플루아지남

플루아지남
플루아지남 구조식 이미지
카스 번호:
79622-59-6
한글명:
플루아지남
동의어(한글):
플루아지남;N-(3-클로로-5-트리플루오르-메틸-2-피리딜)-2,6-디니트로-3-클로로-4-트리플루오로메틸아닐린
상품명:
Fluazinam
동의어(영문):
Fluazinam Standard;3-Chloro-N-(3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)pyridin-2-amine;pp192;Mapro;B 1216;AltiMa;Sekoya;SHIRLAN;ikf1216;IKI 1216
CBNumber:
CB1161197
분자식:
C13H4Cl2F6N4O4
포뮬러 무게:
465.09
MOL 파일:
79622-59-6.mol

플루아지남 속성

녹는점
100-102°
끓는 점
376.1±42.0 °C(Predicted)
밀도
1.766±0.06 g/cm3(Predicted)
증기압
1.5 x 10-3 Pa (25 °C)
인화점
2 °C
저장 조건
2-8°C
용해도
DMF:25.0(Max Conc. mg/mL);53.75(Max Conc. mM)
DMSO:25.0(Max Conc. mg/mL);53.75(Max Conc. mM)
Ethanol:15.0(Max Conc. mg/mL);32.25(Max Conc. mM)
PBS (pH: 7.2):0.25(Max Conc. mg/mL);0.54(Max Conc. mM)
산도 계수 (pKa)
7.11(at 25℃)
수용성
1.7mg l-1(25°C)
색상
Light yellow to Amber to Dark green
Merck
14,4117
BRN
4772672
InChIKey
UZCGKGPEKUCDTF-UHFFFAOYSA-N
LogP
3.560
CAS 데이터베이스
79622-59-6(CAS DataBase Reference)
EPA
Fluazinam (79622-59-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T;N,N,T,Xn,F
위험 카페고리 넘버 23-41-43-50/53-36-20/21/22-11-38-20-63
안전지침서 26-36/37/39-45-60-61-36/37-16-63-57-56-38-28-27-24/25-20/21-13
유엔번호(UN No.) UN 2811
WGK 독일 3
RTECS 번호 UR8085000
위험 등급 6.1
포장분류 II
HS 번호 29333990
유해 물질 데이터 79622-59-6(Hazardous Substances Data)
기존화학 물질 KE-05-0343
유해화학물질 필터링 97-1-375;06-4-41
함량 및 규제정보 물질구분: 금지물질; 혼합물(제품)함량정보: 플루아지남 및 이를 25% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 GHS hazard pictograms P261, P271, P304+P340, P312
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
0
3 0

플루아지남 C화학적 특성, 용도, 생산

개요

Fluazinam, with a LogP of 3.56, has very low solubility in water (1.7 mgL?1, pH6.8, 25?C) but higher solubilities in organic solvents (e.g., acetone 470 g/L, dichloromethane 330 g/L, ethanol 150 g/L, all at 20 ?C). The active ingredient forms light yellow crystals with an MP of 115 to 117 ?C and has a vp of 1.5 mPa (25 ?C). The compound is stable to acid, alkali, and heat (5).

화학적 성질

yellow crystal mp 115 ~ 117°C

용도

Fluazinam is a broad spectrum fungicide. Fluazinam is commonly used for control of Sclerotinia blight and other soilborne pathogens of peanut as well for the control of potato blight.

정의

ChEBI: Fluazinam is a member of the class of aminopyridines that is 2-amino-5-(trifluoromethyl)pyridine in which one of the amino hydrogens is replaced by a 3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl group. A fungicide used to control grey mould, downy mildew and other fungal pathogens. It has a role as an apoptosis inducer, an allergen, a xenobiotic, an environmental contaminant and an antifungal agrochemical. It is a C-nitro compound, a chloropyridine, an aminopyridine, a secondary amino compound, a member of monochlorobenzenes and a member of (trifluoromethyl)benzenes.

일반 설명

Fluazinam is a 2,6-dinitroaniline protectant fungicide, which belongs to the pyridinamine group. It can mostly find applications in agriculture.

위험도

Moderately toxic by ingestion and inhalation. A reproductive hazard.

농업용

Fungicide: Used to control Sclerotinia blight on peanuts and late blight and white mold on potatoes.

상품명

FLUAZINAM 50 WP®; FROWNCIDE®; IKF-1216®; ICIA-192®; OMEGA; PP-192®; SHIRLAN®

색상 색인 번호

Fluazinam is a pesticide with a broad spectrum of anti fungal activity. It caused sensitization in employees in the tulip bulb industry and in farmers. Fluazinam induced contact dermatitis in a worker in a plant where it was manufactured.

Safety Profile

Moderately toxic by ingestion and inhalation. Experimental reproductive effects. When heated to decomposition it emits toxic vapors of NOx, F-, and Cl-.

신진 대사 경로

Fluazinam may typically be applied to crops of potatoes using up to 10 applications each of 150 g ha-1. Routes of degradation involve ring hydroxylation in aerobic soils and reduction of the nitro groups in flooded soils. A large amount of unextractable residue was observed. In potatoes and rats, important reactions involve the reduction of nitro groups and the formation of conjugates. In plants, the trifluoromethyl substituents are hydrolysed to carboxylic acid groups. Most of the information presented below was taken from an evaluation of the fungicide published by the UK Pesticide Safety Directorate (PSD, 1994).

플루아지남 준비 용품 및 원자재

원자재

준비 용품


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