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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 구조식 이미지

카스 번호:: 133545-16-1

상품명:: R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

동의어(영문):: SL-A101-1;(R)-(+)-MeO-BIPHEP;97% (R)-MeO-BIPHEP;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine);(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph...;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)

CBNumber:: CB6502935

분자식:: C38H32O2P2

포뮬러 무게:: 582.62

MOL 파일:: 133545-16-1.mol

MSDS 파일:: SDS

속성

안전

용도

공급 업체 66

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 속성

녹는점: 213-216 °C

알파: 101 º (C=0.3 IN TOLUENE)

끓는 점: 651.1±55.0 °C(Predicted)

저장 조건: under inert gas (nitrogen or Argon) at 2-8°C

물리적 상태: 수정 같은

색상: 회백색

안전

WGK 독일	3
F 고인화성물질	8-10-23
HS 번호	29319090

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& C화학적 특성, 용도, 생산

화학적 성질

White powder

용도

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

화학 반응

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.

1.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
Conjugate addition using 2-heteroaryl titanates and zinc reagents.
Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
Rhodium-catalyzed carbonyl Z-dienylation.
Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.

일반 설명

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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 준비 용품 및 원자재

원자재

준비 용품

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 공급 업체

글로벌( 66)공급 업체

공급자	전화	이메일	국가	제품 수	이점
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49390	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58
Wuhan Fortuna Chemical Co., Ltd	+86-27-59207850 +86-13986145403	info@fortunachem.com	China	5988	58
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	407	58
changzhou huayang technology co., ltd	+8615250961469	2571773637@qq.com	China	9821	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19994	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418684 +8618949823763	sales@tnjchem.com	China	25363	58

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 관련 검색:

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-DIFLUORPHOS(TM) (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (R)-CYCLOHEXYL SONIPHOS (R)-C3-TUNEPHOS-RUTHENIUM COMPLEX (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-N,N'-DIMETHYL-7,7'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3',4,4'-TETRAHYDRO-8,8'-BI-2H-1,4-BENZOXAZINE ISOPROPANOL ADDUCT (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-C3-TUNEPHOS (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN SOLPHOS SL-A001-1 (R)-METHYL SONIPHOS CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYL-PHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM(II) CHLORIDE CH2CL2 ADDUCT (S)-(-)-2,2'-BIS[3'',4''-METHYLENEOXYPHENYLPHOSPHINO]-5,6-5',6'-DIMETHYLENEOXY-BIPHENYL