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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& structure

CAS No.: 133545-16-1

Chemical Name:: R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

Synonyms: SL-A101-1;(R)-(+)-MeO-BIPHEP;97% (R)-MeO-BIPHEP;(R)-(6,6'-Dimethoxy-[1,1'-biphenyl];R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine);(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny;(R)-(+)-(6,6'-dimethoxybiphenyl-2,2'-yl)bis(diphenylphosphine);(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph...

CBNumber:: CB6502935

Molecular Formula:: C38H32O2P2

Molecular Weight:: 582.62

MDL Number:: MFCD03095430

MOL File:: 133545-16-1.mol

MSDS File:: SDS

Last updated:2025-07-04 15:18:11

Product description	Number	Pack Size	Price
(R)-MeO-BIPHEP	M3596	250MG	$140
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	15-0178	100mg	$96
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	15-0178	500mg	$355
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	15-0178	2g	$1207
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	15-0178	10g	$4824
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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Properties

Melting point	213-216 °C
alpha	101 º (C=0.3 IN TOLUENE)
Boiling point	651.1±55.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	crystal
color	off-white
InChIKey	KRJVQCZJJSUHHO-UHFFFAOYSA-N
SMILES	P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=C(OC)C=1C1C(=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1)OC
UNSPSC Code	12352112
NACRES	NA.22

SAFETY

Risk and Safety Statements

WGK Germany	3
F	8-10-23
HS Code	29319090

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& price More Price(14)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	M3596	(R)-MeO-BIPHEP	133545-16-1	250MG	$140	2025-07-31	Buy
Strem Chemicals	15-0178	(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	133545-16-1	100mg	$96	2024-03-01	Buy
Strem Chemicals	15-0178	(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	133545-16-1	500mg	$355	2024-03-01	Buy
Strem Chemicals	15-0178	(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	133545-16-1	2g	$1207	2024-03-01	Buy
Strem Chemicals	15-0178	(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	133545-16-1	10g	$4824	2024-03-01	Buy

Product number	Packaging	Price	Buy
M3596	250MG	$140	Buy
15-0178	100mg	$96	Buy
15-0178	500mg	$355	Buy
15-0178	2g	$1207	Buy
15-0178	10g	$4824	Buy

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

Reactions

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.

1.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
Conjugate addition using 2-heteroaryl titanates and zinc reagents.
Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
Rhodium-catalyzed carbonyl Z-dienylation.
Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Preparation Products And Raw materials

Raw materials

Preparation Products

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Suppliers

Global( 83)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	+86-13017695106 +86-13676922317	jiuyitime@fdachem.com	China	16514	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13493	58
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29847	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28172	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49975	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5743	58
Wuhan Fortuna Chemical Co., Ltd	+86-027-59207850 +86-13986145403;	info@fortunachem.com	China	6009	58
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	435	58
changzhou huayang technology co., ltd	+8615250961469	2571773637@qq.com	China	9644	58

Supplier	Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	58
Shanghai Daken Advanced Materials Co.,Ltd	58
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Accela ChemBio Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Wuhan Fortuna Chemical Co., Ltd	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
changzhou huayang technology co., ltd	58

View Lastest Price from R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-12-02	(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 133545-16-1	US $0.00 / KG	1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
2025-10-13	R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 133545-16-1	US $2.00-5.00 / kg	1kg	99%	100kg	ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
2019-08-09	R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 133545-16-1	US $1.00 / KG	1KG	98%	1kg,5kg,100kg	Career Henan Chemical Co

(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)
133545-16-1
US $0.00 / KG
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
133545-16-1
US $2.00-5.00 / kg
99%
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
133545-16-1
US $1.00 / KG
98%
Career Henan Chemical Co

133545-16-1(R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&)Related Search:

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (R)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (R)-CYCLOHEXYL SONIPHOS

(R)-C3-TUNEPHOS-RUTHENIUM COMPLEX (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-N,N'-DIMETHYL-7,7'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3',4,4'-TETRAHYDRO-8,8'-BI-2H-1,4-BENZOXAZINE ISOPROPANOL ADDUCT (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-C3-TUNEPHOS (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN SOLPHOS SL-A001-1

(R)-METHYL SONIPHOS CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYL-PHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM(II) CHLORIDE CH2CL2 ADDUCT (S)-(-)-2,2'-BIS[3'',4''-METHYLENEOXYPHENYLPHOSPHINO]-5,6-5',6'-DIMETHYLENEOXY-BIPHENYL

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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(R)-MeO-BIPHEP (R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl 97% (R)-MeO-BIPHEP (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(R)-MeO-BIPHEP (R)-(+)-MeO-BIPHEP SL-A101-1 (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) >=97%, optical purity ee: >=99% (S)-(6,6,-dimethoxy-[1,1,-biphenyl]-2,2,-diyl)bis(diphenylphosphine) (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,97% (R)-MeO-BIPHEP (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine) 1,1'-[(1R)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(1,1-diphenyl)-phosphine Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl- (R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph... R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (R)-(+)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diphenylphosphine) (R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) (6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) (R)-(6,6'-Dimethoxy-[1,1'-biphenyl] (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine), CAS 133545-16-1 (6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) (R)-(+)-(6,6'-dimethoxybiphenyl-2,2'-yl)bis(diphenylphosphine) (R)-MeO-BIPHEP, (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) (R)-MeO-BIPHEP / (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl 133545-16-1 C38H32O2P2 Chiral Phosphine MeOBIPHEP Series