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フタル酸ジメチル

フタル酸ジメチル 化学構造式
131-11-3
CAS番号.
131-11-3
化学名:
フタル酸ジメチル
别名:
フタル酸ジメチル;1,2-ベンゼンジカルボン酸ジメチル;ジメチル=フタラート;レペフタール;3,3-ジメトキシプロピオンアルデヒド;フェルミン;パラチノールM;アボリン;フタル酸メチル;ソルバロン;ベンゼン-1,2-ジカルボン酸ジメチル;3,3-ジメトキシプロパナール;ソルバノム;ミパックス;ジメチルテレフタレト;ジメチルテレフタレ-ト;フタル酸ジメチル標準品;フタル酸ジメチル フタル酸メチル;フタル酸ジメチル(DMP);DMP標準品
英語化学名:
Dimethyl phthalate
英語别名:
NTM;DMP;MIPAX;Avolin;ent262;DMP(R);ENT 262;FERMINE;Repeftal;Solvanom
CBNumber:
CB9472655
化学式:
C10H10O4
分子量:
194.18
MOL File:
131-11-3.mol

フタル酸ジメチル 物理性質

融点 :
2 °C(lit.)
沸点 :
282 °C(lit.)
比重(密度) :
1.19 g/mL at 25 °C(lit.)
蒸気圧:
0.008 hPa (20 °C)
屈折率 :
n20/D 1.515(lit.)
闪点 :
295 °F
貯蔵温度 :
2-8°C
溶解性:
4.0g/l
外見 :
Liquid
色:
Clear
比重:
1.194 (20/4℃)
Relative polarity:
0.309
PH:
7 (H2O, 20℃)
水溶解度 :
<0.1 g/100 mL at 20 ºC
Merck :
14,3255
BRN :
1911460
Henry's Law Constant:
At 25 °C: 235, 246, 230, 214, 168, 127, and 118 at pH values of 3.00, 3.37, 5.88, 6.18, 7.62, 8.91, and 8.99, respectively (Hakuta et al., 1977).
暴露限界値:
TLV-TWA air 5 mg/m3 (ACGIH, MSHA, and OSHA).
安定性::
Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, strong bases, nitrates. Sensitive to prolonged exposure to light.
InChIKey:
NIQCNGHVCWTJSM-UHFFFAOYSA-N
CAS データベース:
131-11-3(CAS DataBase Reference)
NISTの化学物質情報:
Dimethyl phthalate(131-11-3)
EPAの化学物質情報:
1,2-Benzenedicarboxylic acid, dimethyl ester(131-11-3)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  F,T
Rフレーズ  20/21/22-36/37/38-39/23/24/25-23/24/25-11-52
Sフレーズ  24/25-45-36/37-16-7
RIDADR  UN 3082
WGK Germany  1
RTECS 番号 TI1575000
自然発火温度 460 °C DIN 51794
TSCA  Yes
HSコード  2917 34 00
有毒物質データの 131-11-3(Hazardous Substances Data)
毒性 LD50 in mice, rats, guinea pigs (ml/kg): 7.2, 6.9, 2.4 orally (Draize)
消防法 危険物第4類第三石油類(非水溶性)
化審法 (3)-1301
安衛法 57,57-2
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H225 引火性の高い液体および蒸気 引火性液体 2 危険 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H370 臓器の障害 特定標的臓器有害性、単回暴露 1 危険 P260, P264, P270, P307+P311, P321,P405, P501
注意書き
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P260 粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P301+P310 飲み込んだ場合:直ちに医師に連絡すること。
P311 医師に連絡すること。

フタル酸ジメチル 価格 もっと(36)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01W0113-0765 フタル酸ジメチル 97.0+% (Capillary GC)
Dimethyl Phthalate 97.0+% (Capillary GC)
131-11-3 500g ¥2450 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01W0113-0296 フタル酸ジメチル 98.0+% (Capillary GC)
Dimethyl Phthalate 98.0+% (Capillary GC)
131-11-3 500g ¥2650 2018-12-26 購入
東京化成工業 P0302 フタル酸ジメチル >99.0%(GC)
Dimethyl Phthalate >99.0%(GC)
131-11-3 25g ¥1800 2018-12-04 購入
東京化成工業 P0302 フタル酸ジメチル >99.0%(GC)
Dimethyl Phthalate >99.0%(GC)
131-11-3 500g ¥2800 2018-12-04 購入
関東化学株式会社(KANTO) 10371-00 フタル酸ジメチル >99.5%(GC)
Dimethyl phthalate (DMP) >99.5%(GC)
131-11-3 500mL ¥2700 2018-12-13 購入

フタル酸ジメチル 化学特性,用途語,生産方法

外観

無色澄明の液体

定義

本品は、フタル酸とメタノールのジエステルであり、次の化学式で表される。

溶解性

水に微溶 (0.5g/100ml水, 20℃)。エタノール及びアセトンに極めて溶けやすく、水にほとんど溶けない。

用途

環境試料中のフタル酸エステルの分析(HPLC)用標準品、GC-MS分析標準品。

用途

可塑剤。溶剤。有機合成原料。

用途

プラスチック添加剤(可塑剤)

用途

アセテートセルロースプラスチック及び顔料ラッカー製造、塩化ビニルフィルム、弾性体可塑物の製造

化粧品の成分用途

可塑剤、溶剤、香料

化学的特性

colourless oily liquid

化学的特性

Dimethyl phthalate occurs as a colorless, or faintly colored, odorless, viscous, oily liquid.

物理的性質

Clear, colorless, odorless, moderately viscous, oily liquid

使用

Dimethyl phthalate is used as an insect repellant. It has also been employed as a solvent for cellulose acetate.

使用

Insect repellant.

使用

It is used as insect repellent.

使用

Dimethyl Phalate is the methyl ester of phthalic acid. Dimethyl phthalate is an ectoparasiticide and has many other uses, including in solid rocket propellants, plastics, and insect repellents.

使用

Solvent and plasticizer for cellulose acetate and cellulose acetate-butyrate compositions. Insect repellent for personal protection against biting insects.

調製方法

Dimethyl phthalate is produced industrially from phthalic anhydride and methanol.

一般的な説明

A water-white liquid without significant odor. Denser than water and insoluble in water. Hence sinks in water. Flash point 300°F. Eye contact may produce severe irritation and direct skin contact may produce mild irritation. Used in the manufacture of a variety of products including plastics, insect repellents, safety glass, and lacquer coatings.

空気と水の反応

Insoluble in water.

反応プロフィール

Dimethyl phthalate reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides. Can generate electrostatic charges by swirling or pouring [Handling Chemicals Safely, 1980. p. 250].

健康ハザード

Symptoms unlikely from any exposure.

健康ハザード

The acute toxicity of dimethyl phthalate intest animals was found to be very low.Ingestion may produce irritation of the gas trointestinal tract, somnolence, hypotension,and coma. The oral LD50 value in miceis 6800 mg/kg. Animal studies have shownthat administration of this compound causeddevelopmental toxicity, having effects on fer tility. Maternal toxicity in Sprague-Dawleyrats was observed at a dietary treatmentlevel of 5% (Field 1989). There was noeffect on average litter size, fetal bodyweight, or the incidence of skeletal or vis ceral malformations.

火災危険

Dimethyl phthalate is combustible.

応用例(製薬)

Dimethyl phthalate is used in pharmaceutical applications as a solvent and plasticizer for film-coatings such as hydroxypropyl methylcellulose, cellulose acetate and cellulose acetate–butyrate mixtures.
In addition to a number of industrial applications, dimethyl phthalate is also widely used as an insect repellent with topical preparations typically applied as a 40% cream or lotion; it has also been applied as a tent fabric treatment.

接触アレルゲン

Phthalates are plasticizers and increase the flexibility of plastics. They are also found in deodorant formulations, perfumes, emollients, and insect repellents.

安全性プロファイル

Moderately toxic by ingestion and intraperitoneal routes. Mldly toxic by inhalation. Experimental teratogenic and reproductive effects. Mutation data reported. An eye irritant. A pesticide and insect repellent. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

安全性

In pharmaceutical applications, dimethyl phthalate is used in film coating and as a topically applied insect repellent.Acute exposure to the eyes and mucous membranes can cause irritation, although dimethyl phthalate is considered less irritant than diethyl phthalate. Inhalation of dimethyl phthalate can cause irritation of the respiratory tract; oral ingestion can cause a burning sensation in the mouth, vomiting, and diarrhea. Owing to the low water solubility and relatively high lipid solubility, dimethyl phthalate may accumulate in body tissues after chronic exposure, which may cause central nervous system depression.
Although some animal studies have suggested that high concentrations of dimethyl phthalate may be teratogenic or cause mutagenic effects with bacteria,(5,6) other studies have shown no adverse effects.(7) There are no confirmed reports of human reproductive or developmental effects, and the compound is not generally regarded as a carcinogenic material.
LD50 (chicken, oral): 8.5g/kg
LD50 (guinea pig, oral): 2.4g/kg
LD50 (mouse, IP): 1.38g/kg
LD50 (mouse, oral): 6.8g/kg
LD50 (rabbit, oral): 4.40g/kg
LD50 (rat, IP): 3.38g/kg
LD50 (rat, oral): 6.80g/kg

Source

May leach from plastic products (e.g., tubing, containers) used in laboratories during chemical analysis of aqueous samples.

環境運命予測

Biological. In anaerobic sludge, degradation occurred as follows: monomethyl phthalate to phthalic acid to protocatechuic acid followed by ring cleavage and mineralization (Shelton et al., 1984). In a static-culture-?ask screening test, dimethyl phthalate showed significant biodegradation with rapid adaptation. The ester (5 and 10 mg/L) was statically incubated in the dark at 25°C with yeast extract and settled domestic wastewater inoculum. After 7 days, 100% biodegrada-tion was achieved (Tabak et al., 1981).
Photolytic. An aqueous solution containing titanium dioxide and subjected to UV light (λ >290 nm) yielded mono- and dihydroxyphthalates as intermediates (Hustert and Moza, 1988).
Chemical/Physical. Hydrolyzes in water forming phthalic acid and methyl alcohol (Wolfe et al., 1980).

貯蔵

Dimethyl phthalate is sensitive to prolonged exposure to light and it should therefore be stored in a cool, dark, dry, well-ventilated area that is protected from physical damage, and isolated from incompatible substances. Containers of dimethyl phthalate may be hazardous when empty as they may retain product residues such as vapors and liquids. There is a slight fire hazard when exposed to heat, and above the flash point explosive vapor–air mixtures may be formed.Carbon dioxide and carbon monoxide are released when dimethyl phthalate is heated to decomposition. Solutions of dimethyl phthalate in acetone, dimethyl sulfoxide, ethanol (95%), and water are stable for 24 hours under normal laboratory conditions.

不和合性

Dimethyl phthalate is incompatible with strong acids or bases, nitrates, and strong oxidizing agents. As with other phthalates, contact with plastics should be avoided.

規制状況(Regulatory Status)

Dimethyl phthalate is included in a number of topical pharmaceutical formulations. Included in the FDA Inactive Ingredients Database (oral tablets, sustained action). As from 1992, dimethyl phthalate is no longer registered for use as a pesticide in California.

フタル酸ジメチル 上流と下流の製品情報

原材料

準備製品


フタル酸ジメチル 生産企業

Global( 315)Suppliers
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Mainchem Co., Ltd.
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Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1861 55
Shenzhen Sendi Biotechnology Co.Ltd.
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Henan DaKen Chemical CO.,LTD.
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131-11-3(フタル酸ジメチル)キーワード:


  • 131-11-3
  • 1,2-benzendicarboxylicacid,dimethylester
  • 1,2-dimethyl phthalate
  • ai3-00262
  • Avolin
  • caswellno380
  • Dimethyl 1,2-benzenedicarboxylate acid
  • Dimethyl benzene-o-dicarboxylate
  • Dimethyl benzeneorthodicarboxylate
  • Dimethyl orthophthalate
  • dimethylbenzene-o-dicarboxylate
  • DiMethyl phthalate, 99% 1LT
  • DiMethyl phthalate, 99% 250ML
  • NSC 15398
  • Phthalic Acid Dimethyl Ester DMP
  • DiMethyl Phthalate Acid Ester in Methanol Certified Reference Material
  • dimethylesterkyselinyftalove
  • dimethyl-phthalate(1,2-benzenedicarboxylicacid,dimethylester)
  • dimethylphthalate(dmp)
  • dmf(insectrepellant)
  • dmf(insectrepellent)
  • DMF, Insect repellent
  • ENT 262
  • ent262
  • epapesticidechemicalcode028002
  • Kemester DMP
  • Kodaflex DMP
  • NTM
  • PHTHALIC ACID DIMETHYL ESTER
  • PHTHALIC ACID, BIS-METHYL ESTER
  • PALATINOL M
  • フタル酸ジメチル
  • 1,2-ベンゼンジカルボン酸ジメチル
  • ジメチル=フタラート
  • レペフタール
  • 3,3-ジメトキシプロピオンアルデヒド
  • フェルミン
  • パラチノールM
  • アボリン
  • フタル酸メチル
  • ソルバロン
  • ベンゼン-1,2-ジカルボン酸ジメチル
  • 3,3-ジメトキシプロパナール
  • ソルバノム
  • ミパックス
  • ジメチルテレフタレト
  • ジメチルテレフタレ-ト
  • フタル酸ジメチル標準品
  • フタル酸ジメチル フタル酸メチル
  • フタル酸ジメチル(DMP)
  • DMP標準品
  • フタル酸ジメチル (DMP)DMP
  • フタル酸ジメチル STANDARD
  • フタル酸ジメチル 溶液
  • フタル酸ジメチル (DMP)DMP, 100 µg/mL in MeOH
  • フタル酸ジメチル Standard, 0.1 mg/mL in EtOAc
  • フタル酸ジメチル Standard, 100 µg/mL in MeOH
  • フタル酸ジメチル Standard, 5.0 mg/mL in MeOH
  • フタル酸ジメチル, 0.1 mg/mL in EtOAc
  • フタル酸ジメチル, 1000 µg/mL in Methanol
  • フタル酸ジメチル, 99%
  • 機能性材料
  • 可塑剤
  • フタル酸エステル (可塑剤)
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