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(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル

(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル 化学構造式
133545-16-1
CAS番号.
133545-16-1
化学名:
(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル
别名:
(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル;(R)-(+)-2,2'-ビス(ジフェニルホスフィノ)-6,6'-ジメトキシ-1,1'-ビフェニル, min. 97% (R)-MeO-BIPHEP(R)-MeO-BIPHEP
英語名:
R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
英語别名:
SL-A101-1;(R)-(+)-MeO-BIPHEP;97% (R)-MeO-BIPHEP;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine);(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph...;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
CBNumber:
CB6502935
化学式:
C38H32O2P2
分子量:
582.62
MOL File:
133545-16-1.mol
MSDS File:
SDS

(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル 物理性質

融点 :
213-216 °C
比旋光度 :
101 º (C=0.3 IN TOLUENE)
沸点 :
651.1±55.0 °C(Predicted)
貯蔵温度 :
under inert gas (nitrogen or Argon) at 2-8°C
外見 :
結晶
色:
オフホワイト

安全性情報

WGK Germany  3
F  8-10-23
HSコード  29319090

(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル 価格 もっと(4)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01SRM15-0178 (R)-(+)-2,2'-ビス(ジフェニルホスフィノ)-6,6'-ジメトキシ-1,1'-ビフェニル, min. 97% (R)-MeO-BIPHEP(R)-MeO-BIPHEP
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP 		133545-16-1 100mg ￥41300 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01SRM15-0178 (R)-(+)-2,2'-ビス(ジフェニルホスフィノ)-6,6'-ジメトキシ-1,1'-ビフェニル, min. 97% (R)-MeO-BIPHEP(R)-MeO-BIPHEP
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP 		133545-16-1 500mg ￥152700 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01SRM15-0178 (R)-(+)-2,2'-ビス(ジフェニルホスフィノ)-6,6'-ジメトキシ-1,1'-ビフェニル, min. 97% (R)-MeO-BIPHEP(R)-MeO-BIPHEP
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP 		133545-16-1 2g ￥519000 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01SRM15-0178 (R)-(+)-2,2'-ビス(ジフェニルホスフィノ)-6,6'-ジメトキシ-1,1'-ビフェニル, min. 97% (R)-MeO-BIPHEP(R)-MeO-BIPHEP
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP 		133545-16-1 10g ￥2074300 2024-03-01 購入

(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル 化学特性,用途語,生産方法

化学的特性

White powder

使用

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

反応性

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
  1. 1.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
  2. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
  3. Conjugate addition using 2-heteroaryl titanates and zinc reagents.
  4. Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
  5. Rhodium-catalyzed carbonyl Z-dienylation.
  6. Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones. 説明図

一般的な説明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル 上流と下流の製品情報

原材料

準備製品

(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル 生産企業

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133545-16-1((R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル)キーワード:

(R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル R-(-)-5,5'-ビス(ジフェニルホスフィノ)-2,2,2',2'-テトラフルオロ-4,4'-ビ-1,3-ベンゾジオキソソール、ジクロロメタン添加 (R)‐(-)‐2,2′‐ビス[ジ(3,5‐ジ‐TERT‐ブチル‐4‐メトキシフェニル)ホスフィノ]‐6,6′‐ジメトキシ‐1,1′‐ビフェニル (S)-(-)-SEGPHOS(regR) (R)‐(+)‐2,2′‐ビス(ジ‐P‐トリルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル (R)-(+)-5,5'-ジクロロ-6,6'-ジメトキシ-2,2'-ビス(ジフェニルホスフィノ)-1,1'-ビフェニル, min. 95% (R)-Cl-MeO-BIPHEP(R)-Cl-MeO-BIPHEP (S)‐(-)‐2,2′‐ビス[ジ(3,5‐ジ‐TERT‐ブチルフェニル)ホスフィノ]‐6,6′‐ジメトキシ‐1,1′‐ビフェニル R-(-)-1,13-ビス(ジフェニルホスフィノ)-7,8-ジヒドロ-6H-ジベンゾ[F,H][1,5]ジオキソニン (S)-(+)-DTBM-SEGPHOS(regR) (S)-(-)-2,2'-ビス[ジ(3,4,5-トリメトキシフェニル)ホスフィノ]-6,6'-ジメトキシ-1,1'-ビフェニル, min. 97% (R)-(+)-〔(5,6),(5′,6′)-ビス(エチレンジオキシ)ビフェニル-2,2′-ジイル〕(ジフェニルホスフィン)
  • 133545-16-1
  • R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
  • (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
  • (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(R)-MeO-BIPHEP
  • (R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
  • 97% (R)-MeO-BIPHEP
  • (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(R)-MeO-BIPHEP
  • (R)-(+)-MeO-BIPHEP
  • SL-A101-1
  • (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) >=97%, optical purity ee: >=99%
  • (S)-(6,6,-dimethoxy-[1,1,-biphenyl]-2,2,-diyl)bis(diphenylphosphine)
  • (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,97% (R)-MeO-BIPHEP
  • (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine)
  • 1,1'-[(1R)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(1,1-diphenyl)-phosphine
  • Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl-
  • (R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny
  • (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph...
  • R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
  • (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
  • R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
  • (R)-(+)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diphenylphosphine)
  • (R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)
  • (R)‐(+)‐2,2′‐ビス(ジフェニルホスフィノ)‐6,6′‐ジメトキシ‐1,1′‐ビフェニル
  • (R)-(+)-2,2'-ビス(ジフェニルホスフィノ)-6,6'-ジメトキシ-1,1'-ビフェニル, min. 97% (R)-MeO-BIPHEP(R)-MeO-BIPHEP
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