャリ-ブチルイミノ-3-イソプロピル-5-フェニルテトラヒドロ-4H-1,3,5-チアジアジン-4-オン;2-tert-ブチルイミノテトラヒドロ-3-イソプロピル-5-フェニル-4H-1,3,5-チアジアジン-4-オン;2-tert-ブチルイミノ-3-イソプロピル-5-フェニル-2,3,5,6-テトラヒドロ-4H-1,3,5-チアジアジン-4-オン;アプロード;ブプロジエン;2-t-ブチルイミノ-3-イソプロピル-5-フェニルペルヒドロ-1,3,5-チアジアジン-4-オン;ブプロフェジン標準品;2tブチルイミノ3イソプロピル5フェニルペルヒドロ1,3,5チアジアジン4オン;2-ターシャリ-ブチルイミノ-3-イソプロピル-5-フェニルテトラヒドロ-4H-1,3,5-チアジアジン-4-オン (別名 ブプロフェジン);2-tert-ブチルイミノ-3-イソプロピル-5-フェニルテトラヒドロ-4H-1,3,5-チアジアジン-4-オン;2-ターシャリ-ブチルイミノ-3-イソプロピル-5-フェニルテトラヒドロ -4H-1,3,5-チアジアジン-4-オン(別名ブプロフェジン);ブプロフェジン STANDARD;ブプロフェジン標準物質;ブプロフェジン;ブプロフェジン Standard, 100 µg/mL in MeOH
英語化学名:
Buprofezin
英語别名:
PP618;BUTYL;Aproad;Appland;NNI 750;VIAPPLA;APPLAUD;BUPROLEX;MARATHON;BUPROFEZIN
CBNumber:
CB4436924
化学式:
C16H23N3OS
分子量:
305.44
MOL File:
69327-76-0.mol

ブプロフェジン 物理性質

融点 :
104-106°C
沸点 :
273°C (12 torr)
比旋光度 :
22 º (c=8,6N HCl)
比重(密度) :
1.18
蒸気圧:
1.25 x l0-3 Pa (25 °C)
屈折率 :
1.52-1.522
闪点 :
176-178°C
貯蔵温度 :
0-6°C
酸解離定数(Pka):
3.02±0.20(Predicted)
外見 :
neat
水溶解度 :
0.9 mg/L at 20 ºC
Decomposition :
176-178 ºC
BRN :
8324923
CAS データベース:
69327-76-0(CAS DataBase Reference)
NISTの化学物質情報:
4H-1,3,5-thiadiazin-4-one, 2-((1,1-dimethylethyl)imino)tetrahydro-3-(1-methylethyl)-5-phenyl-(69327-76-0)
EPAの化学物質情報:
Buprofezin (69327-76-0)

安全性情報

RIDADR  UN3077(solid)
WGK Germany  2
RTECS 番号 XI2865000
有毒物質データの 69327-76-0(Hazardous Substances Data)
毒性 LD50 in mice, rats (mg/kg): 10000, 8740 orally; LC50 (48 hr) in carp: 2-10 mg/l (Kanno, 1981)
安衛法 57,57-2
PRTR法 第1種指定化学物質

ブプロフェジン 価格 もっと(7)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-595N ブプロフェジン
Buprofezin
69327-76-0 10mg ¥11800 2021-03-23 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-595NB-100 ブプロフェジン
Buprofezin
69327-76-0 100mg ¥46300 2021-03-23 購入
関東化学株式会社(KANTO) 49801-07 ブプロフェジン標準品
Buprofezin standard
69327-76-0 100mg ¥15000 2021-03-23 購入
Sigma-Aldrich Japan 37886 ブプロフェジン PESTANAL?, analytical standard
Buprofezin PESTANAL?, analytical standard
69327-76-0 100mg ¥3700 2018-12-25 購入
林純薬工業株式会社 99052020 ブプロフェジン ≧95.0%
Buprofezin ≧95.0%
69327-76-0 200mg ¥10000 2021-03-22 購入

ブプロフェジン MSDS


NNI 750

ブプロフェジン 化学特性,用途語,生産方法

用途

農薬(殺虫剤:チアジアジン類誘導体)

農薬用途

殺虫剤、ダニ駆除剤

使用

Buprofezin is a insecticide which works as a chitin synthesis inhibitor. Buprofezin is used to control stubborn rice pests and is effective in controlling green leaf hoppers and white back plant hoppe rs for long durations.

使用

Insecticide.

使用

Buprofezin is a contact and ingested insecticide, active against Homoptera (whiteflies, leafhoppers, scale insects, etc.) in and on citrus, cotton, cucumbers, tomatoes, sweet potatoes, rice, etc.

危険性

Moderately toxic by ingestion. Low toxic- ity by skin contact.

农业用途

Insecticide, Acaricide, Insect growth regulator: For insect control in food crops and greenhouse ornamentals.

製品名

APPLAUD®; NNI-750®

薬理学

The foregoing indicates that the modes of action of buprofezin and benzoylureas could be similar or identical. However, one differing biochemical effect of buprofezin is inhibition of prostaglandin biosynthesis (33), a mechanism that has been suggested as responsible for its ovicidal activity. Subsequently, the in vitro and in vivo effects of buprofezin were found to be strongly antagonized by 20- hydroxyecdysone (34), which also affected prostaglandin biosynthesis. Thus, inhibition of both prostaglandin and chitin biosynthesis by buprofezin was prevented by 20- hydroxyecdysone, so that both effects of the insecticide are mediated via an effect on the hormone concentration or its receptor. Consequently, buprofezin seems to inhibit the drop in the 20-hydroxyecdysone titer that triggers epidermal cell proliferation, old cuticle digestion, and new cuticle deposition, but the detailed mechanism of this action has yet to be established.

代謝経路

Buprofezin gradually decomposes in soils under flooded and upland conditions, with half-lives of 104 and 80 days, respectively. After 150 days, five degradation products are identified as 2-tert- butylimino-5-(4-hydroxyphenyl)-3-isopropylperhydro- 1,3,5-thiadiazin-4-one, 3-isopropyl-5-phenylperhydro- 1,3,5-thiadiazin-2,4-dione, 1-tert-butyl-3-ispropyl-5- phenylbiuret, 1-isopropyl-3-phenylurea, and phenylurea. As minor products, 2-tert-butylimino-5- phenylperhydro-1,3,5-thiadiazin-4-one or buprofezin sulfoxide are found in the flooded or in the upland soils. Since neither formation of 14CO2 nor hydroxylation is observed in the sterile soils, buprofezin seems to have undergone complete mineralization in soils under both conditions through biological transformation by soil microorganisms.

Degradation

Buprofezin (1) was degraded under acidic conditions with half-lives (DT50) f 6-12 days (pH 4), 34 days (pH 6) and 65 days (pH 10) at 40 °C. Opening of the thiadiazinanone ring appeared to be the primary hydrolytic degradation pathway, to yield 1-tert-butyl-3-isopropyl-5-phenyl-2- thiobiuret (2) and N-isopropyl-N-phenylurea (3) as major products.
Buprofezin is stable to aqueous photolysis. The estimated DT50 of buprofezin in distilled water when exposed to UV light was 39 days. A more complex photodegradation pathway of buprofezin in methanol was reported recently (Datta and Walia, 1997) with DT9 values of 4 hours and 15 days under UV and sunlight irradiation, respectively.

ブプロフェジン 上流と下流の製品情報

原材料

準備製品


ブプロフェジン 生産企業

Global( 194)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 20907 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29954 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 37282 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58
CONIER CHEM AND PHARMA LIMITED
86-18523575427
sales@conier.com CHINA 47498 58
Shaanxi Dideu Medichem Co. Ltd
15319487004
029-88380327 1015@dideu.com CHINA 4103 58
Zhuozhou Wenxi import and Export Co., Ltd
+8613111626072 (WhatsApp)
Wechat: +8613111626072 Wickr me: waynehu zzwenxi@126.com CHINA 13187 58

69327-76-0(ブプロフェジン)キーワード:


  • 69327-76-0
  • 3,5-Thiadiazin-4-one,2-[(1,1-dimethylethyl)imino]tetrahydro-3-(1-methylethyl)-5-phenyl-4H-1
  • 4H-1,3,5-Thiadiazin-4-one, 2-((1,1-dimethylethyl)imino)tetrahydro-3-(1-methylethyl)-5-phenyl-
  • 4h-1,3,5-thiadiazin-4-one,2-((1,1-dimethylethyl)imino)tetrahydro-3-(1-methylet
  • Appland
  • Aproad
  • buprofenzin,w.p.
  • Buprofezine
  • NNI 750
  • 2-tert-Butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiodiazin-4-one
  • 2-tert-Butylimino-3-isopropyl-5-phenylperhydro-1,3,5-thiadiazinan-4-one
  • (2Z)-2-([(Z)-1,1-Dimethylethyl]imino)-3-isopropyl-5-phenyl-1,3,5-thiadiazinan-4-one
  • 2-((1,1-dimethylethyl)imino)tetrahydro-3-(1-methylethyl)-5-phenyl-4h-1,3,5-t
  • 2-tert-Butylimino-3-isopropyl-5-phenyl-1,3,5-thiadiazinan-4-one
  • 2-tert-Butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiadiazin-4-one
  • Burprofezin
  • hiadiazin-4-one
  • 2-tert-buthylimino-3-iso-propyl-5-phenyl-3,4,5,6-tetraphydro-2H-1,3,5-thiadiaziana-4-one
  • 2-tert-Butylimino-3-isopropyl-5-phenyl-2,3,5,6-tetrahydro-4H-1,3,5-thiadiazin-4-one
  • 2-tert-Butyliminotetrahydro-3-isopropyl-5-phenyl-4H-1,3,5-thiadiazin-4-one
  • 2-T-BUTYLIMINO-3-ISOPROPYL-5-PHENYLPERHYDRO-1,3,5-THIADIAZINAM-4-ONE
  • 2-((1,1-Dimethylethyl)imino)tetrahydro-3-(1-methylethyl)-5-phenyl-4H-1,3,5-thiadiazin-4-one 2-(tert-Butylimino)-3-isopropyl-5-phenylperhydro-1,3,5-thidiazin-4-one
  • Buprofezin 100mg [69327-76-0]
  • BUPROFEZINSTANDARD
  • (Z)-2-(tert-butylimino)-5-(4-hydroxyphenyl)-3-isopropyl-1,3,5-thiadiazinan-4-one
  • (Z)-buprofezin
  • 2-tert-butylimino-5-(4-hydroxyphenyl)-3-propan-2-yl-1,3,5-thiadiazinan-4-one
  • VIAPPLA
  • hyl)-5-phenyl-
  • PP618
  • BUTYL
  • アプラウド
  • 2-ターシャリ-ブチルイミノ-3-イソプロピル-5-フェニルテトラヒドロ-4H-1,3,5-チアジアジン-4-オン
  • 2-tert-ブチルイミノテトラヒドロ-3-イソプロピル-5-フェニル-4H-1,3,5-チアジアジン-4-オン
  • 2-tert-ブチルイミノ-3-イソプロピル-5-フェニル-2,3,5,6-テトラヒドロ-4H-1,3,5-チアジアジン-4-オン
  • アプロード
  • ブプロジエン
  • 2-t-ブチルイミノ-3-イソプロピル-5-フェニルペルヒドロ-1,3,5-チアジアジン-4-オン
  • ブプロフェジン標準品
  • 2tブチルイミノ3イソプロピル5フェニルペルヒドロ1,3,5チアジアジン4オン
  • 2-ターシャリ-ブチルイミノ-3-イソプロピル-5-フェニルテトラヒドロ-4H-1,3,5-チアジアジン-4-オン (別名 ブプロフェジン)
  • 2-tert-ブチルイミノ-3-イソプロピル-5-フェニルテトラヒドロ-4H-1,3,5-チアジアジン-4-オン
  • 2-ターシャリ-ブチルイミノ-3-イソプロピル-5-フェニルテトラヒドロ -4H-1,3,5-チアジアジン-4-オン(別名ブプロフェジン)
  • ブプロフェジン STANDARD
  • ブプロフェジン標準物質
  • ブプロフェジン
  • ブプロフェジン Standard, 100 µg/mL in MeOH
  • 昆虫成長調整剤
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